摘要:
A membrane electrode assembly comprising an ionically conductive member and an electrode, wherein the electrode is a smooth, continuous layer that completely covers and supports the ionically conductive member. The electrode further comprises a central region and a peripheral region, wherein a gradient of electrochemically active material exists between the central region and the peripheral region such that a content of the electrochemically active material is greater in the central region than the peripheral region.
摘要:
A membrane electrode assembly comprising an ionically conductive member and an electrode, wherein the electrode is a smooth, continuous layer that completely covers and supports the ionically conductive member. The electrode further comprises a central region and a peripheral region, wherein a gradient of electrochemically active material exists between the central region and the peripheral region such that a content of the electrochemically active material is greater in the central region than the peripheral region.
摘要:
A fuel cell system including a fuel reforming processor having a catalyst therein constructed and arranged to produce a reformate stream including hydrogen and carbon monoxide, a water gas shift reactor downstream of the fuel reforming processor and wherein the water gas shift reactor includes a catalyst therein constructed and arranged to reduce the amount of carbon monoxide in the reformate stream, a preferential oxidation reactor downstream of the water gas shift reactor and wherein the preferential oxidation reactor includes a catalyst therein constructed and arranged to preferentially oxidize carbon monoxide into carbon dioxide and to produce a hydrogen-rich stream, and a fuel cell stack downstream of the preferential oxidation reactor constructed and arranged to produce electricity from the hydrogen-rich stream, a first direct water vaporizing combustor constructed and arranged to combust fuel producing a high-temperature fuel combustion byproducts exhaust and to produce steam from water sprayed into the combustion byproduct exhaust and wherein the first direct water vaporizing combustor is plumbed to the fuel reforming reactor to charge steam therein, and a second direct water vaporizing combustor constructed and arranged to combust fuel to produce a high-temperature fuel combustion byproduct exhaust and to produce steam from water sprayed into the fuel combustion byproduct exhaust and wherein the second direct water vaporizing combustor is plumbed to the water gas shift reactor to charge steam therein.
摘要:
Between adjacent MEA's is a bipolar plate assembly having a first sub-plate with a flow channel which is open to the anode side of the one of the MEA's. A second sub-plate has a flow channel which is open to the cathode side of the adjacent MEA. The sub-plates are nested together to form a coolant flow channel between the sub-plates. The coolant flow path has a height dimension wherein the distance between the adjacent MEA's is substantially unaffected by the height dimension of the coolant flow path. A method of manufacturing a bi-polar plate assembly includes forming a closed coolant flow channel between the sub-plates by nesting the sub-plates together. A method of operating a fuel cell includes passing the coolant through a flow path having a height dimension which is substantially aligned with the height dimension of the hydrogen flow path, the oxygen flow path, or both.
摘要:
A fuel cell system that includes an over-arching algorithm for providing a strategy that reduces relative humidity cycling of the cathode outlet gas between wet and dry operation to extend the useful life of the membrane. The algorithm receives sensor signals indicative of operating parameters of the fuel cell system. The algorithm maintains a cathode exhaust gas relative humidity in a wet operating mode if the operating parameters of the fuel cell system are able to sustain the cathode gas relative humidity above a first predetermined value, and maintains the cathode exhaust gas relative humidity in a dry operating mode if the operating parameters of the fuel cell system are able to sustain the cathode gas relative humidity below a second predetermined value.
摘要:
A system and method of balancing a hydrogen feed for a fuel cell to optimize flow of hydrogen through the fuel cell, wherein a pressure drop through parallel feed channels and active area channels of the fuel cell is balanced.
摘要:
Clearance gaps in the inactive feed regions of a fuel cell stack are controlled by non-bonded, non-nested bipolar plates to provide reactant flow uniformity and pressure within fuel cells and fuel cell stacks utilizing nested bipolar plates in the active feed regions and non-nested bipolar plates in the inactive feed regions.
摘要:
A fuel cell system and a scheme for its operation are provided for improving overall water mass balance within the system. In accordance with one embodiment of the present invention, an electrochemical conversion assembly is provided where the coolant flowfield portion defines an operating coolant temperature profile characterized by areas of relatively low coolant temperature TMIN and areas of relatively high coolant temperature TMAX. The cathode flowfield portion and the coolant flowfield portion are configured such that the reactant input and the reactant output are positioned closer to the areas of relatively low coolant temperature TMIN than the areas of relatively high coolant temperature TMAX. In accordance with another embodiment of the present invention, the cathode flowfield portion and the coolant flowfield portion are configured such that the areas of relatively low coolant temperature TMIN are positioned in closer thermal communication with the reactant input and the reactant output than are the areas of relatively high coolant temperature TMAX.
摘要翻译:提供燃料电池系统及其操作方案,用于改善系统内的总体水质平衡。 根据本发明的一个实施例,提供一种电化学转换组件,其中冷却剂流场部分限定了以相对低的冷却剂温度T MIN MIN区域和相对高的冷却剂的区域为特征的操作冷却剂温度分布 温度T最大值 SUB>。 阴极流场部分和冷却剂流场部分被配置成使得反应物输入和反应物输出被定位成比冷却剂温度相对较高的区域T'更靠近相对较低的冷却剂温度T MINI的区域, SUB> MAX SUB>。 根据本发明的另一个实施例,阴极流场部分和冷却剂流场部分被构造成使得相对低的冷却剂温度T MIN MIN的区域定位成与反应物输入端更加热连通, 反应物输出比相对高的冷却剂温度T MAX MAX的区域。
摘要:
A method and device for operating a fuel cell system. A recirculation loop coupled to a fuel cell cathode ensures that fluids passing through the cathode are recycled, thereby enabling reaction between residual oxygen in the recycled fluid and fuel that has been introduced into the recirculation loop until substantially all of the oxygen is reacted, leaving a substantially oxygen-free, predominantly nitrogen compound in the cathode and related flowpath. Thereafter, this compound can be redirected to purge the remaining residual hydrogen resident in the fuel cell's anode and related flowpath. While the present invention is usable during any period of system operation, it is especially valuable for operational conditions associated with starting up and shutting down a fuel cell system to inhibit the formation of high voltage potentials that could otherwise damage fuel cell catalysts or catalysts supports.
摘要:
A model uses various operating characteristics of a fuel cell to predict the relative humidity profile that is occurring within the fuel cell as a function of the reaction progress. The model is used to predict the relative humidity profile that will occur in response to changes to one or more of the operating characteristics of the fuel cell. A high frequency resistance of the fuel cell can also be used as a measure that is indicative of the humidity within the fuel cell. The model and/or the high frequency resistance can be used in a closed-loop feedback system to control the operation of the fuel cell to maintain the humidification of the MEA and fuel cells within a desired range to achieve a desired fuel cell performance.