Thermoplastic elastomers having improved adhesive proterties
    2.
    发明授权
    Thermoplastic elastomers having improved adhesive proterties 失效
    热塑性弹性体具有改善的粘合剂成分

    公开(公告)号:US06790911B2

    公开(公告)日:2004-09-14

    申请号:US10329592

    申请日:2002-12-26

    IPC分类号: C08F800

    摘要: A thermoplastic vulcanizate prepared by dynamically vulcanizing a halogenated butyl rubber within a mixture that includes the halogenated butyl rubber and from about 10 to about 100 parts by weight of a crystalline thermoplastic resin per 100 parts by weight rubber, to thereby form a thermoplastic vulcanizate, where the thermoplastic resin includes a resin other than polyethylene, melt mixing the thermoplastic vulcanizate with about 5 to about 75 parts by weight of polyethylene resin per 100 parts by weight rubber, from about 3 to about 60 parts by weight of a tackifier per 100 parts by weight rubber, and from about 5 to about 250 parts by weight of a block copolymer containing at least the structure S-B/S-S per 100 parts by weight rubber, where the S block of the block copolymer has a glass transition temperature above about 25° C., the B/S block has a glass transition temperature below about 25° C., and the S content of the B/S block is from about 40 to about 60 percent by weight of said S/B block, the diene content of the total block copolymer is less than 40 weight percent, and the B/S block amount to at least 50 weight percent of the total block copolymer.

    摘要翻译: 通过在包含卤化丁基橡胶的混合物中动态硫化卤化丁基橡胶和每100重量份橡胶约10至约100重量份的结晶热塑性树脂制备的热塑性硫化橡胶,从而形成热塑性硫化橡胶,其中 热塑性树脂包括除了聚乙烯之外的树脂,将热塑性硫化橡胶与每100重量份橡胶约5至约75重量份的聚乙烯树脂熔融混合,每100重量份约3至约60重量份的增粘剂 和约5至约250重量份的嵌段共聚物,其至少包含每100重量份橡胶中的结构SB / SS,其中嵌段共聚物的S嵌段具有高于约25℃的玻璃化转变温度 B / S块的玻璃化转变温度低于约25℃,B / S嵌段的S含量为约40至约60重量% f所述S / B嵌段,总嵌段共聚物的二烯含量小于40重量%,B / S嵌段占总嵌段共聚物的至少50重量%。