Process for the preparation of a furfural derivative comprising neutralizing an acid reaction mixture

    公开(公告)号:US10266508B2

    公开(公告)日:2019-04-23

    申请号:US15736037

    申请日:2016-07-01

    申请人: Synvina C.V.

    IPC分类号: C07D307/46 C07D307/48

    摘要: A furfural derivative having the chemical formula (1) where R represents hydrogen, an alkyl group or an acyl group, is prepared in a process, which process includes reacting a fructose- and/or glucose-containing starting material with a liquid hydroxyl group-containing compound of formula R—OH in the presence of an acid catalyst at a reaction temperature in the range of 150 to 300° C. to produce a primary acid reaction mixture including the furfural derivative of chemical formula (1); separating part of the liquid hydroxyl group-containing compound from the primary acid reaction mixture to yield a secondary acid reaction mixture; neutralizing the secondary acid reaction mixture to a pH-value of at least 3 to obtain a neutralized reaction mixture; and purifying the neutralized reaction mixture to recover the furfural derivative of chemical formula (1).

    PROCESS FOR THE PREPARATION OF A FURFURAL DERIVATIVE COMPRISING NEUTRALIZING AN ACID REACTION MIXTURE

    公开(公告)号:US20180186761A1

    公开(公告)日:2018-07-05

    申请号:US15736037

    申请日:2016-07-01

    申请人: Synvina C.V.

    IPC分类号: C07D307/48

    CPC分类号: C07D307/48 C07D307/46

    摘要: A furfural derivative having the chemical formula (1) where R represents hydrogen, an alkyl group or an acyl group, is prepared in a process, which process includes reacting a fructose-and/or glucose-containing starting material with a liquid hydroxyl group-containing compound of formula R—OH in the presence of an acid catalyst at a reaction temperature in the range of 150 to 300° C. to produce a primary acid reaction mixture including the furfural derivative of chemical formula (1); separating part of the liquid hydroxyl group-containing compound from the primary acid reaction mixture to yield a secondary acid reaction mixture; neutralizing the secondary acid reaction mixture to a pH-value of at least 3 to obtain a neutralized reaction mixture; and purifying the neutralized reaction mixture to recover the furfural derivative of chemical formula (1).

    Process for the preparation of a furfural derivative

    公开(公告)号:US10351543B2

    公开(公告)日:2019-07-16

    申请号:US15736033

    申请日:2016-07-01

    申请人: Synvina C.V.

    IPC分类号: C07D307/50

    摘要: A furfural derivative having the chemical formula (1) wherein R represents hydrogen, an alkyl group or an acyl group, is prepared in a process, which process includes reacting a fructose- and/or glucose-containing starting material with a liquid hydroxyl group-containing compound of formula R—OH in the presence of an acid catalyst at a reaction temperature in the range of 150 to 300° C. to produce an acid reaction mixture including the furfural derivative of chemical formula (1), which acid reaction mixture has a pH-value of smaller than 3; neutralizing the acid reaction mixture to a pH-value in the range of 3 to 6.5 to provide a partially neutralized reaction mixture; and purifying the partially neutralized reaction mixture to recover the furfural derivative of chemical formula (1).

    PROCESS FOR THE PREPARATION OF A FURFURAL DERIVATIVE

    公开(公告)号:US20180170890A1

    公开(公告)日:2018-06-21

    申请号:US15736033

    申请日:2016-07-01

    申请人: Synvina C.V.

    IPC分类号: C07D307/50

    CPC分类号: C07D307/50

    摘要: A furfural derivative having the chemical formula (1) wherein R represents hydrogen, an alkyl group or an acyl group, is prepared in a process, which process includes reacting a fructose- and/or glucose-containing starting material with a liquid hydroxyl group-containing compound of formula R—OH in the presence of an acid catalyst at a reaction temperature in the range of 150 to 300° C. to produce an acid reaction mixture including the furfural derivative of chemical formula (1), which acid reaction mixture has a pH-value of smaller than 3; neutralizing the acid reaction mixture to a pH-value in the range of 3 to 6.5 to provide a partially neutralized reaction mixture; and purifying the partially neutralized reaction mixture to recover the furfural derivative of chemical formula (1).