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公开(公告)号:US20250014792A1
公开(公告)日:2025-01-09
申请号:US18702173
申请日:2022-11-02
Applicant: TDK CORPORATION
Inventor: Hiroki KAWAMURA , Hikaru KUDO , Masashi MIWA
IPC: H01F1/057
Abstract: An R-T-B based permanent magnet contains Al, Ga, and Zr. The R content is greater than or equal to 30.00 mass % and less than or equal to 33.00 mass %, the B content is greater than or equal to 0.70 mass % and less than or equal to 0.88 mass %, the Al content is greater than 0 mass % and less than or equal to 0.07 mass %, the Ga content is greater than or equal to 0.40 mass % and less than or equal to 1.00 mass %, and the Zr content is greater than 0.10 mass % and less than or equal to 1.60 mass %.
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公开(公告)号:US20210407714A1
公开(公告)日:2021-12-30
申请号:US17356178
申请日:2021-06-23
Applicant: TDK CORPORATION
Inventor: Koji MIURA , Masashi MIWA
Abstract: To provide an R-T-B based permanent magnet having a high residual magnetic flux density Br at room temperature and a high coercivity HcJ at high temperature. In the R-T-B based permanent magnet, R is a rare earth element, T is an iron group element, and B is boron, and the R-T-B based permanent magnet includes a light rare earth element and a heavy rare earth element as R. The R-T-B based permanent magnet further includes Al, Ga, and Zr. With respect to 100 mass % of the R-T-B based permanent magnet, a total content of R is 28.50 mass % to 30.25 mass % (not including 28.50 mass %), B content is 0.93 mass % to 0.98 mass %, Al content is 0.03 mass % to 0.19 mass %, Ga content is 0.03 mass % to 0.15 mass %, and Zr content is 0.30 mass % to 0.50 mass %.
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公开(公告)号:US20180301256A1
公开(公告)日:2018-10-18
申请号:US15939719
申请日:2018-03-29
Applicant: TDK CORPORATION
Inventor: Yoshinori FUJIKAWA , Masashi MIWA
CPC classification number: H01F1/0577 , C22C38/002 , C22C38/005 , C22C38/06 , C22C38/10 , C22C38/14 , C22C38/16 , C22C2202/02 , H01F41/0266 , H01F41/0293
Abstract: An R-T-B based sintered magnet including main phase particles having an R2T14B type crystal structure. R is at least one rare earth element essentially including a heavy rare-earth element RH. T is at least one transition metal element essentially including Fe or Fe and Co. B is boron. At least one of the main phase particles includes low RH crystal phases inside the main phase particle. The low RH crystal phases include the R2T14B type crystal structure, wherein an RH concentration in the low RH crystal phases is relatively lower than the RH concentration in the whole main phase particles. The R-T-B based sintered magnet may satisfy rs−rc≥20% when an existence ratio of the main phase particles including the low RH crystal phases in a magnet surface layer part is rs (%) and the same in a magnet central part is rc (%).
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公开(公告)号:US20160196904A1
公开(公告)日:2016-07-07
申请号:US14909606
申请日:2014-08-08
Applicant: TDK CORPORATION
Inventor: Isao KANADA , Hiroyuki ONO , Eiji KATO , Masashi MIWA
CPC classification number: H01F1/0551 , B22F2998/10 , B22F2999/00 , C22C38/00 , C22C38/002 , C22C38/005 , C22C38/008 , C22C38/02 , C22C38/06 , C22C38/10 , C22C38/14 , C22C38/16 , C22C2202/02 , H01F1/0577 , B22F9/023 , B22F9/04 , B22F3/087 , B22F3/1007 , B22F3/1028 , B22F2201/20 , B22F2202/05
Abstract: The present invention provides an R-T-B based sintered magnet that inhibits the demagnetization rate at high temperature even when less or no heavy rare earth elements such as Dy, Tb and the like are used. The R-T-B based sintered magnet includes R2T14B crystal grains and two-grain boundary parts between the R2T14B crystal grains. Two-grain boundary parts formed by R—Co—Cu-M-Fe phase exist, and M is at least one selected from the group consisting of Ga, Si, Sn, Ge and Bi.
Abstract translation: 本发明提供一种即使在使用较少或不重稀土元素如Dy,Tb等的情况下也能抑制高温退磁速度的R-T-B系烧结磁体。 R-T-B系烧结磁体包括R2T14B晶粒和R2T14B晶粒之间的双晶界面部分。 存在由R-Co-Cu-M-Fe相形成的两晶界部分,M为选自Ga,Si,Sn,Ge和Bi中的至少一种。
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公开(公告)号:US20200303102A1
公开(公告)日:2020-09-24
申请号:US16819071
申请日:2020-03-14
Applicant: TDK Corporation
Inventor: Masashi MIWA
Abstract: A permanent magnet 2 includes Nd, Fe, and B, the permanent magnet 2 contains a plurality of main phase grains; and grain boundaries positioned between the main phase grains, the main phase grains include Nd, Fe, and B, at least a portion of the grain boundaries contains an R′—O—C phase, the R′—O—C phase includes a rare earth element R′, O, and C, the concentration of each of R′, O, and C in the R′—O—C phase is higher compared to the main phase grains, the permanent magnet 2 comprises a surface layer portion 21 and a central portion 22, the surface layer portion 21 is positioned on the surface side of the permanent magnet 2, the central portion 22 is positioned on the inner side of the permanent magnet 2, the proportion of the area of the R′—O—C phase occupying in a cross-section of the surface layer portion 21 is S1 %, the proportion of the area of the R′—O—C phase occupying in a cross-section of the central portion 22 is S2%, and S1 is higher than S2.
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公开(公告)号:US20170278602A1
公开(公告)日:2017-09-28
申请号:US15440667
申请日:2017-02-23
Applicant: TDK CORPORATION
Inventor: Takurou IWASA , Masashi MIWA
IPC: H01F1/053 , C22C38/16 , C22C38/14 , C22C38/10 , C21D3/06 , C22C38/00 , B22F9/04 , B22F3/12 , B22F5/00 , H01F1/06 , C22C38/06
Abstract: An R-T-B based permanent magnet includes R-T-B based compounds as main-phase crystal grains. R is a rare earth element. T is iron group element(s) essentially including Fe or Fe and Co. B is boron. A two-grain boundary is contained between the two adjacent main-phase crystal grains. An average grain size of the main-phase crystal grains is 0.9 μm or more and 2.8 μm or less. A thickness of the two-grain boundary is 5 nm or more and 200 nm or less.
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公开(公告)号:US20160180993A1
公开(公告)日:2016-06-23
申请号:US14909563
申请日:2014-08-08
Applicant: TDK CORPORATION
Inventor: Isao KANADA , Hiroyuki ONO , Eiji KATO , Masashi MIWA
CPC classification number: H01F1/0577 , B22F2998/10 , B22F2999/00 , C22C38/00 , C22C38/002 , C22C38/005 , C22C38/06 , C22C38/10 , C22C38/16 , C22C2202/02 , H01F1/0551 , H01F41/0293 , H02K1/02 , B22F3/087 , B22F2202/05 , B22F9/023 , B22F9/04 , B22F3/1007 , B22F3/1028 , B22F2201/20
Abstract: The present invention provides an R-T-B based sintered magnet that inhibits the demagnetization rate at high temperature even when less or no heavy rare earth elements such as Dy, Tb and the like are used. The R-T-B based sintered magnet comprises R2T14B crystal grains and two-grain boundary parts between the R2T14B crystal grains. Two-grain boundary parts formed by a phase containing R, Cu, Co, Ga and Fe with a ratio of 40≦R≦70, 1≦Co≦10, 5≦Cu≦50, 1≦Ga≦15, and 1≦Fe≦40 (wherein, R+Cu+Co+Ga+Fe=100, and R is at least one selected from rare earth elements) exists in the magnet.
Abstract translation: 本发明提供一种即使在使用较少或不重稀土元素如Dy,Tb等的情况下也能抑制高温退磁速度的R-T-B系烧结磁体。 R-T-B系烧结磁体包括R2T14B晶粒和R2T14B晶粒之间的两晶界面部分。 由含有R,Cu,Co,Ga和Fe的相组成的具有40和nlE的相的两晶边界部分; R< E; 70,1& NlE; Co&NlE; 10,5& N; Cu&NlE; 50,1和nlE; Ga和nlE; 15和1& Fe(n); 40(其中,R + Cu + Co + Ga + Fe = 100,R为选自稀土元素中的至少一种)。
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公开(公告)号:US20210304929A1
公开(公告)日:2021-09-30
申请号:US17202424
申请日:2021-03-16
Applicant: TDK Corporation
Inventor: Masashi MIWA , Yoshitomo TANAKA , Koji MIURA , Taeko TSUBOKURA
Abstract: Provided is a permanent magnet including a rare-earth element R (such as Nd), a transition metal element T (such as Fe), B, Zr, and Cu. The permanent magnet contains a plurality of main phase grains including Nd, T, and B, and grain boundary multiple junctions, the one grain boundary multiple junction is a grain boundary surrounded by three or more of the main phase grains, one of the grain boundary multiple junctions contains a ZrB2 crystal and an R—Cu-rich phase including R and Cu, Fe is contained in the ZrB2 crystal, a total concentration of Nd and Pr in the one grain boundary multiple junction containing both the ZrB2 crystal and the R—Cu-rich phase is higher than a total concentration of Nd and Pr in the main phase grain, a concentration of Cu in the one grain boundary multiple junction containing both the ZrB2 crystal and the R—Cu-rich phase is higher than a concentration of Cu in the main phase grain, and a unit of the concentration of each of Nd, Pr, and Cu is atomic %.
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公开(公告)号:US20190304638A1
公开(公告)日:2019-10-03
申请号:US16367650
申请日:2019-03-28
Applicant: TDK CORPORATION
Inventor: Yuki NAGAMINE , Masashi MIWA , Yoshinori FUJIKAWA
Abstract: An R-T-B based permanent magnet excellent in magnetic properties relatively reduces the amount of a heavy rare earth element used. An R-T-B based permanent magnet, wherein R represents a rare earth element, T an iron group element and B boron, includes main phase grains including an R2T14B crystal phase and grain boundaries formed between main phase grains. Grain boundaries include R-O-C-N concentrated parts where concentrations of R, O, C and N are all higher than those in main phase grains. C/R(S)>C/R(C) is satisfied in which C/R(S) represents a C/R ratio (atomic ratio) in R-O-C-N concentrated parts present in a surface of a R-T-B based permanent magnet and C/R(C) represents a C/R ratio (atomic ratio) in the R-O-C-N concentrated parts present in the center of a R-T-B based permanent magnet, and a heavy rare earth element RH is included in the R-T-B based permanent magnet.
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公开(公告)号:US20180286545A1
公开(公告)日:2018-10-04
申请号:US15939778
申请日:2018-03-29
Applicant: TDK CORPORATION
Inventor: Yoshinori FUJIKAWA , Masashi MIWA
CPC classification number: H01F1/0577 , C22C38/005 , H01F41/0293
Abstract: An R-T-B based sintered magnet including a plural number of main phase particles having an R2T14B type crystal structure. R is at least one rare earth element essentially including heavy rare earth elements RH, T is at least one transition metal element essentially including Fe or Fe and Co, and B is boron. At least one of the main phase particles is a reverse core-shell main phase particle including a core part and a shell part, in which CRC/CRS>1.0 is satisfied when a total RH concentration (at %) in the core part is defined as CRC and a total RH concentration (at %) in the shell part is defined as CRS. An existence ratio of the reverse core-shell main phase particles is larger in a surface layer part of the magnet than in a central part of the magnet.
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