公开(公告)号：US20160199828A1

公开(公告)日：2016-07-14

申请号：US15074979

申请日：2016-03-18

Applicant: THE CLOROX COMPANY

Inventor： DAVID R. SCHEUING ,  THOMAS F. FAHLEN ,  JARED HEYMANN ,  MIKE KINSINGER ,  WILLIAM OUELLETTE ,  WILLIAM L. SMITH

IPC: B01J45/00

CPC classification number: C09D147/00 ,  A01N25/10 ,  A01N33/12 ,  A01N59/00 ,  B01J45/00 ,  C09D5/14 ,  C09D5/1662 ,  C09D7/001 ,  C09D7/002 ,  C09D7/20 ,  C09D7/43 ,  C09D133/00 ,  C09D133/02 ,  C09D139/00 ,  C11D3/0036 ,  C11D3/227 ,  C11D3/3723 ,  C11D3/3757 ,  C11D3/3765 ,  C11D3/3769 ,  C11D3/3773 ,  C11D3/3776 ,  C11D3/378 ,  C11D3/3942 ,  C11D3/3947 ,  C11D3/3953 ,  C11D3/3956 ,  C11D3/48

Abstract: The invention relates to compositions and methods of treatment employing compositions comprising polyelectrolyte complexes. The compositions include a water-soluble first polyelectrolyte bearing a net cationic charge or capable of developing a net cationic charge and a water-soluble second polyelectrolyte bearing a net anionic charge or capable of developing a net anionic charge. The total polyelectrolyte concentration of the first solution is at least 110 millimolar. The composition is free of coacervates, precipitates, latex particles, synthetic block copolymers, silicone copolymers, cross-linked poly(acrylic) and cross-linked water-soluble polyelectrolyte. The composition may be a concentrate, to be diluted prior to use to treat a surface.

公开(公告)号：US20170137760A1

公开(公告)日：2017-05-18

申请号：US15421065

申请日：2017-01-31

Applicant: THE CLOROX COMPANY

Inventor： DAVID R. SCHEUING ,  WILLIAM L. SMITH ,  MICHAEL KINSINGER ,  JARED HEYMANN

IPC: C11D17/04 ,  A01N43/16 ,  A01N43/36 ,  B08B1/00 ,  A01N59/16 ,  C11D3/37 ,  C11D3/48 ,  A01N37/02 ,  A01N33/12

CPC classification number: C11D17/049 ,  A01N33/12 ,  A01N37/02 ,  A01N43/16 ,  A01N43/36 ,  A01N59/00 ,  A01N59/16 ,  A61L15/10 ,  A61L15/46 ,  B08B1/006 ,  C07B57/00 ,  C11D3/3723 ,  C11D3/3757 ,  C11D3/3776 ,  C11D3/378 ,  C11D3/48 ,  A01N25/10 ,  A01N25/22 ,  A01N25/24

Abstract: The present invention relates to aqueous compositions of associative polyelectrolyte complexes (PECs), optionally containing surfactants, biocidal agents and/or oxidants, which can provide a cleaning benefit and surface protection to treated articles including reduced soiling tendency, reduced cleaning effort and improved soil repellancy, as well as providing bacteriostatic properties to treated surfaces that thereby gain resistance to water, environmental exposure and microbial challenge. Treatment means and compositions are provided that employ associative polyelectrolyte complexes formed by combining a water soluble cationic first polyelectrolyte with a water soluble second polyelectrolyte bearing groups of opposite charge to the first polyelectrolyte under suitable mixing conditions and at least one oxidant selected from the group: alkaline metal salts and/or alkaline earth metal salts of hypochlorous acid, hypochlorous acid, solubilized chlorine, any source of free chlorine, acidic sodium chlorite, active chlorine generating compound and any combinations or mixtures thereof. Also provided are means to form stable associative polyelectrolyte complexes with at least one oxidant in aqueous solutions having R values from about 0.10 to 20.

公开(公告)号：US20150184113A1

公开(公告)日：2015-07-02

申请号：US14659021

申请日：2015-03-16

Applicant: THE CLOROX COMPANY

Inventor： DAVID R. SCHEUING ,  ARUN AGARWAL ,  DAVID E. DABNEY ,  GREGORY P. DADO ,  LAFAYETTE D. FOLAND ,  SHUMAN MITRA ,  JACQUELINE M. PYTEL ,  WILLIAM L. SMITH ,  ERIKA SZEKERES ,  MICHAEL R. TERRY ,  KENNETH L. VIEIRA

IPC: C11D3/395 ,  C11D3/34

CPC classification number: C11D3/3953 ,  C11D3/34 ,  C11D3/3418 ,  C11D3/3951 ,  C11D3/3956

Abstract: The invention relates to compositions including a hypohalite or hypochlorous acid and a soluble salt of 2,4,6 mesitylene sulfonate. The compositions may include a surfactant, a buffer, or combinations thereof. Other adjuvants may also be present. Such compositions do not require the inclusion of high concentrations of sodium hydroxide or other soluble hydroxide salts to drastically increase pH (and thus stability), although such hydroxides may be present if desired.

Abstract translation: 本发明涉及包含次卤酸盐或次氯酸和2,4,6-三甲苯磺酸盐的可溶性盐的组合物。 组合物可以包括表面活性剂，缓冲剂或其组合。 也可以存在其它佐剂。 这样的组合物不需要包含高浓度的氢氧化钠或其它可溶性氢氧化物盐，以显着增加pH（因而稳定性），尽管如果需要可存在这种氢氧化物。

公开(公告)号：US20190330490A1

公开(公告)日：2019-10-31

申请号：US16506124

申请日：2019-07-09

Applicant: THE CLOROX COMPANY

Inventor： DAVID R. SCHEUING ,  DAVID J. LESTAGE ,  CARL W. BENNETT ,  MONA M. KNOCK ,  CHARLES W. SCALES ,  WILLIAM L. SMITH ,  RUI ZHANG

IPC: C09D133/02 ,  A01N59/16 ,  A01N25/10 ,  A01N33/12 ,  C09D5/14 ,  A01N59/00

Abstract: The present invention relates to aqueous compositions of associative polyelectrolyte complexes (PECs), optionally containing surfactants, biocidal agents and/or oxidants, which can provide surface protection to treated articles including reduced soiling tendency, reduced cleaning effort and improved soil repellancy, as well as providing bacteriostatic properties to treated surfaces that thereby gain resistance to water, environmental exposure and microbial challenge. Treatment means and compositions are provided that employ associative polyelectrolyte complexes formed by combining a water soluble cationic first polyelectrolyte with a water soluble second polyelectrolyte bearing groups of opposite charge to the first polyelectrolyte under suitable mixing conditions where the one polyelectrolyte present in molar excess is added in the form of a first aqueous solution during a mixing step to a second aqueous solution comprising the oppositely charged polyelectrolyte present in molar deficiency. Also provided are means to form stable associative polyelectrolyte complexes in aqueous solutions having R values from about 0.10 to 20, including near stoichiometric R values approaching 1, being the ratio of charged groups present on the component polyelectrolytes employed.

公开(公告)号：US20170022457A1

公开(公告)日：2017-01-26

申请号：US15285428

申请日：2016-10-04

Applicant: THE CLOROX COMPANY

Inventor： DAVID R. SCHEUING ,  THOMAS F. FAHLEN ,  JARED HEYMANN ,  MIKE KINSINGER ,  WILLIAM OUELLETTE ,  WILLIAM L. SMITH

IPC: C11D3/48 ,  C09D7/00 ,  C11D3/37 ,  A01N25/10 ,  B01J45/00 ,  C09D147/00 ,  C09D5/16 ,  C09D133/02 ,  C09D5/14 ,  C11D3/00

CPC classification number: C09D147/00 ,  A01N25/10 ,  A01N33/12 ,  A01N59/00 ,  B01J45/00 ,  C09D5/14 ,  C09D5/1662 ,  C09D7/001 ,  C09D7/002 ,  C09D7/20 ,  C09D7/43 ,  C09D133/00 ,  C09D133/02 ,  C09D139/00 ,  C11D3/0036 ,  C11D3/227 ,  C11D3/3723 ,  C11D3/3757 ,  C11D3/3765 ,  C11D3/3769 ,  C11D3/3773 ,  C11D3/3776 ,  C11D3/378 ,  C11D3/3942 ,  C11D3/3947 ,  C11D3/3953 ,  C11D3/3956 ,  C11D3/48

Abstract: The invention relates to compositions and methods of treatment employing compositions comprising polyelectrolyte complexes. The compositions include a water-soluble first polyelectrolyte bearing a net cationic charge or capable of developing a net cationic charge and a water-soluble second polyelectrolyte bearing a net anionic charge or capable of developing a net anionic charge. The total polyelectrolyte concentration of the first solution is at least 110 millimolar. The composition is free of coacervates, precipitates, latex particles, synthetic block copolymers, silicone copolymers, cross-linked poly(acrylic) and cross-linked water-soluble polyelectrolyte. The composition may be a concentrate, to be diluted prior to use to treat a surface.

Abstract translation: 本发明涉及使用包含聚电解质复合物的组合物的组合物和方法。 组合物包括具有净阳离子电荷或能够显影净阳离子电荷的水溶性第一聚电解质和带有净阴离子电荷或能够产生净阴离子电荷的水溶性第二聚电解质。 第一溶液的总聚电解质浓度至少为110毫摩尔。 该组合物不含凝聚层，沉淀物，胶乳颗粒，合成嵌段共聚物，硅氧烷共聚物，交联聚（丙烯酸）和交联的水溶性聚电解质。 组合物可以是在使用前稀释以处理表面的浓缩物。

公开(公告)号：US20170002304A1

公开(公告)日：2017-01-05

申请号：US15269085

申请日：2016-09-19

Applicant: THE CLOROX COMPANY

Inventor： DAVID R. SCHEUING ,  WILLIAM L. SMITH ,  MICHAEL KINSINGER ,  JARED HEYMANN

IPC: C11D17/04 ,  C11D3/37 ,  B08B1/00 ,  C11D3/48

CPC classification number: C11D17/049 ,  A01N33/12 ,  A01N37/02 ,  A01N43/16 ,  A01N43/36 ,  A01N59/00 ,  A01N59/16 ,  A61L15/10 ,  A61L15/46 ,  B08B1/006 ,  C07B57/00 ,  C11D3/3723 ,  C11D3/3757 ,  C11D3/3776 ,  C11D3/378 ,  C11D3/48 ,  A01N25/10 ,  A01N25/22 ,  A01N25/24

Abstract: The present invention relates to aqueous compositions of associative polyelectrolyte complexes (PECs), optionally containing surfactants, biocidal agents and/or oxidants, which can provide a cleaning benefit and surface protection to treated articles including reduced soiling tendency, reduced cleaning effort and improved soil repellancy, as well as providing bacteriostatic properties to treated surfaces that thereby gain resistance to water, environmental exposure and microbial challenge. Treatment means and compositions are provided that employ associative polyelectrolyte complexes formed by combining a water soluble cationic first polyelectrolyte with a water soluble second polyelectrolyte bearing groups of opposite charge to the first polyelectrolyte under suitable mixing conditions and at least one oxidant selected from the group: alkaline metal salts and/or alkaline earth metal salts of hypochlorous acid, hypochlorous acid, solubilized chlorine, any source of free chlorine, acidic sodium chlorite, active chlorine generating compound and any combinations or mixtures thereof. Also provided are means to form stable associative polyelectrolyte complexes with at least one oxidant in aqueous solutions having R values from about 0.10 to 20.

Abstract translation: 本发明涉及可选地含有表面活性剂，杀生物剂和/或氧化剂的缔合聚电解质复合物（PEC）的含水组合物，其可以为处理物品提供清洁效果和表面保护，包括减少污染趋势，降低清洁力和改善防污性 ，以及为处理的表面提供抑菌性能，从而获得对水的耐受性，环境暴露和微生物挑战。 提供了处理装置和组合物，其使用通过在适合的混合条件下将水溶性阳离子第一聚电解质与带有相反电荷的水溶性第二聚电解质带入基团的第一聚电解质组合形成的缔合聚电解质复合物和至少一种选自以下的氧化剂：碱 次氯酸，次氯酸，溶解氯，任何游离氯源，酸性亚氯酸钠，活性氯产生化合物的金属盐和/或碱土金属盐及其任何组合或混合物。 还提供了在水溶液中形成具有约0.10至20的R值的至少一种氧化剂的稳定的缔合聚电解质络合物的方法。