摘要:
A catalyst including: a support, the support including a mixture of SiO2 and ZrO2; an active ingredient including copper; a first additive including a metal, an oxide thereof, or a combination thereof; and a second additive including Li, Na, K, or a combination thereof. The metal is Mg, Ca, Ba, Mn, Fe, Co, Zn, Mo, La, or Ce. Based on the total weight of the catalyst, the weight percentages of the different components are as follows: SiO2=50-90 wt. %; ZrO2=0.1-10 wt. %; copper=10-50 wt. %; the first additive=0.1-10 wt. %; and the second additive=0.1-5 wt. %.
摘要:
A copper catalyst for producing ethylene glycol by hydrogenation of an oxalate. The catalyst includes a carrier, an additive, and an active component. The carrier is ceramic or metallic honeycomb. The additive is Al, Si, Ba, Ca, Ti, Zr, Fe, Zn, Mn, V, La, Ce, an oxide thereof, or a mixture thereof. The active component is copper, and the active component and the additive are coated on the carrier to form a coating layer. The additive accounts for 5-90 wt. % of the carrier, the active component accounts for 1-40 wt. % of the carrier, and the copper accounts for 5-50 wt. % of the coating layer.