Abstract:
The main object of the present invention is to provide a sulfide solid electrolyte material with high Li ion conductivity. The present invention solves the problem by providing a sulfide solid electrolyte material comprising an ion conductor with an ortho-composition, and LiI, characterized in that the sulfide solid electrolyte material is glass with a glass transition point.
Abstract:
A sulfide solid electrolyte for use in an all-solid-state battery has a composition represented by (100−x) [yLi2S·(1−y)P2S5]·xLiBH4. In the formula, x is a value satisfying 50
Abstract:
A method of producing a sulfide solid electrolyte material includes: forming an intermediate having crosslinking sulfur but no Li2S, by vitrifying, in a first vitrification process, a starting material composition obtained by mixing Li2S and a sulfide of a group 14 or group 15 element such that a proportion of Li2S with respect to the sum total of the Li2S and the sulfide of a group 14 or group 15 element is smaller than a proportion of Li2S required for the sulfide solid electrolyte material to obtain an ortho composition; and eliminating the crosslinking sulfur by vitrifying, in a second vitrification process, an intermediate-containing composition resulting from mixing a bond cleaving compound, which cleaves a bond of the crosslinking sulfur, with the intermediate.
Abstract:
A main object of the present disclosure is to provide an anode mixture capable of suppressing an increase in resistance. The present disclosure achieves the object by providing an anode mixture used for an all solid state battery, the anode mixture comprising a coated anode active material and a sulfide solid electrolyte, wherein the coated anode active material comprises an anode active material and a coating layer covering at least a portion of the surface of the anode active material, and the coating layer contains a borohydride solid electrolyte containing LiBH4 and LiX, wherein X is selected from Cl, Br and I.
Abstract:
The main object of the present invention is to provide a sulfide solid electrolyte material with less hydrogen sulfide generation amount. The present invention solves the above-mentioned problem by providing a sulfide solid electrolyte material using a raw material composition containing Li2S and sulfide of an element of the group 14 or the group 15 in the periodic table, containing substantially no cross-linking sulfur and Li2S.
Abstract:
The main object of the present invention is to provide a sulfide solid electrolyte material with less hydrogen sulfide generation amount. The present invention solves the above-mentioned problem by providing a sulfide solid electrolyte material using a raw material composition containing Li2S and sulfide of an element of the group 14 or the group 15 in the periodic table, containing substantially no cross-linking sulfur and Li2S.
Abstract translation:本发明的主要目的是提供硫化氢生成量少的硫化物固体电解质材料。 本发明通过提供硫化物固体电解质材料来解决上述问题,所述硫化物固体电解质材料使用含有Li 2 S的原料组合物和周期表中第14族或第15族元素的硫化物,其基本上不含交联硫和Li 2 S 。
Abstract:
A sulfide solid electrolyte material contains glass ceramics that contains Li, A, X, and S, and has peaks at 2θ=20.2° and 23.6° in X-ray diffraction measurement with CuKα line. A is at least one kind of P, Si, Ge, Al, and B, and X is a halogen. A method for producing a sulfide solid electrolyte material includes amorphizing a raw material composition containing Li2S, a sulfide of A, and LiX to synthesize sulfide glass, and heating the sulfide glass at a heat treatment temperature equal to or more than a crystallization temperature thereof to synthesize glass ceramics having peaks at 2θ=20.2° and 23.6° in X-ray diffraction measurement with CuKα line, in which a ratio of the LiX contained in the raw material composition and the heat treatment temperature are controlled to obtain the glass ceramics.