METHOD OF PRODUCING A SULFIDE SOLID ELECTROLYTE MATERIAL, SULFIDE SOLID ELECTROLYTE MATERIAL, AND LITHIUM BATTERY

    公开(公告)号:US20180269521A1

    公开(公告)日:2018-09-20

    申请号:US15984916

    申请日:2018-05-21

    Abstract: A method of producing a sulfide solid electrolyte material includes: forming an intermediate having crosslinking sulfur but no Li2S, by vitrifying, in a first vitrification process, a starting material composition obtained by mixing Li2S and a sulfide of a group 14 or group 15 element such that a proportion of Li2S with respect to the sum total of the Li2S and the sulfide of a group 14 or group 15 element is smaller than a proportion of Li2S required for the sulfide solid electrolyte material to obtain an ortho composition; and eliminating the crosslinking sulfur by vitrifying, in a second vitrification process, an intermediate-containing composition resulting from mixing a bond cleaving compound, which cleaves a bond of the crosslinking sulfur, with the intermediate.

    ANODE MIXTURE, METHOD FOR PRODUCING ANODE MIXTURE AND ALL SOLID STATE BATTERY

    公开(公告)号:US20240421348A1

    公开(公告)日:2024-12-19

    申请号:US18733011

    申请日:2024-06-04

    Abstract: A main object of the present disclosure is to provide an anode mixture capable of suppressing an increase in resistance. The present disclosure achieves the object by providing an anode mixture used for an all solid state battery, the anode mixture comprising a coated anode active material and a sulfide solid electrolyte, wherein the coated anode active material comprises an anode active material and a coating layer covering at least a portion of the surface of the anode active material, and the coating layer contains a borohydride solid electrolyte containing LiBH4 and LiX, wherein X is selected from Cl, Br and I.

    SULFIDE SOLID ELECTROLYTE MATERIAL, LITHIUM SOLID-STATE BATTERY, AND METHOD FOR PRODUCING SULFIDE SOLID ELECTROLYTE MATERIAL
    7.
    发明申请
    SULFIDE SOLID ELECTROLYTE MATERIAL, LITHIUM SOLID-STATE BATTERY, AND METHOD FOR PRODUCING SULFIDE SOLID ELECTROLYTE MATERIAL 审中-公开
    硫化固体电解质材料,锂固体电池,以及用于生产硫化物固体电解质材料的方法

    公开(公告)号:US20150357675A1

    公开(公告)日:2015-12-10

    申请号:US14832194

    申请日:2015-08-21

    Abstract: A sulfide solid electrolyte material contains glass ceramics that contains Li, A, X, and S, and has peaks at 2θ=20.2° and 23.6° in X-ray diffraction measurement with CuKα line. A is at least one kind of P, Si, Ge, Al, and B, and X is a halogen. A method for producing a sulfide solid electrolyte material includes amorphizing a raw material composition containing Li2S, a sulfide of A, and LiX to synthesize sulfide glass, and heating the sulfide glass at a heat treatment temperature equal to or more than a crystallization temperature thereof to synthesize glass ceramics having peaks at 2θ=20.2° and 23.6° in X-ray diffraction measurement with CuKα line, in which a ratio of the LiX contained in the raw material composition and the heat treatment temperature are controlled to obtain the glass ceramics.

    Abstract translation: 硫化物固体电解质材料包含含有Li,A,X和S的玻璃陶瓷,并且在CuKα线的X射线衍射测量中,在2θ处具有峰值= 20.2°和23.6°。 A是至少一种P,Si,Ge,Al和B,X是卤素。 硫化物固体电解质材料的制造方法包括使包含Li 2 S,A的硫化物和LiX的原料组合物非晶化,合成硫化物玻璃,将其加热至等于或高于其结晶温度的热处理温度, 在CuKα线的X射线衍射测定中合成具有2θ的峰值= 20.2°和23.6°的玻璃陶瓷,其中控制原料组成中所含的LiX与热处理温度的比例以获得玻璃陶瓷。

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