Abstract:
A method of manufacturing a nonaqueous secondary battery includes: constructing a battery assembly with a positive electrode, a negative electrode, and a nonaqueous electrolytic solution, the nonaqueous electrolytic solution containing a sulfonic acid compound having a triple bond; activating the battery assembly to decompose a portion of the sulfonic acid compound such that a percentage of the sulfonic acid compound is more than 0 mass % and 0.2 mass % or less with respect to 100 mass % of a total amount of the nonaqueous electrolytic solution; self-discharging the battery assembly to measure a voltage drop amount; and determining whether internal short-circuit occurs in the battery assembly based on the voltage drop amount.
Abstract:
A nonaqueous electrolyte secondary battery includes a wound electrode assembly in which a positive electrode having, at its one end in a width direction, a positive electrode exposed portion provided without a positive electrode mixture layer on a positive electrode current collector and a negative electrode are wound together, with a separator interposed therebetween. The positive electrode exposed portion protrudes outward in an axial direction of the wound electrode assembly relative to the separator and the negative electrode at one end in the axial direction of the wound electrode assembly. The negative electrode exposed portion protrudes outward in the axial direction of the wound electrode assembly relative to the separator and the positive electrode at the other end in the axial direction. The positive electrode exposed portion has a cutout portion at least in an outermost circumferential portion of the positive electrode.
Abstract:
An inspection method of a secondary battery includes a charging step, an aging step, a pre-inspection discharge step, a voltage adjustment step, a self-discharge inspection step, and a deficiency determination step. A discharge condition in the pre-inspection discharge step is determined so that a voltage difference accumulation value Vs satisfies a predetermined range. The voltage difference accumulation value Vs is calculated by accumulating a value obtained by subtracting an output voltage from a predetermined voltage over a duration from start of the pre-inspection discharge step to end thereof.
Abstract:
The main object of the present invention is to provide a sulfide solid electrolyte material with less hydrogen sulfide generation amount. The present invention solves the above-mentioned problem by providing a sulfide solid electrolyte material using a raw material composition containing Li2S and sulfide of an element of the group 14 or the group 15 in the periodic table, containing substantially no cross-linking sulfur and Li2S.
Abstract:
An in-vehicle system includes a first battery and a second battery respectively connected to a first load and a second load, a relay that connects the two batteries in parallel, and a processor configured to control turn-on and turn-off of the relay to control a state of electric power supply from the first and second batteries to the first and second loads, detect an abnormality in the first and second batteries, and determine a difference between physical quantities of the two batteries. The processor is further configured to, when detecting the abnormality in the first or second battery, turn off the relay, and when no longer detecting the abnormality in the first and second batteries after the relay is turned off, turn on the relay when the processor determines that the difference between the physical quantities of the two batteries satisfies a predetermined condition.
Abstract:
A lithium-ion secondary battery (100) includes a wound electrode body (80), a nonaqueous electrolyte, and a box-shaped case (50). The wound electrode body includes a positive electrode (10), a negative electrode (20), and a separator (40). The box-shaped case contains the wound electrode body and the nonaqueous electrolyte. The wound electrode body includes a starting-end-side negative electrode remainder portion (22) provided in a winding-direction starting end portion (81) of the wound electrode body. The winding-direction starting end portion exists at a winding center side. The starting-end-side negative electrode remainder portion protrudes toward the winding center side along a winding direction beyond the positive electrode. A surplus nonaqueous electrolyte exists in a gap between the wound electrode body and the box-shaped case. The starting-end-side negative electrode remainder portion is positioned in a region where the surplus nonaqueous electrolyte exists, when the lithium-ion secondary battery is disposed in a predetermined posture.
Abstract:
A lithium-ion secondary battery (10) includes a wound electrode assembly (40) having a positive electrode current collector foil (51) and a negative electrode current collector foil 61). An edge portion (52) of the positive electrode current collector foil (51) is exposed in a spiral form at one end of a winding axis (WL). An edge portion (62) of the negative electrode current collector foil (61) is exposed in a spiral form at the other end of the winding axis (WL). The spirally exposed edge portion (52) of the positive electrode current collector foil (51) is divided and gathered into a plurality of parts divided at at least one of a plurality of gaps (S), excluding a central portion (WC) containing the winding axis (WL), provided between wound layers of the positive electrode current collector foil (51) stacked in a direction orthogonal to the winding axis (WL). Likewise, the spirally exposed edge portion (62) of the negative electrode current collector foil (61) is divided and gathered into a plurality of parts divided at at least one of a plurality of gaps (S), excluding the central portion (WC) containing the winding axis (WL), provided between wound layers of the negative electrode current collector foil (61) stacked in a direction orthogonal to the winding axis (WL).
Abstract:
A method of manufacturing a nonaqueous secondary battery includes: constructing a battery assembly with a positive electrode, a negative electrode, and a nonaqueous electrolytic solution, the nonaqueous electrolytic solution containing an unsaturated carbonate; activating the battery assembly to decompose a portion of the unsaturated carbonate such that a percentage of the unsaturated carbonate is adjusted to be 0.9 mass % or less with respect to 100 mass % of a total amount of the nonaqueous electrolytic solution; self-discharging the battery assembly to measure a voltage drop amount; and determining whether internal short-circuit occurs in the battery assembly based on the voltage drop amount.
Abstract:
A nonaqueous electrolyte secondary battery includes a wound electrode body, and the wound electrode body includes two curved portions and a center flat portion which has flat surfaces. A positive electrode winding end, a negative electrode winding end, and separator winding ends are positioned on the same curved portion. The negative electrode winding end is arranged at an advanced position from the positive electrode winding end in a winding direction, and at least one of the separator winding ends is positioned at an advanced position from the negative electrode winding end in the winding direction. A distance a (mm) from the negative electrode winding end to the separator winding end and a distance b (mm) from the positive electrode winding end to the negative electrode winding end satisfy relationships 0.5≦a×(a+b)≦104 and 0≦b≦11.
Abstract:
A manufacturing method for a non-aqueous secondary battery includes the following steps. (a) Preparing an electrode body including a positive electrode having a positive electrode active material layer and a negative electrode having a negative electrode active material layer. (b) Constructing a battery assembly using the electrode body and a non-aqueous electrolyte. (c) Initially charging the battery assembly. (d) Aging the battery assembly at a temperature of 60° C. or higher. (e) Forcibly starting to discharge the battery assembly in said temperature region after lowering the temperature of the battery assembly down to a temperature region of 35° C. or higher and 55° C. or lower. (f) Adjusting the SOC of the battery assembly. (g) Measuring a voltage drop amount by self-discharging the battery assembly. And (h) determining whether or not the battery assembly is qualified based on the voltage drop amount.