公开(公告)号：US4751308A

公开(公告)日：1988-06-14

申请号：US9802

申请日：1987-02-02

申请人： Takashi Abe ,  Eiji Hayashi ,  Hiroshige Muramatsu ,  Hiroshi Okazaki ,  Mahito Soeda

发明人： Takashi Abe ,  Eiji Hayashi ,  Hiroshige Muramatsu ,  Hiroshi Okazaki ,  Mahito Soeda

IPC分类号： C07D209/48 ,  C07D209/46 ,  C07D217/24 ,  C07D221/04 ,  C07D221/02 ,  C07D209/02 ,  C07D209/34

CPC分类号： C07D221/04 ,  C07D217/24

摘要： Perfluorobicyclolactam compounds represented by the general formula: ##STR1## wherein --A-- stands for ##STR2## l, m, and n respectively stand for 0 or 1, 3 or 4, and 1 or 2, and R.sub.f stands for a lower perfluoroalkyl group, are novel compounds. These compounds are useful as intermediates for the synthesis of, e.g., functional macromolecular membranes and lubricants. These compounds are produced by subjecting compounds of the general formula: ##STR3## and fuming sulfuric acid to a thermal reaction.

摘要翻译： 由以下通式表示的全氟双环内酰胺化合物：其中-A-代表分别代表0或1,3或4和1或2，Rf代表 对于较低全氟烷基，是新的化合物。 这些化合物可用作合成例如功能性大分子膜和润滑剂的中间体。 这些化合物是通过将下列通式化合物进行热反应制备的：通过下式得到的化合物：＆lt; IMAGE＆gt;和发烟硫酸。

公开(公告)号：US5380844A

公开(公告)日：1995-01-10

申请号：US231489

申请日：1994-04-22

申请人： Haruhiko Fukaya ,  Takashi Abe ,  Eiji Hayashi ,  Yoshio Hayakawa

发明人： Haruhiko Fukaya ,  Takashi Abe ,  Eiji Hayashi ,  Yoshio Hayakawa

IPC分类号： C07D207/10 ,  C07C407/00 ,  C07C409/40 ,  C07D211/36 ,  C07D211/38 ,  C07D241/04 ,  C07D263/04 ,  C07D265/30 ,  C07D295/00 ,  C08K5/34 ,  C08K5/35 ,  C07D211/30

CPC分类号： C07D263/04 ,  C07D265/30 ,  C08K5/34 ,  C08K5/35

摘要： A nitrogen-containing perfluoroalkanoyl peroxide is provided which is represented by the formula: ##STR1## wherein Rf.sub.1 and Rf.sub.2 independently stand for an alkyl group of 1 to 5 carbon atoms, provided that Rf.sub.1 and Rf.sub.2 are joined to each other in one of the three patterns of union, 1) direct union, 2) union through the medium of an oxygen atom or 3) union through the medium of a nitrogen atom to form one of the three rings, i.e. five-membered ring, six-membered ring or seven-membered ring. The nitrogen-containing perfluoroalkanoyl peroxide is produced by a method which comprises oxidizing a compound represented by the following formula: ##STR2##

公开(公告)号：US5609787A

公开(公告)日：1997-03-11

申请号：US341068

申请日：1994-11-17

申请人： Takashi Abe ,  Haruhiko Fukaya ,  Eiji Hayashi ,  Yoshio Hayakawa

发明人： Takashi Abe ,  Haruhiko Fukaya ,  Eiji Hayashi ,  Yoshio Hayakawa

IPC分类号： A62D1/06 ,  A62D1/00 ,  A62D1/02

CPC分类号： A62D1/0085 ,  A62D1/0092

摘要： A method for extinguishing fire uses a gaseous fire-extinguishing agent having as an active component thereof a polyfluoro-tertiary amine represented by the following formula:(CF.sub.3).sub.2 NRfwherein Rf stands for a polyfluoroalkyl group of 1-4 carbon atoms or a polyfluoroalkenyl group of 1-4 carbon atoms.

摘要翻译： 灭火方法使用具有下式的多氟叔胺作为活性成分的气态灭火剂：（CF 3）2 NR f其中Rf代表1-4个碳原子的多氟烷基或多氟烯基 1-4个碳原子。

公开(公告)号：US5208339A

公开(公告)日：1993-05-04

申请号：US941884

申请日：1992-09-08

申请人： Haruhiko Fukaya ,  Takashi Abe ,  Eiji Hayashi ,  Yoshio Hayakawa

发明人： Haruhiko Fukaya ,  Takashi Abe ,  Eiji Hayashi ,  Yoshio Hayakawa

IPC分类号： C07D207/10 ,  C07C407/00 ,  C07C409/40 ,  C07D211/36 ,  C07D211/38 ,  C07D241/04 ,  C07D263/04 ,  C07D265/30 ,  C07D295/00 ,  C08K5/34 ,  C08K5/35

CPC分类号： C07D263/04 ,  C07D265/30 ,  C08K5/34 ,  C08K5/35

摘要： A nitrogen-containing perfluoroalkanoyl peroxide is provided which is represented by the formula: ##STR1## wherein Rf.sub.1 and Rf.sub.2 independently stand for an alkyl group of 1 to 5 carbon atoms, provided that Rf.sub.1 and Rf.sub.2 are joined to each other in one of the three patterns of union, 1) direct union, 2) union through the medium of an oxygen atom or 3) union through the medium of a nitrogen atom to form one of the three rings, i.e. five-membered ring, six-membered ring or seven-membered ring. The nitrogen-containing perfluoroalkanoyl peroxide is produced by a method which comprises oxidizing a compound represented by the following formula: ##STR2##

摘要翻译： 提供含氮全氟烷酰基过氧化物，其由下式表示：其中Rf1和Rf2独立地代表1至5个碳原子的烷基，条件是Rf1和Rf2在三种之一中彼此连接 联合模式，1）直接联合，2）通过氧原子的介质结合，或3）通过氮原子的介质结合形成三个环之一，即五元环，六元环或七 记忆戒指 含氮全氟烷酰基过氧化物是通过包括氧化由下式表示的化合物的方法制备的：＆lt; IMAGE＆gt;

公开(公告)号：US5117055A

公开(公告)日：1992-05-26

申请号：US482969

申请日：1990-02-22

申请人： Takashi Abe ,  Eiji Hayashi ,  Haruhiko Fukaya

发明人： Takashi Abe ,  Eiji Hayashi ,  Haruhiko Fukaya

IPC分类号： C07C51/58

CPC分类号： C07C51/58

摘要： A perfluoroalkyl halogenide represented by the formula: ##STR1## wherein X stands for one element selected from the group consisting of iodine and bromine, R.sub.f for a perfluorohydrocarbon group, n for an integer in the range of 1 to 3, and m for an integer in the range of 1 to 3, provided that n and m satisfy the relationship, n.gtoreq.m, is produced by a method which consists essentially in subjecting a perfluorocarboxylic acid fluoride represented by the formula, ##STR2## wherein R.sub.f and n have the same meanings as defined above, to a thermal reaction with a lithium halogenide represented by XI, wherein X has the same meaning as defined above.

摘要翻译： 由下式表示的全氟烷基卤化物：其中X代表选自碘和溴的一种元素，全氟烃基的Rf，1至3的整数n，整数m 在1〜3的范围内，只要n和m满足关系，则通过基本上由下式构成的方法来生成：其中Rf和n具有式（1）所示的全氟羧酸氟化物 与由上述定义相同的含义与由XI表示的卤化锂的热反应，其中X具有与上述相同的含义。

公开(公告)号：US5486275A

公开(公告)日：1996-01-23

申请号：US293963

申请日：1994-08-24

申请人： Haruhiko Fukaya ,  Takashi Abe ,  Eiji Hayashi ,  Yoshio Hayakawa ,  Hajime Baba

发明人： Haruhiko Fukaya ,  Takashi Abe ,  Eiji Hayashi ,  Yoshio Hayakawa ,  Hajime Baba

IPC分类号： A61K49/04 ,  A62D1/08 ,  C07B39/00 ,  C07C209/60 ,  C07C209/80 ,  C07C211/15 ,  C07D207/10 ,  C07D211/38 ,  C07D223/04 ,  C07D223/06 ,  C07D227/06 ,  C07D241/04 ,  C07D265/30 ,  C09K21/10 ,  C10M133/06 ,  C10M133/38 ,  C10N20/00 ,  C10N40/14 ,  C10N40/16 ,  C07C2/00

CPC分类号： C07C209/60 ,  C07D265/30

摘要： A nitrogen-containing perfluoroalkyl bromide, a novel compound to the art, is represented by the formula, ##STR1## wherein Rf.sub.1 and Rf.sub.2 independently stand for a perfluoroalkyl group of one to five carbon atoms, provided that Rf.sub.1 and Rf.sub.2 are 1) separated from each other, 2) directly bonded to each other, 3) bonded to each other through the medium of an oxygen atom, or 4) bonded to each other through the medium of a nitrogen atom. This novel compound is produced by decarbonylating a nitrogen-containing perfluorocarboxylic acid bromide represented by the formula, ##STR2## by exposure to an ultraviolet light.

摘要翻译： 含氮全氟烷基溴是本领域新颖的化合物，由下式表示，其中Rf1和Rf2独立地表示1-5个碳原子的全氟烷基，条件是Rf1和Rf2分别为1） 彼此直接接合，3）通过氧原子的介质彼此键合，或4）通过氮原子的介质彼此键合。 该新型化合物是通过曝光于紫外光下，由式“IMAGE”表示的含氮全氟羧酸溴化物进行脱碳酸化而制得的。

公开(公告)号：US5347002A

公开(公告)日：1994-09-13

申请号：US78817

申请日：1993-06-21

申请人： Haruhiko Fukaya ,  Takashi Abe ,  Eiji Hayashi ,  Yoshio Hayakawa

发明人： Haruhiko Fukaya ,  Takashi Abe ,  Eiji Hayashi ,  Yoshio Hayakawa

IPC分类号： C07D207/10 ,  C07C407/00 ,  C07C409/40 ,  C07D211/36 ,  C07D211/38 ,  C07D241/04 ,  C07D263/04 ,  C07D265/30 ,  C07D295/00 ,  C08K5/34 ,  C08K5/35 ,  C07D207/04 ,  C07D405/12

CPC分类号： C07D263/04 ,  C07D265/30 ,  C08K5/34 ,  C08K5/35

摘要： A nitrogen-containing perfluoroalkanoyl peroxide is provided which is represented by the formula: ##STR1## wherein Rf.sub.1 and Rf.sub.2 independently stand for an alkyl group of 1 to 5 carbon atoms, provided that Rf.sub.1 and Rf.sub.2 are joined to each other in one of the three patterns of union, 1) direct union, 2) union through the medium of an oxygen atom or 3) union through the medium of a nitrogen atom to form one of the three rings, i.e. five-membered ring, six-membered ring or seven-membered ring. The nitrogen-containing perfluoroalkanoyl peroxide is produced by a method which comprises oxidizing a compound represented by the following formula: ##STR2##

摘要翻译： 提供含氮全氟烷酰基过氧化物，其由下式表示：其中Rf1和Rf2独立地代表1至5个碳原子的烷基，条件是Rf1和Rf2在三种之一中彼此连接 联合模式，1）直接联合，2）通过氧原子的介质结合，或3）通过氮原子的介质结合形成三个环之一，即五元环，六元环或七 记忆戒指 含氮全氟烷酰基过氧化物是通过包括氧化由下式表示的化合物的方法制备的：＆lt; IMAGE＆gt;

公开(公告)号：US4985556A

公开(公告)日：1991-01-15

申请号：US242308

申请日：1988-09-09

申请人： Takashi Abe ,  Eiji Hayashi

发明人： Takashi Abe ,  Eiji Hayashi

IPC分类号： C07C211/24 ,  C07C229/20 ,  C07D207/10 ,  C07D211/38 ,  C07D223/04 ,  C07D265/30

CPC分类号： C07D265/30 ,  C07C211/24 ,  C07C229/20 ,  C07D207/10 ,  C07D211/38 ,  C07D223/04

摘要： Perfluorocarboxylic acid fluorides represented by the formula A-B, wherein A is either ##STR1## and B stands for a perfluoro-di-substituted amino group, and perfluoro(dialkylaminopropenes) represented by the formula A"-B", wherein A" stands for ##STR2## and B" has the same meaning as B defined above, are novel compounds. Methods for the production of these novel compounds are also disclosed.

摘要翻译： 由式AB表示的全氟羧酸氟化物，其中A是A和B代表全氟二取代氨基，和由式A“-B”表示的全氟（二烷基氨基丙烯），其中A“ 代表和B“具有与上述B相同的含义，是新化合物。 还公开了生产这些新化合物的方法。

公开(公告)号：US4469879A

公开(公告)日：1984-09-04

申请号：US458038

申请日：1983-01-14

申请人： Takashi Abe ,  Hajime Baba ,  Eiji Hayashi ,  Shunji Nagase

发明人： Takashi Abe ,  Hajime Baba ,  Eiji Hayashi ,  Shunji Nagase

IPC分类号： C07D307/82 ,  C07D307/935

CPC分类号： C07D307/82 ,  C07D307/935

摘要： Trichloropolyfluoro-bicyclo ethers are novel compounds, useful as a solvent or thermal medium for various pharmaceutical chemicals. They are produced by the reaction of perfluoro-bicyclo ether with anhydrous aluminum chloride.

摘要翻译： 三氯多氟双环醚是可用作各种药物化学品的溶剂或热介质的新化合物。 它们通过全氟二环醚与无水氯化铝的反应产生。

公开(公告)号：US5476934A

公开(公告)日：1995-12-19

申请号：US294353

申请日：1994-08-23

申请人： Haruhiko Fukaya ,  Takashi Abe ,  Eiji Hayashi ,  Yoshio Hayakawa

发明人： Haruhiko Fukaya ,  Takashi Abe ,  Eiji Hayashi ,  Yoshio Hayakawa

IPC分类号： C07D207/10 ,  C07C407/00 ,  C07C409/40 ,  C07D211/36 ,  C07D211/38 ,  C07D241/04 ,  C07D263/04 ,  C07D265/30 ,  C07D295/00 ,  C08K5/34 ,  C08K5/35 ,  C07D207/04 ,  C07D211/30 ,  C07D405/12

CPC分类号： C07D263/04 ,  C07D265/30 ,  C08K5/34 ,  C08K5/35

摘要： A nitrogen-containing perfluoroalkanoyl peroxide is provided which is represented by the formula: ##STR1## wherein Rf.sub.1 and Rf.sub.2 independently stand for an alkyl group of 1 to 5 carbon atoms, provided that Rf.sub.1 and Rf.sub.2 are joined to each other in one of the three patterns of union, 1) direct union, 2) union through the medium of an oxygen atom or 3) union through the medium of a nitrogen atom to form one of the three rings, i.e. five-membered ring, six-membered ring or seven-membered ring. The nitrogen-containing perfluoroalkanoyl peroxide is produced by a method which comprises oxidizing a compound represented by the following formula: ##STR2##

摘要翻译： 提供含氮全氟烷酰基过氧化物，其由下式表示：其中Rf1和Rf2独立地代表1至5个碳原子的烷基，条件是Rf1和Rf2在三种之一中彼此连接 联合模式，1）直接联合，2）通过氧原子的介质结合，或3）通过氮原子的介质结合形成三个环之一，即五元环，六元环或七 记忆戒指 含氮全氟烷酰基过氧化物是通过包括氧化由下式表示的化合物的方法制备的：＆lt; IMAGE＆gt;