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公开(公告)号：US5449710A
公开(公告)日：1995-09-12
申请号：US239134
申请日：1994-05-06
申请人： Takashi Umeda , Akio Nodera , Kazuto Hashimoto
发明人： Takashi Umeda , Akio Nodera , Kazuto Hashimoto
摘要： There is disclosed a flame retardative polycarbonate resin composition which comprises 100 parts by weight of an aromatic polycarbonate resin (A), 0.01 to 0.5 part by weight of an alkali/or alkaline-earth metal salt of a perfluoroalkanesulfonic acid (B), 0.03 to 5 parts by weight of an organopolysiloxane containing organoxysilyl group bonded to a silicon atom through a divalent hydrocarbon group (C), and optionally 5 to 120 parts by weight of an inorganic filler. The above composition has excellent flame retardancy capable of preventing dripping thereof at the time of combustion of a thin-walled material made from the highly fluidized composition while maintaining the dimensional stability and the mechanical properties such as impact resistance that are inherent in polycarbonate.
摘要翻译： 公开了一种阻燃性聚碳酸酯树脂组合物，其包含100重量份的芳族聚碳酸酯树脂（A），0.01至0.5重量份的全氟烷基磺酸（B）的碱金属或碱土金属盐，0.03至 5重量份含有通过二价烃基（C）与硅原子键合的有机甲硅烷基的有机聚硅氧烷，以及任选的5〜120重量份的无机填料。 上述组合物具有优异的阻燃性，其能够防止在由高度流化的组合物制成的薄壁材料的燃烧时滴落，同时保持聚碳酸酯固有的尺寸稳定性和机械性能如耐冲击性。
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公开(公告)号：US08198366B2
公开(公告)日：2012-06-12
申请号：US11718895
申请日：2005-10-25
申请人： Yusuke Hayata , Akio Nodera
发明人： Yusuke Hayata , Akio Nodera
IPC分类号： C08G63/08 , C08G77/448 , C08L51/06 , C08F283/02 , C08F283/12
CPC分类号： C08L67/08 , C08L33/06 , C08L51/04 , C08L69/00 , C08L77/00 , C08L2201/00 , C08L2666/02
摘要： The present invention provides a thermoplastic resin composition containing (A) a resin mixture including (a-1) a polycarbonate resin in an amount of 45 to 97% by mass and (a-2) a fatty acid polyester in an amount of 55 to 3 % by mass, and (B) a rubber-like elastomer in an amount of 0.5 to 20 parts by mass per 100 parts by mass of the resin mixture, wherein component (B) is dispersed in an interface between ingredient (a-1) and ingredient (a-2) or in domains of ingredient (a-2). The composition has high impact characteristics and high fluidity and overcomes appearance defects such as pearl-like gloss and jetting marks.
摘要翻译： 本发明提供一种热塑性树脂组合物，其含有（A）树脂混合物，所述树脂混合物包含（a-1）45〜97质量％的聚碳酸酯树脂和（a-2）55〜 3质量％，和（B）相对于100质量份树脂混合物为0.5〜20质量份的橡胶状弹性体，其中，成分（B）分散在成分（a-1） ）和成分（a-2）或成分（a-2）的结构域。 该组合物具有高冲击特性和高流动性，并且克服了诸如珍珠样光泽和喷射痕迹的外观缺陷。
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3.发明授权Thermoplastic resin composition, polycarbonate resin composition, and molded article thereof 有权热塑性树脂组合物，聚碳酸酯树脂组合物及其成型品公开(公告)号：US08044127B2
公开(公告)日：2011-10-25
申请号：US11770237
申请日：2007-06-28
申请人： Akio Nodera
发明人： Akio Nodera
IPC分类号： C08K5/523
CPC分类号： B82Y30/00 , C08G77/448 , C08K3/041 , C08K5/0066 , C08K5/49 , C08K5/523 , C08L27/18 , C08L55/02 , C08L69/00 , C08L83/10
摘要： The present invention provides a thermoplastic resin composition containing 100 parts by mass of a mixture of a thermoplastic resin (A) and carbon nanotubes (B), the mixture comprising the component (A) in an amount of 20 to 99.95 mass % and the component (B) in an amount of 0.05 to 20 mass %; a flame retardant (C) in an amount of 0.05 to 30 parts by mass; and a polyfluoroolefin resin in an amount of 0 to 2 parts by mass.The flame retardant is preferably a phosphorus compound, and the thermoplastic resin preferably contains, as a component, an aromatic polycarbonate-polyorganosiloxane copolymer.
摘要翻译： 本发明提供含有100质量份热塑性树脂（A）和碳纳米管（B）的混合物的热塑性树脂组合物，所述组合物（A）的含量为20〜99.95质量％，成分 （B）的量为0.05〜20质量％ 阻燃剂（C）的含量为0.05〜30质量份; 和0〜2质量份的多氟烯烃树脂。 阻燃剂优选为磷化合物，热塑性树脂优选含有作为成分的芳香族聚碳酸酯 - 聚有机硅氧烷共聚物。
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公开(公告)号：US08030379B2
公开(公告)日：2011-10-04
申请号：US11720935
申请日：2005-12-02
申请人： Akio Nodera , Yusuke Hayata , Yutaka Tsubokura , Yoshiaki Miura
发明人： Akio Nodera , Yusuke Hayata , Yutaka Tsubokura , Yoshiaki Miura
IPC分类号： C08K5/52 , C08K5/526 , C08L67/00 , C08G63/08 , C08F283/04
摘要： Provided is a polycarbonate resin composition having high rigidity, high flowability, high heat resistance, and excellent flame retardancy and molded articles with good appearance using the polycarbonate resin composition. The polycarbonate resin composition comprises 4 to 50 parts by mass of a nonmetallic inorganic filler (B) and 0.01 to 1 part by mass of a phosphate compound (C) relative to 100 parts by mass of a resin mixture (A) which is composed of 60 to 97% by mass of an aromatic polycarbonate resin (a-1) and 40 to 3% by mass of a fatty acid polyester (a-2).
摘要翻译： 本发明提供一种具有高刚性，高流动性，高耐热性和优异阻燃性的聚碳酸酯树脂组合物以及使用该聚碳酸酯树脂组合物具有良好外观的模塑制品。 聚碳酸酯树脂组合物相对于100质量份的由以下组成的树脂混合物（A）100质量份，包含4〜50质量份的非金属无机填料（B）和0.01〜1质量份的磷酸盐化合物（C） 60〜97质量％的芳香族聚碳酸酯树脂（a-1）和40〜3质量％的脂肪酸聚酯（a-2）。
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5.发明申请公开(公告)号：US20090061220A1
公开(公告)日：2009-03-05
申请号：US11817364
申请日：2006-03-28
申请人： Akio Nodera , Yusuke Hayata
发明人： Akio Nodera , Yusuke Hayata
CPC分类号： C08L69/00 , C08L27/18 , C08L51/085 , C08L63/00 , Y10T428/269 , C08L2666/02
摘要： There is provided an aromatic polycarbonate resin composition having excellent flame retardancy, mechanical properties and fluidity and affording a thin-walled molded article.The aromatic polycarbonate resin composition includes a resin component containing (A) 90 to 99.5% by mass of an aromatic polycarbonate resin and (B) 10 to 0.5% by mass of a polyorganosiloxane-containing graft copolymer, and, compounded in 100 parts by mass of the resin component, (C) 0.1 to 5 parts by mass of a bisphenol type epoxy compound and (D) 0.05 to 2 parts by mass of polytetrafluoroethylene capable of forming fibrils, wherein the polyorganosiloxane-containing graft copolymer in the resin composition has a dispersion average particle diameter of 0.1 to 1.0 μm. The molded article has a section with a thickness of 1 mm or less and is obtainable by molding the aromatic polycarbonate resin composition.
摘要翻译： 提供了具有优异的阻燃性，机械性能和流动性的芳族聚碳酸酯树脂组合物，并提供了薄壁成型制品。 芳香族聚碳酸酯树脂组合物包含含有（A）（A）90〜99.5质量％的芳香族聚碳酸酯树脂和（B）10〜0.5质量％的含聚有机硅氧烷的接枝共聚物的树脂成分，并且配合成100质量份 的树脂成分，（C）0.1〜5质量份双酚型环氧化合物和（D）0.05〜2质量份能够形成原纤维的聚四氟乙烯，其中，所述树脂组合物中的含聚有机硅氧烷的接枝共聚物具有 分散体平均粒径为0.1〜1.0μm。 模制品具有厚度为1mm以下的截面，可以通过模塑芳族聚碳酸酯树脂组合物而获得。
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公开(公告)号：US20060052519A1
公开(公告)日：2006-03-09
申请号：US11248272
申请日：2005-10-13
申请人： Akio Nodera , Masahiro Kitayama
发明人： Akio Nodera , Masahiro Kitayama
CPC分类号： C08L69/00 , C08G77/448 , C08L25/06 , C08L27/12 , C08L27/18 , C08L51/04 , C08L53/02 , C08L55/02 , C08L83/04 , C08L83/10 , C08L2666/02 , C08L2666/24 , C08L2666/14 , C08L2666/04
摘要： A flame-retardant polycarbonate resin composition comprising 100 parts by weight of a resin mixture of (A) from 60 to 99% by weight of a polycarbonate resin and (B) from 1 to 40% by weight of a styrenic resin, and from 0.1 to 10 parts by weight of (C) a functional group having silicone compound, and from 0.02 to 5 parts by weight of (D) a fluoro-olefin resin.
摘要翻译： 一种阻燃聚碳酸酯树脂组合物，其包含100重量份的（A）60至99重量％的聚碳酸酯树脂和（B）1至40重量％的苯乙烯树脂的树脂混合物和0.1 至（10）重量份的（C）具有硅氧烷化合物的官能团和0.02至5重量份的（D）氟代烯烃树脂。
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公开(公告)号：US06576706B1
公开(公告)日：2003-06-10
申请号：US09744248
申请日：2001-01-30
申请人： Akio Nodera , Masahiro Kitayama
发明人： Akio Nodera , Masahiro Kitayama
IPC分类号： C08L6900
CPC分类号： C08L69/00 , C08G77/448 , C08L25/06 , C08L27/12 , C08L27/18 , C08L51/04 , C08L53/02 , C08L55/02 , C08L83/04 , C08L83/10 , C08L2666/02 , C08L2666/24 , C08L2666/14 , C08L2666/04
摘要： A flame-retardant polycarbonate resin composition comprising either a resin mixture of a polycarbonate resin and a styrenic resin, a functional group-having silicone compound, and a fluoro-olefin resin; or a polycarbonate resin, a functional group-having silicone compound, and a core/shell-type, grafted rubbery elastomer; or a resin mixture of a polycarbonate resin and a styrenic resin, a fluoro-olefin resin, an inorganic filler, and a polycarbonate-polyorganosiloxane copolymer and/or a functional group-having silicone resin, which composition and its moldings, exhibit good flame retardance, good impact resistance, and good thermal stability.
摘要翻译： 一种阻燃聚碳酸酯树脂组合物，其包含聚碳酸酯树脂和苯乙烯树脂的树脂混合物，含官能团的硅氧烷化合物和氟代烯烃树脂; 聚碳酸酯树脂，具有官能团的硅氧烷化合物和核/壳型接枝橡胶弹性体; 聚碳酸酯树脂和苯乙烯树脂的树脂混合物，氟代烯烃树脂，无机填料和聚碳酸酯 - 聚有机硅氧烷共聚物和/或具有官能团的硅氧烷树脂的组合物及其模制品具有良好的阻燃性， 耐冲击性好，热稳定性好。
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8.发明授权公开(公告)号：US06331584B1
公开(公告)日：2001-12-18
申请号：US09383397
申请日：1999-08-26
申请人： Akio Nodera , Naoki Mitsuta
发明人： Akio Nodera , Naoki Mitsuta
IPC分类号： C08K549
CPC分类号： C08K5/523 , C08L27/12 , C08L51/04 , C08L69/00 , C08L2666/02
摘要： Provided are a flame-retardant polycarbonate resin composition containing a phosphate compound as the flame retardant, and also injection moldings of the composition. The composition has good moldability, and its moldings have good phosphate mold-deposits resistance and good mold releasability. In particular, when containing a styrenic resin, the composition has much better melt fluidity, and its moldings have improved impact resistance and flame retardancy. The composition comprises 100 parts by weight of a resin or resin mixture of (A) from 20 to 100% by weight of a polycarbonate resin and (B) from 0 to 80% by weight of a styrenic resin, from 1 to 30 parts by weight of (C) a phosphate compound having a melting point of not lower than 70° C., and from 0.1 to 10 parts by weight of (D) at least one member selected from the group consisting of polyglycerins, polyalkylene glycols, esters of polyglycerins, esters of polyalkylene glycols and polyesters of polycarboxylic acids with polyalcohols.
摘要翻译： 提供含有作为阻燃剂的磷酸盐化合物的阻燃聚碳酸酯树脂组合物，以及组合物的注射成型品。 该组合物具有良好的成型性，其成型品具有良好的耐磷酸盐沉积性和良好的脱模性。 特别是，当含有苯乙烯树脂时，组合物具有更好的熔体流动性，并且其模制品具有改善的耐冲击性和阻燃性。 该组合物包含100重量份的（A）20至100重量％的聚碳酸酯树脂的树脂或树脂混合物和（B）0至80重量％的苯乙烯树脂，1至30重量份 （C）熔点不低于70℃的磷酸盐化合物的重量和0.1至10重量份的（D）至少一种选自聚甘油，聚亚烷基二醇，聚亚烷基二醇， 聚甘油，聚亚烷基二醇的酯和多元羧酸与多元醇的聚酯。
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公开(公告)号：US06197857B1
公开(公告)日：2001-03-06
申请号：US09433210
申请日：1999-11-04
申请人： Akio Nodera , Naoki Mitsuta , Noritada Takeuchi
发明人： Akio Nodera , Naoki Mitsuta , Noritada Takeuchi
IPC分类号： C08K552
CPC分类号： C08L51/04 , C08L25/08 , C08L27/18 , C08L51/085 , C08L55/02 , C08L69/00 , C08L83/04 , C08L2666/02 , C08L2666/14
摘要： An object of the invention is to provide a flame-retardant polycarbonate resin composition which can provide a sliding property of a molding product formed of a flame-retardant resin composition obtained by blending a polycarbonate resin and a styrene resin with a phosphate ester compound and having a good flowability without decreasing an appearance of a molding product. The invention relates to a flame-retardant polycarbonate resin composition including 100 parts by weight of a resin composed of (A) from 60 to 99% by weight of a polycarbonate resin and (B) from 40 to 1% by weight of a styrene resin, (C) from 1 to 30 parts by weight of a phosphate ester compound and (D) from 0.3 to 3 parts by weight of a silicone oil having a viscosity of from 1,000 to 20,000 cs.
摘要翻译： 本发明的目的是提供一种阻燃性聚碳酸酯树脂组合物，其能够提供由通过将聚碳酸酯树脂和苯乙烯树脂与磷酸酯化合物共混而得到的阻燃性树脂组合物形成的成型体的滑动性， 良好的流动性，而不会降低成型产品的外观。 本发明涉及一种阻燃聚碳酸酯树脂组合物，其包含100重量份由（A）60至99重量％的聚碳酸酯树脂和（B）40至1重量％的苯乙烯树脂 ，（C）1〜30重量份磷酸酯化合物和（D）0.3〜3重量份粘度为1,000〜20,000cs的硅油。
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公开(公告)号：US08410214B2
公开(公告)日：2013-04-02
申请号：US11814034
申请日：2005-12-27
申请人： Yusuke Hayata , Akio Nodera
发明人： Yusuke Hayata , Akio Nodera
摘要： The present invention provides a thermoplastic resin composition comprising 100 mass parts of a polycarbonate resin composition comprising 50 to 95 mass % of (A) a polycarbonate resin and 50 to 5 mass % of (B) a polylactic acid based resin and 5 to 65 mass parts of (C) a vinyl based graft copolymer. The above thermoplastic resin composition comprising the polycarbonate resin and the lactic acid based resin and endowed with a mechanical characteristic of polycarbonate and an excellent fluidity of polylactic acid in combination is improved in a hydrolysis resistance and provides a molded article further improved in an impact resistance and a thin-walled falling weight impact strength. A rise in the above characteristics makes it possible to use the plastic molded articles over a long period of time, and not only the thin-walled molding property and the portability are improved, but also the thermoplastic resin composition of the present invention can industrially advantageously be used as well for large-sized molded articles. In the thermoplastic resin composition of the present invention, use of the polycarbonate-polyorganosiloxane copolymer as the polycarbonate resin component makes it possible to improve as well the flame retardancy and advantageously use the thermoplastic resin composition of the present invention for office automation equipments, information and communication equipments, car parts, building components, home electric appliances and the like.
摘要翻译： 本发明提供一种热塑性树脂组合物，其包含100质量份的聚碳酸酯树脂组合物，其包含50〜95质量％的（A）聚碳酸酯树脂和50〜5质量％的（B）聚乳酸类树脂，5〜65质量％ 部分（C）乙烯基接枝共聚物。 包含聚碳酸酯树脂和乳酸基树脂并且具有聚碳酸酯的机械特性和聚乳酸的优异流动性的上述热塑性树脂组合物的耐水解性提高，并且提供了进一步提高耐冲击性的成型体， 薄壁落锤冲击强度。 上述特征的上升使得可以长时间使用塑料模塑制品，不仅提高了薄壁成型性和便携性，而且本发明的热塑性树脂组合物在工业上可以有利地 也可用于大型成型制品。 在本发明的热塑性树脂组合物中，通过使用聚碳酸酯 - 聚有机硅氧烷共聚物作为聚碳酸酯树脂成分，能够提高阻燃性，有利地将本发明的热塑性树脂组合物用于办公自动化设备，信息和 通信设备，汽车零件，建筑构件，家用电器等。
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