公开(公告)号：US20120301809A1

公开(公告)日：2012-11-29

申请号：US13576003

申请日：2011-01-31

申请人： Naoki Mitsuta ,  Shintaro Tanaka ,  Taku Eguchi

发明人： Naoki Mitsuta ,  Shintaro Tanaka ,  Taku Eguchi

IPC分类号： H01M8/10 ,  B82Y30/00

CPC分类号： H01M8/1004 ,  H01M4/8657 ,  H01M8/0254 ,  H01M8/0258 ,  H01M8/1025 ,  H01M8/1039 ,  H01M8/1067 ,  H01M2008/1095 ,  H01M2250/20 ,  Y02E60/521 ,  Y02T90/32

摘要： Provided is a membrane electrode assembly for a polymer electrolyte fuel cell which is hard to be unstable in electric power generation even though a change in power generation surroundings, or a change in the humidity conditions in the vicinity of the electrodes occurs, has high initial performance, and suppresses the performance deterioration in a long-term use. The membrane electrode assembly for a polymer electrolyte fuel cell (1) comprises: a proton conductive membrane (2) for conducting protons; electrode catalyst layers (3) arranged at both sides of the proton conductive membrane (2) containing catalyst particles and an electrode electrolyte; and gas diffusion layers (4) arranged on the respective electrode catalyst layers (3), having a porous basic material. Further, intermediate layers (5) each having a thickness of 2-6 μm are included, with noble metallic nanoparticles (51), an electrode electrolyte (52) and carbon powder.

摘要翻译： 本发明提供一种聚合物电解质型燃料电池用膜电极接合体，即使在发电环境发生变化或发生电极附近的湿度状况变化的情况下，也难以发电，因此具有高的初期性能 ，并且抑制长期使用中的性能劣化。 用于聚合物电解质燃料电池（1）的膜电极组件包括：质子传导膜（2），用于导电质子; 布置在含有催化剂颗粒和电极电解质的质子传导膜（2）两侧的电极催化剂层（3） 以及布置在各个电极催化剂层（3）上的具有多孔基材的气体扩散层（4）。 此外，包括厚度为2-6μm的中间层（5），其中含有贵金属纳米颗粒（51），电极电解质（52）和碳粉末。

公开(公告)号：US20060216572A1

公开(公告)日：2006-09-28

申请号：US11388431

申请日：2006-03-24

申请人： Hiromichi Yoshida ,  Shigeru Inai ,  Minoru Koshinuma ,  Ryo Jinba ,  Seiji Sugiura ,  Naoki Mitsuta ,  Katsumi Hayashi

发明人： Hiromichi Yoshida ,  Shigeru Inai ,  Minoru Koshinuma ,  Ryo Jinba ,  Seiji Sugiura ,  Naoki Mitsuta ,  Katsumi Hayashi

IPC分类号： H01M8/02 ,  H01M4/94

CPC分类号： H01M8/04228 ,  H01M8/0258 ,  H01M8/0263 ,  H01M8/0265 ,  H01M8/0286 ,  H01M8/241 ,  H01M8/2457

摘要： An oxygen-containing gas flow field is formed on a surface of a first metal separator. The oxygen-containing gas flow field is connected between an oxygen-containing gas supply passage and an oxygen-containing gas discharge passage. The oxygen-containing gas flow field comprises oxygen-containing gas flow grooves, and ends of the oxygen-containing gas flow grooves are extended outwardly beyond ends of electrode catalyst layer of a membrane electrode assembly, and connected to an inlet buffer and an outlet buffer. When the purging process is performed at the time of stopping operation of the fuel cell, the purging air supplied to the oxygen-containing gas flow field discharges water retained in the electrode catalyst layers from the ends to the outlet buffer.

摘要翻译： 在第一金属分离器的表面上形成含氧气体流场。 含氧气体流场连接在含氧气体供给通道和含氧气体排出通道之间。 含氧气体流场包括含氧气体流动槽，并且含氧气体流动槽的端部向外延伸超过膜电极组件的电极催化剂层的端部，并且连接到入口缓冲器和出口缓冲器 。 当在燃料电池停止运行时执行清洗处理时，供给到含氧气体流场的净化空气从端部向出口缓冲器排出保留在电极催化剂层中的水。

公开(公告)号：US20060110650A1

公开(公告)日：2006-05-25

申请号：US11285985

申请日：2005-11-23

申请人： Seiji Sugiura ,  Jun Kondo ,  Shigeru Inai ,  Hiromichi Yoshida ,  Hiroyuki Tanaka ,  Naoki Mitsuta

发明人： Seiji Sugiura ,  Jun Kondo ,  Shigeru Inai ,  Hiromichi Yoshida ,  Hiroyuki Tanaka ,  Naoki Mitsuta

IPC分类号： H01M8/24 ,  H01M2/08

CPC分类号： H01M8/04291 ,  H01M8/02 ,  H01M8/0258 ,  H01M8/0263 ,  H01M8/0267 ,  H01M8/0271 ,  H01M8/0273 ,  H01M8/0276 ,  H01M8/04179 ,  H01M8/241 ,  H01M8/242 ,  H01M8/2465 ,  H01M8/2483 ,  H01M2008/1095 ,  H01M2250/20 ,  Y02T90/32

摘要： A fuel cell stack includes a stack body, an end separator, a terminal plate, an insulating plate, and an end plate provided at one end of the stack body in a stacking direction. The insulating plate has a recess for accommodating the terminal plate. Further, the insulating plate has a bypass passage connected between a fuel gas supply passage and a fuel gas discharge passage outside the recess for discharging condensed water. An insulating seal member is provided on the end separator to cover the bypass passage. The condensed water flows through an insulated passage formed by the insulating seal member and the bypass passage.

摘要翻译： 燃料电池堆包括堆叠体，端部分离器，端子板，绝缘板和设置在堆叠体的堆叠方向的一端的端板。 绝缘板具有容纳端子板的凹部。 此外，绝缘板具有连接在燃料气体供给通道和用于排出冷凝水的凹部之外的燃料气体排出通道之间的旁通通道。 绝缘密封构件设置在端部分离器上以覆盖旁路通道。 冷凝水流过由绝缘密封构件和旁通通道形成的绝缘通道。

公开(公告)号：US06465555B1

公开(公告)日：2002-10-15

申请号：US09410030

申请日：1999-10-01

申请人： Akio Nodera ,  Naoki Mitsuta

发明人： Akio Nodera ,  Naoki Mitsuta

IPC分类号： C08K332

CPC分类号： C08K3/02 ,  C08K3/34 ,  C08K2003/026 ,  C08L51/04 ,  C08L69/00 ,  C08L25/00

摘要： Provided are a flame-retardant thermoplastic resin composition comprising 100 parts by weight of a resin mixture of (A) from 50 to 95% by weight of a polycarbonate resin and (B) from 5 to 50% by weight of a styrenic resin, from 0.1 to 10 parts by weight of (C) red phosphorus, and from 5 to 50 parts by weight of (D) talc, and its injection moldings. The composition comprising a polycarbonate resin and a styrenic resin is troubled little by red coloration with red phosphorus therein. The composition can be well molded into pale color or light color moldings. The color tone and the outward appearance of the moldings are both good, and the heat resistance, impact resistance, rigidity and even the flame retardancy of the moldings are much improved. In the composition, red phosphorus is preferably stabilized.

摘要翻译： 提供一种阻燃热塑性树脂组合物，其包含100重量份的（A）50至95重量％的聚碳酸酯树脂和（B）5至50重量％的苯乙烯树脂的树脂混合物， 0.1〜10重量份（C）红磷，5〜50重量份（D）滑石粉及其注射成型品。 包含聚碳酸酯树脂和苯乙烯树脂的组合物几乎不会由于其中的红磷的红色着色而困扰。 组合物可以很好地模塑成浅色或浅色模制品。 模制品的色调和外观都是好的，并且模制品的耐热性，耐冲击性，刚性甚至阻燃性都得到很大改善。 在组合物中，红磷优选稳定。

公开(公告)号：US06448324B1

公开(公告)日：2002-09-10

申请号：US09365406

申请日：1999-08-02

申请人： Akio Nodera ,  Naoki Mitsuta ,  Kouichi Hara

发明人： Akio Nodera ,  Naoki Mitsuta ,  Kouichi Hara

IPC分类号： C08K334

CPC分类号： C08L69/00 ,  C08L2666/02 ,  C08L33/00

摘要： Provided are a flame-retardant polycarbonate resin composition having good blow moldability, and blow moldings of the composition having good flame retardancy and having good impact resistance, high mechanical strength and good thermal stability intrinsic to polycarbonate resins. The composition comprises 100 parts by weight of a resin or resin mixture of (A) from 30 to 100% by weight of a polycarbonate resin and (B) from 0 to 70% by weight of a styrenic resin, from 1 to 50 parts by weight of (C) a flame retardant, and from 1 to 20 parts by weight of (D) a methyl methacrylate polymer having a weight-average molecular weight of at least 1,000,000, and optionally contains (E) a fluoro-olefinic resin, (F) a rubber-like elastomer, and (G) an inorganic filler.

摘要翻译： 提供具有良好吹塑成型性的阻燃性聚碳酸酯树脂组合物，该组合物的吹塑成型体具有良好的阻燃性，并且具有良好的耐冲击性，高机械强度和聚碳酸酯树脂固有的良好的热稳定性。 该组合物包含100重量份的（A）30至100重量％的聚碳酸酯树脂的树脂或树脂混合物和（B）0至70重量％的苯乙烯树脂，1至50重量份 （C）阻燃剂的重量和1至20重量份的（D）重均分子量为至少1,000,000的甲基丙烯酸甲酯聚合物，并且任选地包含（E）氟烯烃树脂（ F）橡胶状弹性体，（G）无机填料。

公开(公告)号：US09966623B2

公开(公告)日：2018-05-08

申请号：US14346377

申请日：2012-09-06

申请人： Yukihito Tanaka ,  Kazuo Nunokawa ,  Hiroshi Sohma ,  Kenichi Tanaka ,  Naoki Mitsuta ,  Masashi Sugishita ,  Daisuke Okonogi

发明人： Yukihito Tanaka ,  Kazuo Nunokawa ,  Hiroshi Sohma ,  Kenichi Tanaka ,  Naoki Mitsuta ,  Masashi Sugishita ,  Daisuke Okonogi

IPC分类号： H01M8/10 ,  H01M8/1004 ,  H01M8/0267 ,  H01M8/0271 ,  H01M8/0273 ,  H01M8/0276 ,  H01M8/0286 ,  H01M8/1018 ,  H01M8/0284

CPC分类号： H01M8/1004 ,  H01M8/0267 ,  H01M8/0271 ,  H01M8/0273 ,  H01M8/0276 ,  H01M8/0284 ,  H01M8/0286 ,  H01M2008/1095

摘要： An electrolyte membrane-electrode structure with a resin frame is provided with: an electrolyte membrane-electrode structure that is provided with an anode-side electrode and a cathode-side electrode, with a solid polymer electrolyte membrane being held therebetween; and a resin frame member that is arranged around the outer periphery of the solid polymer electrolyte membrane. An intermediate layer is continuously arranged: between an outer peripheral end portion of the cathode-side electrode and a first inner peripheral end portion of the resin frame member; on an outer peripheral end portion of the solid polymer electrolyte membrane, said outer peripheral end portion being exposed outside the outer peripheral end portion of the cathode-side electrode; and between an outer peripheral end portion of the anode-side electrode and a second inner peripheral end portion of the resin frame member.

公开(公告)号：US08114552B2

公开(公告)日：2012-02-14

申请号：US11723436

申请日：2007-03-20

申请人： Yuichiro Hama ,  Masaru Iguchi ,  Junichi Yano ,  Nagayuki Kanaoka ,  Naoki Mitsuta

发明人： Yuichiro Hama ,  Masaru Iguchi ,  Junichi Yano ,  Nagayuki Kanaoka ,  Naoki Mitsuta

IPC分类号： H01M8/10

CPC分类号： H01M4/8828 ,  H01M4/8807 ,  H01M4/8882 ,  H01M4/92 ,  H01M4/926 ,  H01M8/1004 ,  H01M8/1025 ,  H01M8/1039 ,  Y02P70/56

摘要： There is provided an electrode structure for a polymer electrolyte fuel cell having excellent power generation performance and excellent durability and a method for manufacturing the same. Also provided is a polymer electrolyte fuel cell including the electrode structure and an electrical apparatus and a transport apparatus using the polymer electrolyte fuel cell. The electrode structure includes a polymer electrolyte membrane 2 sandwiched between a pair of electrode catalyst layers 1, 1 containing carbon particles supporting catalyst particles. The polymer electrolyte membrane 2 is made of a sulfonated polyarylene-based polymer. The sulfonated polyarylene-based polymer has an ion exchange capacity in the range of 1.7 to 2.3 meq/g, and the polymer contains a component insoluble in N-methylpyrrolidone in an amount of 70% or less relative to the total amount of the polymer, after the polymer is subjected to heat treatment for exposing it under a constant temperature atmosphere of 12° C. for 200 hours. A catalyst paste containing catalyst particles and a polymer electrolyte is coated on a sheet-like support 6 and dried to form an electrode catalyst layer 1 containing a solvent in an amount in the range of 0.5% or less by weight of the total membrane. The electrode catalyst layers 3, 3 are thermally transferred and joined on both sides of the polymer electrolyte membrane 1.

摘要翻译： 提供了具有优异的发电性能和优异的耐久性的用于聚合物电解质燃料电池的电极结构及其制造方法。 还提供了包括电极结构的聚合物电解质燃料电池和使用聚合物电解质燃料电池的电气设备和输送设备。 电极结构包括夹在包含支持催化剂颗粒的碳颗粒的一对电极催化剂层1,1之间的聚合物电解质膜2。 高分子电解质膜2由磺化聚亚芳基系聚合物构成。 磺化聚亚芳基系聚合物的离子交换容量为1.7〜2.3meq / g，聚合物中含有不溶于N-甲基吡咯烷酮的成分相对于聚合物总量为70％以下， 在聚合物经受热处理以使其在12℃的恒温气氛下暴露200小时。 将含有催化剂颗粒和聚合物电解质的催化剂浆料涂覆在片状载体6上并干燥，形成含有溶剂总量为0.5重量％以下的溶剂的电极催化剂层1。 电极催化剂层3,3在高分子电解质膜1的两面热转印并接合。

公开(公告)号：US20110207014A1

公开(公告)日：2011-08-25

申请号：US13022573

申请日：2011-02-07

申请人： Naoki MITSUTA ,  Taku EGUCHI

发明人： Naoki MITSUTA ,  Taku EGUCHI

IPC分类号： H01M8/10 ,  H01M8/00 ,  B05D5/12

CPC分类号： H01M4/8605 ,  H01M4/881 ,  H01M4/9083 ,  H01M4/926 ,  H01M8/1004 ,  H01M2008/1095 ,  Y02P70/56

摘要： A fuel cell membrane electrode assembly includes an anode electrode catalyst layer, a cathode electrode catalyst layer, and a polymer electrolyte membrane. A ratio of a pore volume occupied by pores with a pore size of 0.1 μm or less is 70% or more in a pore volume occupied by pores with a pore size of 3 μm or less formed in the anode electrode catalyst layer. The polymer electrolyte membrane is sandwiched between the anode electrode catalyst layer and the cathode electrode catalyst layer.

摘要翻译： 燃料电池膜电极组件包括阳极电极催化剂层，阴极电极催化剂层和聚合物电解质膜。 在阳极电极催化剂层中形成的孔径为3μm以下的孔所占的孔体积中，孔径为0.1μm以下的孔的孔体积比为70％以上。 聚合物电解质膜被夹在阳极电极催化剂层和阴极电极催化剂层之间。

公开(公告)号：US20100190088A1

公开(公告)日：2010-07-29

申请号：US12752941

申请日：2010-04-01

申请人： Nagayuki KANAOKA ,  Naoki Mitsuta ,  Yuichiro Hama ,  Ryoichiro Takahashi ,  Hiroshi Souma ,  Masaru Iguchi ,  Yoichi Asano

发明人： Nagayuki KANAOKA ,  Naoki Mitsuta ,  Yuichiro Hama ,  Ryoichiro Takahashi ,  Hiroshi Souma ,  Masaru Iguchi ,  Yoichi Asano

IPC分类号： H01M8/10

CPC分类号： H01M8/1032 ,  H01M4/8605 ,  H01M4/92 ,  H01M4/926 ,  H01M8/1004 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/1048 ,  H01M8/1081 ,  Y02P70/56

摘要： A membrane electrode assembly for a polymer electrolyte fuel cell has superior power generation characteristics under low humidity conditions and superior starting characteristics under low temperature conditions. In the membrane electrode assembly for a polymer electrolyte fuel cell in which a polymer electrolyte membrane is disposed between a pair of electrodes containing a catalyst, the polymer electrolyte membrane has a polymer segment A having an ion conductive component and a polymer segment B not having an ion conductive component. Furthermore, in the case in which the polymer electrolyte membrane is immersed in water at 90° C. for 30 minutes, absorbed water which exhibits a thawing temperature of from −30 to 0° C. is in a range from 0.01 to 3.0 g per 1 g of the polymer.

摘要翻译： 用于聚合物电解质燃料电池的膜电极组件在低湿度条件下具有优异的发电特性，并且在低温条件下具有优异的起动特性。 在其中聚合物电解质膜设置在包含催化剂的一对电极之间的聚合物电解质燃料电池的膜电极组件中，聚合物电解质膜具有具有离子传导性成分的聚合物链段A和不具有 离子传导元件。 此外，在将聚合物电解质膜浸渍在90℃的水中30分钟的情况下，解冻温度为-30〜0℃的吸收水为0.01〜3.0g 1g聚合物。

公开(公告)号：US20070166594A1

公开(公告)日：2007-07-19

申请号：US11723436

申请日：2007-03-20

申请人： Yuichiro Hama ,  Masaru Iguchi ,  Junichi Yano ,  Nagayuki Kanaoka ,  Naoki Mitsuta

发明人： Yuichiro Hama ,  Masaru Iguchi ,  Junichi Yano ,  Nagayuki Kanaoka ,  Naoki Mitsuta

IPC分类号： H01M8/10 ,  H01M4/96 ,  H01M4/88 ,  B05D5/12

CPC分类号： H01M4/8828 ,  H01M4/8807 ,  H01M4/8882 ,  H01M4/92 ,  H01M4/926 ,  H01M8/1004 ,  H01M8/1025 ,  H01M8/1039 ,  Y02P70/56

摘要： There is provided an electrode structure for a polymer electrolyte fuel cell having excellent power generation performance and excellent durability and a method for manufacturing the same. Also provided is a polymer electrolyte fuel cell including the electrode structure and an electrical apparatus and a transport apparatus using the polymer electrolyte fuel cell. The electrode structure includes a polymer electrolyte membrane 2 sandwiched between a pair of electrode catalyst layers 1, 1 containing carbon particles supporting catalyst particles. The polymer electrolyte membrane 2 is made of a sulfonated polyarylene-based polymer. The sulfonated polyarylene-based polymer has an ion exchange capacity in the range of 1.7 to 2.3 meq/g, and the polymer contains a component insoluble in N-methylpyrrolidone in an amount of 70% or less relative to the total amount of the polymer, after the polymer is subjected to heat treatment for exposing it under a constant temperature atmosphere of 12° C. for 200 hours. A catalyst paste containing catalyst particles and a polymer electrolyte is coated on a sheet-like support 6 and dried to form an electrode catalyst layer 1 containing a solvent in an amount in the range of 0.5% or less by weight of the total membrane. The electrode catalyst layers 3, 3 are thermally transferred and joined on both sides of the polymer electrolyte membrane 1.

摘要翻译： 提供了具有优异的发电性能和优异的耐久性的用于聚合物电解质燃料电池的电极结构及其制造方法。 还提供了包括电极结构的聚合物电解质燃料电池和使用聚合物电解质燃料电池的电气设备和输送设备。 电极结构包括夹在包含支持催化剂颗粒的碳颗粒的一对电极催化剂层1,1之间的聚合物电解质膜2。 高分子电解质膜2由磺化聚亚芳基系聚合物构成。 磺化聚亚芳基系聚合物的离子交换容量为1.7〜2.3meq / g，聚合物中含有不溶于N-甲基吡咯烷酮的成分相对于聚合物总量为70％以下， 在聚合物经受热处理以使其在12℃的恒温气氛下暴露200小时。 将含有催化剂颗粒和聚合物电解质的催化剂浆料涂覆在片状载体6上并干燥以形成含有溶剂的总量为0.5重量％以下的溶剂的电极催化剂层1。 电极催化剂层3,3在高分子电解质膜1的两面热转印并接合。