摘要:
A novel flexible polyurethane foam having good vibration characteristics and being excellent in occupant posture stability, is provided.A flexible polyurethane foam obtainable by reacting a high molecular weight polyoxyalkylene polyol or a polymer-dispersed polyol containing fine polymer particles in the high molecular weight polyoxyalkylene polyol, with a polyisocyanate compound in the presence of a catalyst, a blowing agent and a foam stabilizer, characterized in that as at least a part of the foam stabilizer, the following fluorinated compound (F) is used in an amount of from 0.00001 to 1 part by mass per 100 parts by mass of all active hydrogen compounds: fluorinated compound (F): a compound which is a copolymer of a fluorinated acrylate or a fluorinated methacrylate (p), an alkyl acrylate having a long chain alkyl group, an alkyl methacrylate having a long chain alkyl group, an acrylate containing an oxyalkylene group or a methacrylate containing an oxyalkylene group (q), and optional other copolymerizable monomer (r), wherein the fluorine content is from 12 to 50 mass %.
摘要:
A novel flexible polyurethane foam having good vibration characteristics and being excellent in occupant posture stability, is provided. A flexible polyurethane foam obtainable by reacting a high molecular weight polyoxyalkylene polyol or a polymer-dispersed polyol containing fine polymer particles in the high molecular weight polyoxyalkylene polyol, with a polyisocyanate compound in the presence of a catalyst, a blowing agent and a foam stabilizer, characterized in that as at least a part of the foam stabilizer, the following fluorinated compound (F) is used in an amount of from 0.00001 to 1 part by mass per 100 parts by mass of all active hydrogen compounds: fluorinated compound (F): a compound which is a copolymer of a fluorinated acrylate or a fluorinated methacrylate (p), an alkyl acrylate having a long chain alkyl group, an alkyl methacrylate having a long chain alkyl group, an acrylate containing an oxyalkylene group or a methacrylate containing an oxyalkylene group (q), and optional other copolymerizable monomer (r), wherein the fluorine content is from 12 to 50 mass %.
摘要:
A flexible polyurethane foam excellent in the vibration characteristics and the load-deflection characteristics, a process for producing the flexible polyurethane foam stably and inexpensively, and a seat for an automobile excellent in posture-stability performance and supported feeling with little bottom-hitting feeling, are provided. When a polyoxyalkylene polyol and a polyisocyanate compound are reacted in the presence of a urethane-forming catalyst, a blowing agent and a foam stabilizer, a predetermined amount of a compound of the following formula (1) is used: wherein the average of n is from 13 to 2,100.
摘要:
A flexible polyurethane foam excellent in the vibration characteristics and the load-deflection characteristics, a process for producing the flexible polyurethane foam stably and inexpensively, and a seat for an automobile excellent in posture-stability performance and supported feeling with little bottom-hitting feeling, are provided.When a polyoxyalkylene polyol and a polyisocyanate compound are reacted in the presence of a urethane-forming catalyst, a blowing agent and a foam stabilizer, a predetermined amount of a compound of the following formula (1) is used: wherein the average of n is from 13 to 2,100.
摘要:
To provide a flexible polyurethane foam having good vibration characteristics and suitable particularly for a seat for an automobile. A flexible polyurethane foam obtained by reacting a high molecular weight polyoxyalkylene polyol or a polymer-dispersed polyol containing fine polymer particles in the high molecular weight polyoxyalkylene polyol, with a polyisocyanate compound, in the presence of a catalyst, a blowing agent and a foam stabilizer, characterized in that an amino-modified silicone (F) having a silicon atom and a nitrogen atom in its molecule is used in an amount of from 0.00001 to 1 part by mass per 100 parts by mass of all active hydrogen compounds.
摘要:
To provide a flexible polyurethane foam having good vibration characteristics and suitable particularly for a seat for an automobile.A flexible polyurethane foam obtained by reacting a high molecular weight polyoxyalkylene polyol or a polymer-dispersed polyol containing fine polymer particles in the high molecular weight polyoxyalkylene polyol, with a polyisocyanate compound, in the presence of a catalyst, a blowing agent and a foam stabilizer, characterized in that an amino-modified silicone (F) having a silicon atom and a nitrogen atom in its molecule is used in an amount of from 0.00001 to 1 part by mass per 100 parts by mass of all active hydrogen compounds.
摘要:
To provide a flexible polyurethane foam which is excellent in low resiliency and durability without using a plasticizer and which shows little change in hardness against a change in temperature and at the same time, has high air flow.A process for producing a flexible polyurethane foam, which comprises reacting a polyol mixture comprising the following polyol (A), the following polyol (B) and the following monool (D) with a polyisocyanate compound in the presence of a blowing agent and a foam stabilizer, at an isocyanate index of at least 90, wherein: Polyol (A) is a polyether polyol having an average of from 2 to 3 hydroxyl groups, a hydroxyl value of from 10 to 60 mgKOH/g and an oxyethylene group content of from 0 to 30 mass %, obtained by ring-opening polymerization of an alkylene oxide to an initiator using a phosphazene compound, a Lewis acid compound or an alkali metal compound catalyst; Polyol (B) is a polyether polyol having an average of from 2 to 3 hydroxyl groups and a hydroxyl value of from 70 to 250 mgKOH/g; and Monool (D) is a polyether monool having a hydroxyl value of from 10 to 200 mgKOH/g.
摘要:
To provide a flexible polyurethane foam which is excellent in low resiliency and durability without using a plasticizer and which shows little change in hardness against a change in temperature and at the same time, has high air permeability. A process for producing a flexible polyurethane foam, which comprises reacting a polyol mixture comprising polyol (A), polyol (B) and monool (D) with a polyisocyanate compound in the presence of a blowing agent etc. at an isocyanate index of at least 90. Polyol (A) is a polyether polyol having an average of 2-3 hydroxyl groups and a hydroxyl value of from 10 to 90 mgKOH/g, obtained by ring-opening addition polymerization of an alkylene oxide to an initiator using a double metal cyanide complex catalyst; Polyol (B) is a polyether polyol having an average of 2-3 hydroxyl groups and a hydroxyl value of from 15 to 250 mgKOH/g, other than the polyol (A); and Monool (D) is a polyether monool having a hydroxyl value of from 10 to 200 mgKOH/g.
摘要:
To provide a flexible polyurethane foam having good vibration characteristics and suitable particularly for a seat for an automobile. A flexible polyurethane foam obtained by reacting a polyol composition with a polyisocyanate compound in the presence of a catalyst, a blowing agent and a foam stabilizer, characterized in that the polyol composition comprises a high molecular weight polyoxyalkylene polyol (A) and a polymer-dispersed polyol (C) containing fine polymer particles in a high molecular weight polyoxyalkylene polyol (B), and at least part of the fine polymer particles are fine polymer particles obtained by polymerizing a monomer containing a fluorinated acrylate or a fluorinated methacrylate.
摘要:
To provide a flexible polyurethane foam which is excellent in low resiliency and durability without using a plasticizer and which shows little change in hardness against a change in temperature and at the same time, has high air permeability. A process for producing a flexible polyurethane foam, which comprises reacting a polyol mixture comprising polyol (A), polyol (B) and monool (D) with a polyisocyanate compound in the presence of a blowing agent etc. at an isocyanate index of at least 90. Polyol (A) is a polyether polyol having an average of 2-3 hydroxyl groups and a hydroxyl value of from 10 to 90 mgKOH/g, obtained by ring-opening addition polymerization of an alkylene oxide to an initiator using a double metal cyanide complex catalyst; Polyol (B) is a polyether polyol having an average of 2-3 hydroxyl groups and a hydroxyl value of from 15 to 250 mgKOH/g, other than the polyol (A); and Monool (D) is a polyether monool having a hydroxyl value of from 10 to 200 mgKOH/g.