公开(公告)号：US06607682B1

公开(公告)日：2003-08-19

申请号：US09509502

申请日：2000-03-29

申请人： Takema Yamaguchi ,  Tomonori Iwamoto ,  Minori Yamaguchi ,  Kenichi Senda

发明人： Takema Yamaguchi ,  Tomonori Iwamoto ,  Minori Yamaguchi ,  Kenichi Senda

IPC分类号： B29C4402

CPC分类号： C08J9/232 ,  B29C44/3461 ,  B29C44/445 ,  C08J9/18 ,  C08J2323/12

摘要： Polypropylene resin pre-expanded particles having an expandability of 1.0 to 1.8 shown by the equation: Expandability = Expansion  ratio  of  polypropylene  resin  pre- expanded  particles  after  steam  heating Expansion  ratio  of  polypropylene  resin  pre- expanded  particles  before  steam  heating wherein the expansion ratio of polypropylene resin pre-expanded particles after steam heating denotes the value obtained when heating the pre-expanded particles by steam having a temperature equal to the melting point peak temperature measured by differential scanning calorimetry of the base resin constituting the particles, the pre-expanded particles being able to be molded by various in-mold foaming methods in a shortened period of cooling time in molding to stably produce cellular molded articles having good melt adhesion of the particles and surface appearance and having uniform density in the surface and inner portions.

摘要翻译： 聚丙烯树脂预发泡粒子，其膨胀率为1.0〜1.8，如下式所示：蒸汽加热后的聚丙烯树脂预发泡粒子的膨胀率，表示将预发泡粒子用温度等于 通过构成颗粒的基础树脂的差示扫描量热法测量的熔点峰值温度，预成型颗粒能够通过各种模内发泡方法在缩短的成型冷却时间内成型以稳定地生产多孔模制品 具有良好的熔融粘附性和表面外观，并且在表面和内部具有均匀的密度。

公开(公告)号：US06167892A

公开(公告)日：2001-01-02

申请号：US09284565

申请日：1999-04-16

申请人： Tomonori Iwamoto ,  Takema Yamaguchi ,  Minori Yamaguchi

发明人： Tomonori Iwamoto ,  Takema Yamaguchi ,  Minori Yamaguchi

IPC分类号： B08B304

CPC分类号： C08J9/224 ,  B29C44/3461 ,  C08J2323/16

摘要： A method of washing pre-expanded particles having a substantially water insoluble inorganic compound attached thereto by contacting the pre-expanded particles with an aqueous washing solution of a water soluble compound. The water soluble compound has a solubility with water of at least 1 g/100 g of water and has 1-500 surface bonding functional groups and 1-500 hydrophilic functional groups. At least one of the surface bonding functional groups of the water soluble compound attaches to the water insoluble inorganic compound.

摘要翻译： 通过使预发泡颗粒与水溶性化合物的水性洗涤溶液接触来洗涤具有附着于其上的基本上水不溶性无机化合物的预发泡颗粒的方法。 水溶性化合物与水的溶解度为至少1g / 100g水，具有1-500个表面键合官能团和1-500个亲水官能团。 水溶性化合物的至少一个表面键合官能团与水不溶性无机化合物相连。

公开(公告)号：US06822023B2

公开(公告)日：2004-11-23

申请号：US09998170

申请日：2001-12-03

申请人： John Bready Stuart ,  Steven Charles Skarke ,  Tetsuya Ogita ,  Takema Yamaguchi ,  Tomonori Iwamoto

发明人： John Bready Stuart ,  Steven Charles Skarke ,  Tetsuya Ogita ,  Takema Yamaguchi ,  Tomonori Iwamoto

IPC分类号： C08J300

CPC分类号： C08J9/16 ,  C08J9/0028 ,  C08J2203/14 ,  C08J2323/02 ,  C08J2323/10 ,  C08K5/34926 ,  Y10S521/907 ,  C08L23/02

摘要： Flame retardant polyolefin pre-expanded particles made of a resin composition comprising a polyolefin resin and a sterically hindered amine ether flame retardant, which can be molded with good moldability to give in-mold foamed articles which have an excellent flame resistance and do not generate harmful gas at the time of burning.

摘要翻译： 由包含聚烯烃树脂和空间位阻胺醚阻燃剂的树脂组合物制成的阻燃聚烯烃预发泡颗粒，其可以模塑成型，具有良好的成型性，得到具有优异阻燃性且不产生有害物质的模内发泡制品 燃烧时的气体。

公开(公告)号：US06593382B2

公开(公告)日：2003-07-15

申请号：US10058077

申请日：2002-01-29

申请人： Taro Kiguchi ,  Tomonori Iwamoto ,  Kenichi Senda

发明人： Taro Kiguchi ,  Tomonori Iwamoto ,  Kenichi Senda

IPC分类号： C08J918

CPC分类号： C08J9/18 ,  C08J2323/02

摘要： Polyolefin resin pre-expanded particles having two fusion peaks on DSC curve wherein the proportion of the heat of fusion Qh of the peak appearing on the high temperature side based on the total heat of fusion of the two peaks represented by the equation: [Qh/(Ql+Qh)]×100 falls within the range of 10 to 60% in which Ql is the heat of fusion of the peak appearing on the low temperature side, and the standard deviation of said proportion is not more than 1.2. The pre-expanded particles are prepared by releasing an aqueous dispersion of resin particles impregnated with a blowing agent from a vessel into an atmosphere of lower pressure than the inner pressure of the vessel to expand the particles, while stepwise or continuously raising the inner temperature or the inner pressure of the vessel at a specific rate, and can be molded with stable molding cycle to give cellular molded articles having stable dimensions.

公开(公告)号：US06797734B2

公开(公告)日：2004-09-28

申请号：US10433873

申请日：2003-06-04

申请人： Tomonori Iwamoto ,  Takayuki Goda

发明人： Tomonori Iwamoto ,  Takayuki Goda

IPC分类号： C08J922

CPC分类号： C08J9/16 ,  C08J9/0028 ,  C08J9/125 ,  C08J2203/06 ,  C08J2323/12

摘要： The present invention provides polypropylene resin pre-expanded particles having small fluctuation in cell diameter and expansion ratio compared to in the past. The pre-expanded particles are obtained by having as a base resin, a polypropylene resin composition comprising polypropylene resin (A), a compound having a triazine skeleton and molecular weight of at most 300 per triazine skeleton unit (B) and as a random component, hydrophilic polymer (C) and inorganic filler (D) and water as the foaming agent. By using the pre-expanded particles, a polypropylene resin in-mold expanded article having decreased unevenness in color and fluctuation in weight can be obtained.

摘要翻译： 本发明提供了与过去相比，细胞直径和膨胀率波动小的聚丙烯树脂预发泡颗粒。 预发泡颗粒通过具有聚丙烯树脂（A），三嗪骨架的化合物和三嗪骨架单元（B）的分子量至多为300的聚丙烯树脂组合物作为基础树脂而获得，并且作为随机组分 ，亲水性聚合物（C）和无机填料（D）和水作为发泡剂。 通过使用预发泡颗粒，可以获得具有减少的颜色不均匀性和重量波动的聚丙烯树脂模内膨胀制品。

公开(公告)号：US20140072813A1

公开(公告)日：2014-03-13

申请号：US14112503

申请日：2012-04-19

申请人： Mari Fujii ,  Tomonori Iwamoto ,  Masatoshi Hasegawa

发明人： Mari Fujii ,  Tomonori Iwamoto ,  Masatoshi Hasegawa

IPC分类号： C09D7/00

CPC分类号： C09D7/20 ,  B32B17/064 ,  B32B2379/08 ,  C08G73/14 ,  C08L79/08 ,  H01L29/78603 ,  H01L51/0096 ,  Y10T428/31623

摘要： An object of the present invention is to obtain a polyamide-imide solution that has a low linear thermal expansion coefficient, that is, an excellent linear thermal expansion coefficient, and that also is excellent in coating applicability. A further object of the present invention is to provide, with use of the polyamide-imide solution, a product or member which has high requirements for heat resistance and a low linear thermal expansion coefficient. In particular, the present invention is intended to provide a product or member that is suitably used for applications in which the polyamide-imide film obtained from the polyamide-imide solution of the present invention is formed on a surface of an inorganic material such as metal, metal oxide, or monocrystalline silicon.The above objects can be achieved by a polyamide-imide solution including: a specific polyamide-imide; and an organic solvent, the organic solvent being a mixture solvent of an amide solvent and a non-amide solvent, the non-amide solvent being at least one solvent selected from the group consisting of ether solvents, ketone solvents, ester solvents, glycol ether solvents, and glycol ester solvents.

摘要翻译： 本发明的目的是获得线性热膨胀系数低的线性热膨胀系数优异的涂布适用性优异的聚酰胺 - 酰亚胺溶液。 本发明的另一个目的是提供使用聚酰胺 - 酰亚胺溶液对耐热性要求高且线性热膨胀系数低的产品或部件。 特别地，本发明旨在提供适合用于将由本发明的聚酰胺 - 酰亚胺溶液获得的聚酰胺酰亚胺膜形成在无机材料如金属的表面上的应用的产品或部件 ，金属氧化物或单晶硅。 上述目的可以通过聚酰胺 - 酰亚胺溶液实现，包括：特定的聚酰胺 - 酰亚胺; 和有机溶剂，所述有机溶剂是酰胺溶剂和非酰胺溶剂的混合溶剂，所述非酰胺溶剂是选自醚溶剂，酮溶剂，酯溶剂，乙二醇醚中的至少一种溶剂 溶剂和乙二醇酯溶剂。

公开(公告)号：US20080153933A1

公开(公告)日：2008-06-26

申请号：US11795067

申请日：2005-12-21

申请人： Taro Kiguchi ,  Tomonori Iwamoto

发明人： Taro Kiguchi ,  Tomonori Iwamoto

IPC分类号： C08F210/06

CPC分类号： C08J9/232 ,  B29C44/445 ,  C08J2323/10

摘要： An object of the present invention is to provide an in-mold foamed article having good surface appearances and high rigidity produced by using a common molding machine that withstands a pressure of up to 0.4 MPa. The present invention provides polypropylene resin pre-expanded particles containing a base resin which is a resin having a melt flow rate of 5 g/10 min or more and 20 g/10 min or less and a melting point of 140° C. or higher and 155° C. or lower and satisfying the conditional formula below, and an in-mold foamed article produced from molding the pre-expanded particles: [Heat of crystal fusion (J/g)]≧1.2×[Melting point (° C.)]−96

摘要翻译： 本发明的目的是提供一种具有良好的表面外观和高刚性的模内发泡制品，其通过使用耐受高达0.4MPa的压力的普通成型机。 本发明提供聚丙烯树脂预发泡粒子，其含有熔体流动速率为5g / 10分钟以上且20g / 10分钟以下且熔点为140℃以上的树脂的基础树脂 和155℃以下，满足下述条件式，以及通过模制预发泡颗粒而制造的模内发泡制品：<？in-line-formula description =“In-line Formulas”end =“lead” α> [晶体熔化热（J / g）]> = 1.2×[熔点（℃）] - 96 <？在线公式描述=“在线公式”end =“tail”

公开(公告)号：US08088835B2

公开(公告)日：2012-01-03

申请号：US11659674

申请日：2005-07-27

申请人： Tomonori Iwamoto ,  Takayuki Gouda

发明人： Tomonori Iwamoto ,  Takayuki Gouda

IPC分类号： B29C44/34 ,  C08F110/00 ,  C08F210/00 ,  C08J9/16 ,  C08J9/22

CPC分类号： C08J9/232 ,  B29C44/445 ,  C08J2323/10 ,  C08L23/10 ,  C08L2203/14

摘要： It is an object of the present invention to provide a method for easily and economically producing an expansion-molded polypropylene-based resin article stably with a high porosity, that has continuous voids and that can be used as materials such as a sound absorbing material and a draining material. More specifically, the present invention relates to a method for producing an expansion-molded polypropylene-based resin article, in which a mold is filled with expanded polypropylene-based resin particles, and the expanded particles are heated and fused using water vapor, and then cooled, wherein expanded polypropylene-based resin particles are used in which a polypropylene-based resin having a melt index (MI) of not less than 0.1 g/10 minutes and not more than 9 g/10 minutes is used as a base resin, a cell size is not more than 150 μm, two melting peaks are present on a DSC curve obtained by differential scanning calorimetry, and β/(α+β) is not less than 0.35 and not more than 0.75 when taking a melting calorie at the lower temperature peak as α (J/g) and taking a melting calorie at the higher temperature peak as β (J/g), and a porosity of an obtained molded article is not less than 20% and not more than 50%.

摘要翻译： 本发明的目的是提供一种容易且经济地制造具有高孔隙率的稳定地发泡成型的聚丙烯类树脂制品的方法，该方法具有连续的空隙，并且可以用作诸如吸声材料的材料， 排水材料。 更具体地说，本发明涉及一种发泡聚丙烯类树脂制品的制造方法，其中模具填充有发泡聚丙烯基树脂颗粒，并且使用水蒸气加热和熔融发泡颗粒，然后 使用其中使用熔融指数（MI）不小于0.1g / 10分钟且不大于9g / 10分钟的聚丙烯基树脂作为基础树脂的发泡聚丙烯基树脂颗粒， 单元尺寸不大于150μm，通过差示扫描量热法获得的DSC曲线上存在两个熔融峰，并且当获得熔融卡路里时，＆bgr / /（α+＆bgr））不小于0.35且不大于0.75 在较低的温度峰值为α（J / g），并将较高温度峰值的溶解热量作为＆bgr; （J / g），所得成型体的孔隙率为20％以上且50％以下。

公开(公告)号：US08084509B2

公开(公告)日：2011-12-27

申请号：US11791344

申请日：2005-11-18

申请人： Tetsuya Shibata ,  Tomonori Iwamoto

发明人： Tetsuya Shibata ,  Tomonori Iwamoto

IPC分类号： C08J9/16 ,  C08J9/00 ,  B29C44/30

CPC分类号： C08J9/0061 ,  C08J2323/12 ,  C08J2323/16 ,  C08J2423/00 ,  C08J2423/16 ,  C08L23/10 ,  C08L2203/14 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2666/06

摘要： The present invention provides a pre-expanded particulate polyolefin-based resin capable of easily attaining satisfactory secondary expandability, satisfactory surface appearance, and satisfactory dimensional stability even when it is intended to obtain an in-mold expansion molded article having a thin-wall shape. The present invention provides a pre-expanded particulate polypropylene-based resin including a polypropylene-based resin X as a base resin, where the resin X includes a resin mixture of at least a polypropylene-based resin A having a melting point of 140° C. or lower and a polypropylene-based resin B having a melting point of 145° C. or higher, and the resin mixture is modified by an organic peroxide so as to have a melt index of 5 g/10 min or more and less than 20 g/10 min.

摘要翻译： 本发明提供一种即使在获得具有薄壁形状的模内发泡模制品的情况下，也能够容易地获得令人满意的二次膨胀性，令人满意的表面外观以及令人满意的尺寸稳定性的预发泡颗粒状聚烯烃系树脂。 本发明提供一种预发泡粒状聚丙烯系树脂，其包含作为基础树脂的聚丙烯系树脂X，其中树脂X包括至少具有140℃熔点的聚丙烯类树脂A的树脂混合物 熔点为145℃以上的聚丙烯系树脂B，通过有机过氧化物改性树脂混合物，使其熔融指数为5g / 10分钟以上且小于 20 g / 10 min

公开(公告)号：US08569390B2

公开(公告)日：2013-10-29

申请号：US11795067

申请日：2005-12-21

申请人： Taro Kiguchi ,  Tomonori Iwamoto

发明人： Taro Kiguchi ,  Tomonori Iwamoto

IPC分类号： C08J9/16 ,  C08J9/22 ,  C08L23/00

CPC分类号： C08J9/232 ,  B29C44/445 ,  C08J2323/10

摘要： An object of the present invention is to provide an in-mold foamed article having good surface appearances and high rigidity produced by using a common molding machine that withstands a pressure of up to 0.4 MPa. The present invention provides polypropylene resin pre-expanded particles containing a base resin which is a resin having a melt flow rate of 5 g/10 min or more and 20 g/10 min or less and a melting point of 140° C. or higher and 155° C. or lower and satisfying the conditional formula below, and an in-mold foamed article produced from molding the pre-expanded particles: [Heat of crystal fusion (J/g)]≧1.2×[Melting point (° C.)]−96.

摘要翻译： 本发明的目的是提供一种具有良好的表面外观和高刚性的模内发泡制品，其通过使用耐受高达0.4MPa的压力的普通成型机。 本发明提供聚丙烯树脂预发泡粒子，其含有熔体流动速率为5g / 10分钟以上且20g / 10分钟以下且熔点为140℃以上的树脂的基础树脂 155℃以下，满足下述条件式，通过模塑预发泡粒子制成的模内发泡体：[结晶熔化热（J / g）]> = 1.2×[熔点（° C）] - 96。