Process for producing α-substituted acrylic acid esters
    1.
    发明授权
    Process for producing α-substituted acrylic acid esters 有权
    制备α-取代的丙烯酸酯的方法

    公开(公告)号:US07067691B2

    公开(公告)日:2006-06-27

    申请号:US11016770

    申请日:2004-12-21

    IPC分类号: C07C69/62 C07C69/52

    CPC分类号: C07C67/08 C07C69/653

    摘要: A process for producing an α-substituted acrylic acid ester represented by the formula [1], wherein each of R1 and R2 is independently a hydrogen atom, methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, sec-butyl group, tert-butyl group, fluoromethyl group, difluoromethyl group, trifluoromethyl group, or perfluoroethyl group, includes reacting an α-substituted acrylic acid anhydride represented by the formula [7], with 1,1-bis(trifluoromethyl)-1,3-diol represented by the formula [2].

    摘要翻译: 由式[1]表示的α-取代的丙烯酸酯的制备方法,其中R 1和R 2各自独立地为氢原子,甲基, 乙基,正丙基,异丙基,正丁基,仲丁基,叔丁基,氟甲基,二氟甲基,三氟甲基或全氟乙基,包括使由α-取代的丙烯酸酐 式[7]与由式[2]表示的1,1-双(三氟甲基)-1,3-二醇组成。

    Process for producing alpha-substituted acrylic acid esters
    2.
    发明申请
    Process for producing alpha-substituted acrylic acid esters 有权
    制备α-取代的丙烯酸酯的方法

    公开(公告)号:US20050165249A1

    公开(公告)日:2005-07-28

    申请号:US11016770

    申请日:2004-12-21

    IPC分类号: C07C67/08 C07C67/03

    CPC分类号: C07C67/08 C07C69/653

    摘要: A process for producing an α-substituted acrylic acid ester represented by the formula [1], wherein each of R1 and R2 is independently a hydrogen atom, methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, sec-butyl group, tert-butyl group, fluoromethyl group, difluoromethyl group, trifluoromethyl group, or perfluoroethyl group, includes reacting an α-substituted acrylic acid anhydride represented by the formula [7], with 1,1-bis(trifluoromethyl)-1,3-diol represented by the formula [2].

    摘要翻译: 由式[1]表示的α-取代的丙烯酸酯的制备方法,其中R 1和R 2各自独立地为氢原子,甲基, 乙基,正丙基,异丙基,正丁基,仲丁基,叔丁基,氟甲基,二氟甲基,三氟甲基或全氟乙基,包括使由α-取代的丙烯酸酐 式[7]与由式[2]表示的1,1-双(三氟甲基)-1,3-二醇组成。

    Polymerizable acrylate compound containing hexafluorocarbinol group and polymer made therefrom
    3.
    发明授权
    Polymerizable acrylate compound containing hexafluorocarbinol group and polymer made therefrom 失效
    含有六氟甲醇基的可聚合的丙烯酸酯化合物和由其制备的聚合物

    公开(公告)号:US07750178B2

    公开(公告)日:2010-07-06

    申请号:US10563961

    申请日:2004-02-05

    IPC分类号: C07C69/52

    CPC分类号: C08F20/28 C07C69/653

    摘要: The present invention relates to a polymerizable acrylate compound represented by the general formula (1): (in the formula, R1 represents a hydrogen atom, halogen atom, hydrocarbon group or fluorine-containing alkyl group, R2 and R3 may be different or identical, and each of them independently is a hydrogen atom, fluorine atom, hydrocarbon group optionally branched, fluorine-containing alkyl group, aromatic group, or cyclic structure containing an aliphatic group and may contain oxygen or carbonyl bond) and a polymer compound obtained by using the same.

    摘要翻译: 本发明涉及由通式(1)表示的可聚合丙烯酸酯化合物:(式中,R1表示氢原子,卤素原子,烃基或含氟烷基,R2和R3可以不同或相同, 并且它们各自独立地为氢原子,氟原子,任选支化的烃基,含氟烷基,芳族基团或含有脂族基团的环状结构,并且可以含有氧或羰基键)和通过使用 相同。

    Novel polymerizable acrylate compound containing hexafluorocarbinol group and polymer made therefrom
    4.
    发明申请
    Novel polymerizable acrylate compound containing hexafluorocarbinol group and polymer made therefrom 失效
    含有六氟甲醇基的新型可聚合丙烯酸酯化合物和由其制备的聚合物

    公开(公告)号:US20060217507A1

    公开(公告)日:2006-09-28

    申请号:US10563961

    申请日:2004-02-05

    IPC分类号: C08F214/18 C07C69/52

    CPC分类号: C08F20/28 C07C69/653

    摘要: The present invention relates to a polymerizable acrylate compound represented by the general formula (1): (in the formula, R1 represents a hydrogen atom, halogen atom, hydrocarbon group or fluorine-containing alkyl group, R2 and R3 may be different or identical, and each of them independently is a hydrogen atom, fluorine atom, hydrocarbon group optionally branched, fluorine-containing alkyl group, aromatic group, or cyclic structure containing an aliphatic group and may contain oxygen or carbonyl bond) and a polymer compound obtained by using the same.

    摘要翻译: 本发明涉及由通式(1)表示的可聚合丙烯酸酯化合物:(式中,R 1表示氢原子,卤素原子,烃基或含氟烷基,R R 2和R 3可以不同或相同,它们各自独立地是氢原子,氟原子,任选支化的烃基,含氟烷基,芳族基团 ,或含有脂族基团的环状结构,并且可以含有氧或羰基键)和通过使用它们得到的高分子化合物。

    Process for producing α-substituted acrylic norbornanyyl compounds
    5.
    发明授权
    Process for producing α-substituted acrylic norbornanyyl compounds 有权
    制备α-取代的丙烯酸降冰片烷基化合物的方法

    公开(公告)号:US07385079B2

    公开(公告)日:2008-06-10

    申请号:US10995335

    申请日:2004-11-24

    IPC分类号: C07C69/52

    摘要: A process for producing an α-substituted acrylic norbornanyl compound represented by the formula [3] includes reacting an α-substituted acrylic acid anhydride represented by the formula [1] with a substituted norbornanyl alcohol represented by the formula [2]. wherein R1 represents a hydrogen atom, methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, sec-butyl group, tert-butyl group, fluoromethyl group, difluoromethyl group, trifluoromethyl group, or perfluoroethyl group, and wherein one of R2, R3 and R4 is a CF3C(CF3)(OH)CH2— group, and each of the other two of R2, R3 and R4 is a hydrogen.

    摘要翻译: 由式[3]表示的α-取代的丙烯酸降冰片烷基化合物的制备方法包括使由式[1]表示的α-取代的丙烯酸酐与由式[2]表示的取代的降冰片烷基酯反应。 其中R 1表示氢原子,甲基,乙基,正丙基,异丙基,正丁基,仲丁基,叔丁基,氟甲基,二氟甲基, 三氟甲基或全氟乙基,其中R 2,R 3和R 4之一是CF 3 N C(CF 3)(OH)CH 2 - 基团,R 2,R 3,R 3, R 4和R 4是氢。

    Process for producing alpha-substituted acrylic norbornanyyl compounds
    6.
    发明申请
    Process for producing alpha-substituted acrylic norbornanyyl compounds 有权
    制备α-取代的丙烯酸降冰片烷基化合物的方法

    公开(公告)号:US20050131248A1

    公开(公告)日:2005-06-16

    申请号:US10995335

    申请日:2004-11-24

    IPC分类号: C07C67/08 C07C69/52

    摘要: A process for producing an α-substituted acrylic norbornanyl compound represented by the formula [3] includes reacting an α-substituted acrylic acid anhydride represented by the formula [1] with a substituted norbornanyl alcohol represented by the formula [2]. wherein R1 represents a hydrogen atom, methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, sec-butyl group, tert-butyl group, fluoromethyl group, difluoromethyl group, trifluoromethyl group, or perfluoroethyl group, and wherein one of R2, R3 and R4 is a CF3C(CF3)(OH)CH2— group, and each of the other two of R2, R3 and R4 is a hydrogen.

    摘要翻译: 由式[3]表示的α-取代的丙烯酸降冰片烷基化合物的制备方法包括使由式[1]表示的α-取代的丙烯酸酐与由式[2]表示的取代的降冰片烷基酯反应。 其中R 1表示氢原子,甲基,乙基,正丙基,异丙基,正丁基,仲丁基,叔丁基,氟甲基,二氟甲基, 三氟甲基或全氟乙基,其中R 2,R 3和R 4之一是CF 3 N C(CF 3)(OH)CH 2 - 基团,R 2,R 3,R 3, R 4和R 4是氢。