摘要:
A propylenic polymer according to the present invention or a composition thereof have an excellent melt flowability and contains a less amount of stickiness-causing components, and also has a low modulus and is pliable, and is capable of providing a transparent molded article, thus being useful as a substitute for a pliable vinyl chloride resin. In addition, a molded article made therefrom exhibits an excellent heat seal performance at a low temperature, and is excellent in terms of transparency and rigidity. Specifically, it has an isotactic pentad fraction (mmmm), which indicates a stereoregulariry, of 30 to 80%, a molecular weight distribution (Mw/Mn) of 3.5 or less and an intrinsic viscosity [η] of 0.8 to 5 dl/g.
摘要翻译:根据本发明的丙烯聚合物或其组合物具有优异的熔体流动性并且含有较少量的粘着性成分,并且还具有低模量和柔韧性,并且能够提供透明模制品,因此是 可用作柔性氯乙烯树脂的替代物。 此外,由其制成的模制品在低温下表现出优异的热封性能,并且在透明性和刚性方面优异。 具体地说,其具有30至80%的立体有规配比的全同立构五单元组分数(mmmm),3.5或更小的分子量分布(Mw / Mn)和特性粘度η为0.8至5dl / g 。
摘要:
A propylenic polymer according to the present invention or a composition thereof have an excellent melt flowability and contains a less amount of stickiness-causing components, and also has a low modulus and is pliable, and is capable of providing a transparent molded article, thus being useful as a substitute for a pliable vinyl chloride resin. In addition, a molded article made therefrom exhibits an excellent heat seal performance at a low temperature, and is excellent in terms of transparency and rigidity. Specifically, it has an isotactic pentad fraction (mmmm), which indicates a stereoregulariry, of 30 to 80%, a molecular weight distribution (Mw/Mn) of 3.5 or less and an intrinsic viscosity [η] of 0.8 to 5 dl/g.
摘要翻译:根据本发明的丙烯聚合物或其组合物具有优异的熔体流动性并且含有较少量的粘着性成分,并且还具有低模量和柔韧性,并且能够提供透明模制品,因此是 可用作柔性氯乙烯树脂的替代物。 此外,由其制成的模制品在低温下表现出优异的热封性能,并且在透明性和刚性方面优异。 具体地说,其具有30至80%的立构规整性的全同立构五单元组分数(mmmm),3.5或更小的分子量分布(Mw / Mn)和特性粘度η为0.8至5dl / g 。
摘要:
A propylenic polymer according to the present invention or a composition thereof have an excellent melt flowability and contains a less amount of stickiness-causing components, and also has a low modulus and is pliable, and is capable of providing a transparent molded article, thus being useful as a substitute for a pliable vinyl chloride resin. In addition, a molded article made therefrom exhibits an excellent heat seal performance at a low temperature, and is excellent in terms of transparency and rigidity. Specifically, it has an isotactic pentad fraction (mmmm), which indicates a stereoregulariry, of 30 to 80%, a molecular weight distribution (Mw/Mn) of 3.5 or less and an intrinsic viscosity [η] of 0.8 to 5 dl/g.
摘要:
The propylene polymer of the present invention satisfies (1) a 25° C. hexane soluble content (H25) of 0-80 wt %; and (2) either no melting temperature (Tm) measurable by differential scanning calorimetry (DSC), or a melting temperature (Tm) satisfying, if measurable by DSC, the following relationship: ΔH≧3×(Tm−120) wherein ΔH is a melting endotherm (J/g). The propylene homopolymer of the present invention satisfies (1) a meso pentad fraction (mmmm) of 30-60 mol %; (2) a racemic pentad fraction (rrrr) satisfying the following relationship: [rrrr/(1−mmmm)]≦0.1; (3) a fraction (W25) eluted at a temperatures up to 25° C. by temperature-programmed chromatography, of from 20-100 wt %; and, (4) a pentad fraction (rmrm) of more than 2.5 mol %. The propylene copolymer of the present invention satisfies (1) a stereoregularity index (P) of 55-90 mol % as determined by 13C-NMR measurement; and (2) a fraction (W25) eluted at a temperatures up to 25° C. by temperature-programmed chromatography, of from 20-100 wt %.
摘要:
A propylenic polymer according to the present invention or a composition thereof have an excellent melt flowability and contains a less amount of stickiness-causing components, and also has a low modulus and is pliable, and is capable of providing a transparent molded article, thus being useful as a substitute for a pliable vinyl chloride resin. In addition, a molded article made therefrom exhibits an excellent heat seal performance at a low temperature, and is excellent in terms of transparency and rigidity. Specifically, it has an isotactic pentad fraction (mmmm), which indicates a stereoregulariry, of 30 to 80%, a molecular weight distribution (Mw/Mn) of 3.5 or less and an intrinsic viscosity [η] of 0.8 to 5 dl/g.
摘要翻译:根据本发明的丙烯聚合物或其组合物具有优异的熔体流动性并且含有较少量的粘着性成分,并且还具有低模量和柔韧性,并且能够提供透明模制品,因此是 可用作柔性氯乙烯树脂的替代物。 此外,由其制成的模制品在低温下表现出优异的热封性能,并且在透明性和刚性方面优异。 具体地说,其具有30至80%的立构规整性的全同立构五单元组分数(mmmm),3.5或更小的分子量分布(Mw / Mn)和特性粘度η为0.8至5dl / g 。
摘要:
A propylenic polymer according to the present invention or a composition thereof have an excellent melt flowability and contains a less amount of stickiness-causing components, and also has a low modulus and is pliable, and is capable of providing a transparent molded article, thus being useful as a substitute for a pliable vinyl chloride resin. In addition, a molded article made therefrom exhibits an excellent heat seal performance at a low temperature, and is excellent in terms of transparency and rigidity. Specifically, it has an isotactic pentad fraction (mmmm), which indicates a stereoregularity, of 30 to 80%, a molecular weight distribution (Mw/Mn) of 3.5 or less and an intrinsic viscosity [η] of 0.8 to 5 dl/g.
摘要翻译:根据本发明的丙烯聚合物或其组合物具有优异的熔体流动性并且含有较少量的粘着性成分,并且还具有低模量和柔韧性,并且能够提供透明模制品,因此是 可用作柔性氯乙烯树脂的替代物。 此外,由其制成的模制品在低温下表现出优异的热封性能,并且在透明性和刚性方面优异。 具体地说,其具有立构规整性的全同立构五单元组分数(mmmm)为30〜80%,分子量分布(Mw / Mn)为3.5以下,特性粘度η为0.8〜5dl / g 。
摘要:
The propylene polymer of the present invention satisfies (1) a 25° C. hexane soluble content (H25) of 0-80 wt %; and (2) either no melting temperature (Tm) measurable by differential scanning calorimetry (DSC), or a melting temperature (Tm) satisfying, if measurable by DSC, the following relationship: ΔH≧3×(Tm−120) wherein ΔH is a melting endotherm (J/g). The propylene homopolymer of the present invention satisfies (1) a meso pentad fraction (mmmm) of 30-60 mol %; (2) a racemic pentad fraction (rrrr) satisfying the following relationship: [rrrr/(1−mmmm)]≦0.1; (3) a fraction (W25) eluted at a temperatures up to 25° C. by temperature-programmed chromatography, of from 20-100 wt %; and, (4) a pentad fraction (rmrm) of more than 2.5 mol %. The propylene copolymer of the present invention satisfies (1) a stereoregularity index (P) of 55-90 mol % as determined by 13C-NMR measurement; and (2) a fraction (W25) eluted at a temperatures up to 25° C. by temperature-programmed chromatography, of from 20-100 wt %.
摘要:
A propylenic polymer according to the present invention or a composition thereof have an excellent melt flowability and contains a less amount of stickiness-causing components, and also has a low modulus and is pliable, and is capable of providing a transparent molded article, thus being useful as a substitute for a pliable vinyl chloride resin. In addition, a molded article made therefrom exhibits an excellent heat seal performance at a low temperature, and is excellent in terms of transparency and rigidity. Specifically, it has an isotactic pentad fraction (mmmm), which indicates a stereoregulariry, of 30 to 80%, a molecular weight distribution (Mw/Mn) of 3.5 or less and an intrinsic viscosity [η] of 0.8 to 5 dl/g.
摘要:
A novel double crosslinking type transition metal compound is herein disclosed which is represented by the general formula (I) wherein M is a metallic element in the groups 3 to 10 or a lanthanoide series of the periodic table; E1 and E2 are each a cyclopentadienyl group, an indenyl group or the like, and they form a crosslinking structure via A1 and A2; A1 and A2 are each a crosslinking group comprising a hydrocarbon group of one or more carbon atoms; X is a &sgr;-bonding ligand; and Y is a Lewis base. Also disclosed are a double crosslinking type biscyclopentadienyl derivative and bisindenyl derivative for use in the above-mentioned transition metal compound, its preparation process, a catalyst for olefin polymerization using the transition metal compound, and a preparation process of an olefin polymer by the use of this catalyst.
摘要:
The present invention relates to a transition metal compound represented by the general formula (I), and a olefin polymerization catalyst comprising above transition metal compound and activating co-catalyst as the main components. (wherein, M represents a metal element in the groups 3 to 10 of the periodic table or in the lanthanoide series, X represents a &sgr; bonding ligand bonded to M, Y represents a Lewis base, A represents a cross-linking group, p is an integer of 1 to 20, q is an integer of 1 to 5 and represents [(valence of M)−2], r is an integer of 0 to 3. R1 represents a group in above R2 to R9 except hydrogen atom). The present invention provides a transition metal compound useful for olefin polymerization catalyst, and olefin polymerization catalyst using above compound.