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公开(公告)号：US4954427A
公开(公告)日：1990-09-04
申请号：US60790
申请日：1987-06-12
申请人： Noriyuki Inoue , Tetsuro Kojima , Tatsuo Heki , Shigeo Hirano
发明人： Noriyuki Inoue , Tetsuro Kojima , Tatsuo Heki , Shigeo Hirano
CPC分类号： G03C1/48546 , G03C1/061 , G03C2001/108 , Y10S430/141
摘要： A process for the formation of direct positive images comprising (1) imagewise exposing to light, a light-sensitive material comprising a photographic emulsion layer containing unfogged internal latent image type silver halide particles on at least one support, and (2) developing the light-sensitive material in the presence of a nucleating agent and at least one nucleation accelerator of general formula (I):A--(Y).sub.n R].sub.m (I)wherein A represents a group which is adsorbed by a silver halide; Y represents a divalent linkage group consisting of atoms or atomic groups selected from the group consisting of a hydrogen atom, a carbon atom, a nitrogen atom, an oxygen atom, and a sulfur atom; R represents an organic group containing at least one of a thioether group, an amino group, an ammonium group, an ether group, and a heterocyclic group; n represents an integer of 0 or 1; and m represents an integer of 1 or 2 to form direct positive images.
摘要翻译： 一种用于形成直接阳性图像的方法，包括（1）成像曝光，包含在至少一个载体上含有未雾化的内部潜像型卤化银颗粒的照相乳剂层的感光材料，和（2）显影光 在存在成核剂和至少一种通式（I）的成核促进剂的情况下：A-（Y）nR] m（I）其中A表示被卤化银吸附的基团; Y表示由选自氢原子，碳原子，氮原子，氧原子和硫原子的原子或原子团组成的二价连接基团; R表示含有硫醚基，氨基，铵基，醚基和杂环基中的至少一个的有机基团; n表示0或1的整数; m表示1或2的整数，形成直接正像。
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2.发明授权Method for forming direct positive image comprising developing with a combination of a nucleating agent and a hydrazine derivative 失效用于形成直接阳性图像的方法，其包括用成核剂和肼衍生物的组合显影
公开(公告)号：US4880729A
公开(公告)日：1989-11-14
申请号：US91913
申请日：1987-09-01
申请人： Tatsuo Heki , Noriyuki Inoue , Shigeo Hirano
发明人： Tatsuo Heki , Noriyuki Inoue , Shigeo Hirano
CPC分类号： G03C1/48546
摘要： A method for forming a direct positive image by the steps of (a) imagewise exposing a light-sensitive material including a support having thereon at least one photographic emulsion layer containing a nonprefogged silver halide capable of forming an internal latent image and (b) developing the exposed material in the presence of a nucleating agent containing a combination of at least one quaternary heterocyclic compound and at least one hydrazine compound. The resulting direct positive has sufficiently high maximum density and low minimum density, and satisfactory stability over time.
摘要翻译： 一种用于通过以下步骤形成直接正像的方法：（a）使包含其上的支持体的感光材料成像曝光至少一个含有能够形成内部潜像的非反射卤化银的照相乳剂层和（b）显影剂 在含有至少一种四元杂环化合物和至少一种肼化合物的组合的成核剂存在下的暴露材料。 所得到的直接正极具有足够高的最大密度和低的最小密度，并且随着时间的推移令人满意的稳定性。
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3.发明授权Direct positive photographic materials and a method of forming direct positive images 失效直接的正性照相材料和形成直接正像的方法
公开(公告)号：US4948712A
公开(公告)日：1990-08-14
申请号：US184552
申请日：1988-06-07
IPC分类号： G03C7/30
CPC分类号： G03C7/3022 , G03C2200/20 , G03C7/3029 , Y10S430/156
摘要： The invention provides (1) direct positive photographic photosensitive materials in which at least one type of FR compound which releases fogging agent or development accelerator or a precursor thereof in accordance with the amount of silver developed when the silver halide is being developed is included in a direct positive photographic material comprising at least one layer of non-pre-fogged internal latent image type silver halide emulsion on a support, and (2) a method of forming direct positive images of which the distinguishing features are that in a method for the formation of direct positive images in which a direct positive photographic photosensitive material comprising at least one layer of non-pre-fogged internal latent image forming silver halide emulsion on a support is processed, after image exposure, in a surface developer, at least one type of FR compound which releases fogging agent or development accelerator or precursors thereof is included in the said photographic mateiral, and that the said photosensitive material is subjected to a fogging process and to a development process during and/or after the said fogging process.It is possible by means of this invention to obtain direct positive photographic materials which have excellent stability with respect to the passage of time and especially good stability with respect to the passage of time under conditions of high temperature and high humidity.Moreover, it is possible to obtain direct positive photographic materials and a method of forming direct positive images which have a high maximum image density and a high resolving power.Moreover, it is possible to obtain direct positive photographic materials and a method of forming direct positive images with which direct positive images which have a satisfactorily high color density can be obtained, even on processing in highly stable developers of low pH.
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公开(公告)号：US4859579A
公开(公告)日：1989-08-22
申请号：US149271
申请日：1988-01-28
申请人： Shigeo Hirano , Tetsuro Kojima , Mitsuru Yamamoto , Noriyuki Inoue , Tatsuo Heki
发明人： Shigeo Hirano , Tetsuro Kojima , Mitsuru Yamamoto , Noriyuki Inoue , Tatsuo Heki
IPC分类号： C07D219/02 , C07D219/04 , C07D219/06 , C07D219/08 , C07D221/12 , C07D221/16 , C07D221/18 , C07D401/04 , C07D401/12 , C07D413/12 , C07D417/12 , C07D471/04 , C07D491/04 , C07D495/04 , C07D513/04 , G03C1/06 , G03C1/36 , G03C1/485 , G03C8/08
CPC分类号： C07D401/04 , C07D219/02 , C07D219/04 , C07D219/06 , C07D219/08 , C07D221/12 , C07D221/16 , C07D221/18 , C07D401/12 , C07D413/12 , C07D417/12 , C07D471/04 , C07D491/04 , C07D495/04 , C07D513/04 , G03C1/067 , G03C1/48546 , Y10S430/141
摘要： A silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide photographic emulsion layer, wherein at least one layer selected from the emulsion layer and other hydrophilic colloid layers contains at least one alkynyl substituted heterocyclic quaternary ammonium salt represented by the following general formula (I): ##STR1## wherein Z represents a non-metallic atomic group necessary to form a substituted or unsubstituted 5-membered or 6-membered heterocyclic ring to which a aromatic ring or a heterocyclic ring may further be condensed; R.sup.1 represents a substituted or unsubstituted aliphatic group; X represents ##STR2## Q represents a non-metallic atomic group necessary to form a substituted or unsubstituted 4-membered to 12-membered non-aromatic hydrocarbon ring or substituted or unsubstituted non-aromatic heterocyclic ring; at least one of R.sup.1, a substituent for Z and a substituent for Q includes an alkynyl group; Y represents a counter ion necessary for charge balance; and n represents a number necessary to balance the charge.
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公开(公告)号：US4835091A
公开(公告)日：1989-05-30
申请号：US65353
申请日：1987-06-23
申请人： Noriyuki Inoue , Tatsuo Heki , Shigeo Hirano
发明人： Noriyuki Inoue , Tatsuo Heki , Shigeo Hirano
CPC分类号： G03C1/48538 , G03C1/48546 , G03C7/3022 , G03C7/407
摘要： A process for forming a direct positive image which comprises image-wise exposing a light-sensitive material comprising a support having provided thereon at least one internal latent image type direct positive silver halide photographic emulsion layer, subjecting the selecting material to whole surface exposure before or during developing process, and then developing the resulting material in the presence of a quaternary salt type nucleating agent or a hydrazine type nucleating agent.The process is very high in the latitude for changes of expose amount, developing time, developing solution components, process temperature and the like and makes it possible to progress the development is a short time even in a low pH developing solution.
摘要翻译： 一种用于形成直接正像的方法，该方法包括使包含具有至少一个内部潜像型直接正卤化银摄影乳剂层的支持体的感光材料成像曝光，使选择材料经受整个表面曝光之前或 在显影过程中，然后在季盐型成核剂或肼型成核剂的存在下显影所得材料。 该过程在曝光量，显影时间，显影液成分，加工温度等的变化的纬度上是非常高的，并且即使在低pH显影液中也可以进行短时间的发展。
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6.发明授权
公开(公告)号：US4877723A
公开(公告)日：1989-10-31
申请号：US117725
申请日：1987-11-06
申请人： Shigeo Hirano , Noriyuki Inoue , Tatsuo Heki
发明人： Shigeo Hirano , Noriyuki Inoue , Tatsuo Heki
CPC分类号： G03C1/48546 , Y10S430/141
摘要： A silver halide photographic material which comprises a support having provided thereon at least one photosensitive silver halide photographic emulsion layer, wherein the emulsion layer or at least one of the other hydrophilic colloid layers contains at least one of alkynyl-substituted heterocyclic quaternary ammonium salts represented by the formula: ##STR1## wherein Z represents a group of non-metallic atoms required to form a 5- to 6-membered heterocyclic ring, R.sup.1 represents an aliphatic group, R.sup.2, R.sup.3 and R.sup.4, which may be the same or different, each represents a hydrogen atom, an aliphatic group, or an aromatic group, at least one of R.sup.1, R.sup.2, R.sup.3, R.sup.4 and Z has at least one substituent having an alkynyl group, Y represents a counter ion for the charge balance, and n is a number required for charge balance.
摘要翻译： 一种卤化银照相材料，其包括其上提供有至少一个光敏卤化银照相乳剂层的载体，其中所述乳剂层或其它亲水胶体层中的至少一个包含至少一种炔基取代的杂环季铵盐 式（I）其中Z表示形成5-至6-元杂环所需的一组非金属原子，R 1表示脂族基团，R 2，R 3和R 4可以相同或不同， 不同的是，各自表示氢原子，脂族基团或芳香族基团，R 1，R 2，R 3，R 4和Z中的至少一个具有至少一个具有炔基的取代基，Y表示电荷平衡的抗衡离子， n是电荷平衡所需的数字。
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公开(公告)号：US4871653A
公开(公告)日：1989-10-03
申请号：US67850
申请日：1987-06-30
申请人： Noriyuki Inoue , Tatsuo Heki , Tetsuro Kojima
发明人： Noriyuki Inoue , Tatsuo Heki , Tetsuro Kojima
CPC分类号： G03C1/48546 , G03C5/305 , Y10S430/141
摘要： A process for forming a direct-positive image by developing an imagewise exposed photosensitive material, having on a support at least one photographic emulsion layer containing nonprefogged silver halide grains capable of forming an internal latent image, in which development is carried out in the presence of a combination of a nucleating agent and at least one compound having at least one mercapto group selected from a tetrazaindene, a triazaindene, and a pentaazaindene. The hydrogen atom of which mercapto group may optionally be further substituted with an alkali metal atom or an ammonium group. The invention process provides rapid and consistent formation of direct-positive images having high maximum density and low minimum density.
摘要翻译： 通过显影成像曝光的感光材料形成直接正像的方法，在载体上具有至少一个含有能够形成内部潜像的非离子卤化银颗粒的照相乳剂层，其中在存在 成核剂和至少一种具有至少一个巯基的化合物的组合，所述巯基选自四嗪，三氮杂茚和五氮杂茚。 巯基可以任选地被碱金属原子或铵基取代的氢原子。 本发明方法提供了快速且一致地形成具有高最大密度和低最小密度的直接正像。
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公开(公告)号：US4816290A
公开(公告)日：1989-03-28
申请号：US36450
申请日：1987-04-09
申请人： Tatsuo Heki , Noriyuki Inoue
发明人： Tatsuo Heki , Noriyuki Inoue
摘要： A process of forming a solid granular film is disclosed, which comprises dispersing solid granules into a liquid with the aid of a dispersant, removing the dispersant from the resulting dispersion to suspend the solid granules at the vapor-liquid interface, and transferring the solid granules onto a support, whereby high covering power is attained with respect to solid granules.
摘要翻译： 公开了一种形成固体颗粒膜的方法，其包括在分散剂的帮助下将固体颗粒分散在液体中，从所得分散体中除去分散剂以将固体颗粒悬浮在气液界面处，并将固体颗粒 到支撑体上，从而获得相对于固体颗粒的高覆盖力。
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公开(公告)号：US4933265A
公开(公告)日：1990-06-12
申请号：US317142
申请日：1989-02-23
申请人： Noriyuki Inoue , Tatsuo Heki , Tetsuro Kojima , Shinji Ueda
发明人： Noriyuki Inoue , Tatsuo Heki , Tetsuro Kojima , Shinji Ueda
IPC分类号： C07D235/28 , C07D249/12 , C07D263/58 , C07D285/12 , C07D285/125 , C07D285/135 , C07D521/00 , G03C1/485 , G03C7/392 , G03C7/413
CPC分类号： C07D263/58 , C07D231/12 , C07D233/56 , C07D235/28 , C07D249/08 , C07D249/12 , C07D285/125 , C07D285/135 , G03C1/48546 , G03C7/3924 , G03C7/413
摘要： A process for forming a direct positive color image is disclosed, the process comprising imagewise exposing a photosensitive material containing at least one emulsion layer of silver halide of internal latent image type, which has not been preliminarily fogged, and a color image-forming coupler; developing said material using a surface developing solution containing an aromatic primary amine color developing agent in the presence of a nucleating agent and/or in the condition that fogging exposure is carried out prior to the developing step or during the developing step; bleaching; and fixing, wherein said color coupler is a compound which is in itself substantially nondiffusible, and capable of forming or releasing a substantially nondiffusible dye upon oxidative coupling with said aromatic primary amine color developing agent and said development processing is carried out at a pH of 11.5 or less using a developing solution containing substantially no benzyl alcohol in the presence of at least one compound selected from the group consisting of the compounds represented by the general formula (I)A[(Y.sup.1).sub.n R].sub.m
摘要翻译： 公开了一种用于形成直接正彩色图像的方法，该方法包括成像曝光含有至少一种尚未预先雾化的内部潜像型卤化银乳剂层的感光材料和彩色成像耦合器; 在成核剂存在下和/或在显影步骤之前或显影步骤中进行雾化曝光的条件下，使用含有芳族伯胺彩色显影剂的表面显影溶液显影所述材料; 漂; 和固定，其中所述着色剂是本身基本上不可扩散的化合物，并且能够在与所述芳族伯胺显色剂氧化偶联时形成或释放基本上不可扩散的染料，并且所述显影处理在pH为11.5的条件下进行 或更少使用在至少一种选自由通式（I）A [（Y1）nR] m表示的化合物组成的组的存在下，基本上不含苄醇的显影溶液
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公开(公告)号：US4789627A
公开(公告)日：1988-12-06
申请号：US66049
申请日：1987-06-23
申请人： Noriyuki Inoue , Tatsuo Heki , Shinji Ueda
发明人： Noriyuki Inoue , Tatsuo Heki , Shinji Ueda
CPC分类号： G03C7/3022 , G03C1/48576
摘要： In a method for forming a direct positive color image which comprises image-wise exposing to light a light-sensitive material comprising a support having provided thereon at least one photographic emulsion layer contaiing unfogged internal latent image type silver halide grains and a color image-forming coupler; developing the light-sensitive material with a surface developing solution containing an aromatic primary amine type color developing agent in the presence of a nucleating agent and/or fogging exposure; bleaching and fixing the resulting material to form the direct positive color image, the improvement is characterized in that the developing solution has a pH of 11.5 or less and does not substantially contain benzyl alcohol; the color coupler is a compound which forms or releases a substantially non-diffusive dye by oxidation coupling with a developing agent, and the internal latent image type silver halide grains have a particular core/shell structure.According to the method, a direct positive color image having a high maximum color density and a low minimum image density can be obtained in a short time.
摘要翻译： 在用于形成直接正彩色图像的方法中，其包括以光学方式曝光的感光材料，所述感光材料包括其上提供有至少一个不含有无内部潜像型卤化银颗粒的照相乳剂层的支持体和彩色图像形成 耦合器 在成核剂和/或雾化曝光的存在下用含有芳族伯胺型彩色显影剂的表面显影液显影感光材料; 漂白和固定所得材料以形成直接正彩色图像，其改进的特征在于显影液的pH为11.5或更低，基本不含苄醇; 彩色成色剂是通过与显影剂氧化偶联形成或释放基本上非扩散性染料的化合物，并且内部潜像型卤化银颗粒具有特定的核/壳结构。 根据该方法，可以在短时间内获得具有高最大色彩浓度和低最小图像浓度的直接正彩色图像。
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