Abstract:
Provided is a separator for a non-aqueous secondary battery containing a porous substrate; and a porous layer that is provided on one side of the porous substrate, and that contains a resin and a filler, in which a shrinkage ratio in a MD direction, when heat-treated at 100° C. for 30 minutes under no tension, is more than 1.2% and less than or equal to 3.5%.
Abstract:
The separator for a non-aqueous secondary battery which includes a porous substrate, and an adhesive porous layer that is provided on one side or both sides of the porous substrate and that contains a polyvinylidene fluoride type resin, the adhesive porous layer further contains (1) a carboxylic anhydride, a resin that contains a carboxylic anhydride as a monomer component, or a combination thereof, and (2) a resin that contains a hydroxyl group or an amino group.
Abstract:
Provided is a separator for a non-aqueous secondary battery, the separator contains a porous substrate and an adhesive porous layer that is provided on one side or on both sides of the porous substrate, and that contains a polyvinylidene fluoride type resin and a filler, in which the porous substrate contains a fluorine atom, and when differential scanning calorimetry is performed with all of the polyvinylidene fluoride type resin contained in the adhesive porous layer as a sample, two or more endothermic peaks and/or two or more exothermic peaks are observed.
Abstract:
An embodiment of the present invention provides a separator for a non-aqueous secondary battery containing a porous substrate; a heat-resistant porous layer that is provided on one side or on both sides of the porous substrate, and that contains a binder resin and inorganic particles, the inorganic particles having an average primary particle diameter from 0.01 μm to less than 0.45 μm; and an adhesive layer that is provided on one side or on both sides of a laminated body of the porous substrate and the heat-resistant porous layer, and adhesive resin particles adhered to the laminated body.
Abstract:
Provided is a separator for a non-aqueous secondary battery containing a porous substrate; and a heat resistant porous layer that is provided on one side or on both sides of the porous substrate, and that contains a binder resin and barium sulfate particles, in which an average primary particle size of the barium sulfate particles contained in the heat resistant porous layer is from 0.01 μm to less than 0.30 μm.
Abstract:
A separator for a non-aqueous secondary battery, containing a porous substrate, and an adhesive porous layer that is provided on one side or both sides of the porous substrate, in which the adhesive porous layer contains a polyvinylidene fluoride type resin including a vinylidene fluoride monomer unit and a hexafluoropropylene monomer unit, and the polyvinylidene fluoride type resin has an acid value of from 3.0 mgKOH/g to 20 mgKOH/g.
Abstract:
Provided is a separator for a non-aqueous secondary battery, including: a porous substrate, and a heat resistant porous layer that is provided on one side or both sides of the porous substrate, that is an aggregate of resin particles and an inorganic filler, and that satisfies the following expression (1). In expression (1), Vf is a volume proportion (% by volume) of the inorganic filler in the heat resistant porous layer, and CPVC is a critical pigment volume concentration (% by volume) of the inorganic filler. Also provided is a separator for a non-aqueous secondary battery, including: a porous substrate, a heat resistant porous layer that is provided on one side or both sides of the porous substrate, that includes a resin and an filler, and that satisfies the following expression (2), and an adhesive porous layer that is provided on both sides of a stacked body of the porous substrate and the heat resistant porous layer, and that includes an adhesive resin. In expression (2), Vf is a volume proportion (% by volume) of the filler in the heat resistant porous layer, and CPVC is a critical pigment volume concentration (% by volume) of the filler. 0.65≤Vf/CPVC≤0.99 expression (1) 0.40≤Vf/CPVC≤0.99 expression (2)
Abstract:
The present invention provides a separator for a non-aqueous secondary battery, the separator including: a polyolefin microporous membrane having a degree of crystallinity of from 60 to 85% and a tie molecular volume fraction of from 0.7 to 1.7%; and a heat resistant porous layer containing a heat resistant resin and provided on one side or both sides of the polyolefin microporous membrane.
Abstract:
A separator for a non-aqueous secondary battery contains: a porous layer that is provided on only one side of the porous substrate, and that contains a resin having at least one bonding group selected from an amide bond, an imide bond, and a sulfonyl bond, in which, in the porous substrate, an absolute value of a difference between a temperature of an endothermic peak observed at 120° C. to 145° C. in a temperature raising process 1, and a temperature of an endothermic peak observed at 120° C. to 145° C. in a temperature raising process 2, is 1.50° C. or higher in DSC measurement when the temperature raising process 1 of continuously raising the temperature from 30° C. to 200° C. at a temperature change rate of 5° C./min in a nitrogen atmosphere, and the temperature raising process 2 of lowering the temperature from 200° C. to 30° C. and raising the temperature from 30° C. to 200° C., are performed.
Abstract:
Provided is a separator for a non-aqueous secondary battery containing a porous substrate; and an adhesive porous layer that is provided on one side or on both sides of the porous substrate, and that contains a polyvinylidene fluoride type resin, an acrylic type resin and metal sulfate particles, in which an average primary particle diameter of the metal sulfate particles contained in the adhesive porous layer is from 0.01 μm to less than 0.30 μm.