摘要:
A hydrogenated product of an aromatic vinyl polymer, wherein the hydrogenation rate of the aromatic rings thereof is at least 97%, a ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) is at most 2.0, the weight average molecular weight (Mw) is 100,000 to 300,000, and the content of a component having a molecular weight (M) of at most 10,000 is at most 2% by weight based on the total weight of the polymer; a hydrogenated product of an aromatic vinyl polymer, wherein the content of foreign matter having a particle diameter of at least 0.5 &mgr;m in the hydrogenated polymer is at most 3.0×104 particles/g; and a substrate for information recording media obtained by molding a resin material containing a hydrogenated product of an aromatic vinyl polymer, wherein the hydrogenation rate of the aromatic rings thereof is at least 97%, a :ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) is at most 2.0, and the weight average molecular weight (Mw) is 100,000 to 300,000, and production process thereof.
摘要:
A molded or formed product obtained by molding or forming a resin composition comprising (A) at least one vinyl cyclic hydrocarbon polymer selected from the group consisting of hydrogenated products of aromatic vinyl polymers, vinylcyclohexene polymers or hydrogenated products thereof, and vinylcyclohexane polymers, and (B) at least one substance selected from the group consisting of compounding additives incompatible with the polymer, organic compounds having at least one alcoholic hydroxyl group and at least one ether linkage, and organic compounds having at least one alcoholic hydroxyl group and at least one ester linkage, wherein the initial light transmittance (a) of the molded or formed product at an optional wavelength within a range of 400 to 800 nm and the light transmittance (b) of the molded or formed product after the molded or formed product is held for 1,000 hours in an atmosphere of 65° C. in temperature and 90% in relative humidity satisfy the relationship of the equation (1): [(b)/(a)]×100≧70 (1) and a resin composition.
摘要:
A molded or formed product obtained by molding or forming a resin composition comprising (A) at least one vinyl cyclic hydrocarbon polymer selected from the group consisting of hydrogenated products of aromatic vinyl polymers, vinylcyclohexene polymers or hydrogenated products thereof, and vinylcyclohexane polymers, and (B) at least one substance selected from the group consisting of compounding additives incompatible with the polymer, organic compounds having at least one alcoholic hydroxyl group and at least one ether linkage, and organic compounds having at least one alcoholic hydroxyl group and at least one ester linkage, wherein the initial light transmittance (a) of the molded or formed product at an optional wavelength within a range of 400 to 800 nm and the light transmittance (b) of the molded or formed product after the molded or formed product is held for 1,000 hours in an atmosphere of 65° C. in temperature and 90% in relative humidity satisfy the relationship of the equation (1): [(b)/(a)]×100≧70 (1) and a resin composition.
摘要:
A molded or formed product obtained by molding or forming a resin composition comprising (A) at least one vinyl cyclic hydrocarbon polymer selected from the group consisting of hydrogenated products of aromatic vinyl polymers, vinylcyclohexene polymers or hydrogenated products thereof, and vinylcyclohexane polymers, and (B) at least one substance selected from the group consisting of compounding additives incompatible with the polymer, organic compounds having at least one alcoholic hydroxyl group and at least one ether linkage, and organic compounds having at least one alcoholic hydroxyl group and at least one ester linkage, wherein the initial light transmittance (a) of the molded or formed product at an optional wavelength within a range of 400 to 800 nm and the light transmittance (b) of the molded or formed product after the molded or formed product is held for 1,000 hours in an atmosphere of 65° C. in temperature and 90% in relative humidity satisfy the relationship of the equation (1): [(b)/(a)]×100≧70 (1) and a resin composition.
摘要:
A resin obtained by subjecting a norbornene type monomer having an aromatic ring structure (e.g. 5-phenyl-2-norbornene) to ring-opening polymerization and hydrogenating 95% or more of the unsaturated bonds in the backbone structure of the resulting polymer by the use of a catalyst composed of a combination of a transition metal compound and an alkyl metal compound, while leaving 80% or more of the aromatic ring structures, which resin has not only a high refractive index but also characteristics of a hydrogenated norbornene ring-opening polymerization product, i.e., excellent heat resistance, transparency, low birefringent properties, weather resistance, light resistance, low water absorption properties, moisture resistance, small dielectric constant, small dielectric loss, chemical resistance, etc., said resin being usable in optical materials, medical tools and materials, tools and materials for treating electronic parts, etc.
摘要:
The present invention provides a hydrogenated polycyclic norbornene ring-opening polymer which is excellent in heat resistance, optical characteristics and processability which comprises recurring units represented by the following formula [I] and [II] or these recurring units substituted with alkyl in an amount of at least 10 mol % based on total polymer units and has an intrinsic viscosity [.eta.] of 0.01-20 dl/g measured in toluene at 25.degree. C., with at least 50% of C--C bonds which constitute main chain being single bonds: ##STR1## wherein --denotes a double bond or a single bond.
摘要:
The object of the present invention is to provide a cycloolefin-based polymer with very low content of foreign matters, a molded article obtained by using the cycloolefin-based polymer, and a process for producing the cycloolefin-based polymer. The present invention relates to a cycloolefin-based polymer which has an intrinsic viscosity [&eegr;] of 0.01-20 dl/g as determined in decalin at 80° C. and has a content of foreign matters having a particle diameter of 0.5 &mgr;m or more of 3×104 particles/g or less, a process for producing the cycloolefin-based polymer, and a molded material comprising the cycloolefin-based polymer and a molded article obtained therefrom.
摘要:
A process for producing a polymer by ring-opening polymerization of a norbornene-type monomer, which comprises starting the ring-opening polymerization in the presence of a Ziegler-type catalyst consisting essentially of an organometallic compound of a metal belonging to the groups I to III of the periodic table and titanium tetrahalide, carrying out the ring-opening polymerization until the norbornene-type monomer shows a conversion ratio of not less than 60%, and then adding a tungsten and/or molybdenum-based metathesis catalyst to the polymerization reaction system to continue the ring-opening polymerization.
摘要:
A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of main-chain carbon-carbon double bonds of a ring-open polymer which is obtained by ring-opening polymerization of 2-norbornene is disclosed. The hydrogenated norbornene ring-open polymer has a weight average molecular weight (Mw) determined by gel permeation chromatography (GPC) of 50,000 to 200,000, a molecular weight distribution (Mw/Mn) of 1.5 to 10.0, and a melting point of 110 to 145° C. Also disclosed is a hydrogenated norbornene ring-open polymer (hydrogenated polymer) obtained by hydrogenating 80% or more of carbon-carbon double bonds of a ring-open polymer which is obtained by ring-opening copolymerization of 2-norbornene and a substituent-containing norbornene monomer, wherein the proportion of a repeating unit (A) derived from the 2-norbornene with respect to all repeating units is 90 to 99 wt % and the proportion of a repeating unit (B) derived from the substituent-containing norbornene monomer with respect to all repeating units is 1 to 10 wt %. The hydrogenated ring-open polymer has a melting point of 110 to 145° C. A resin composition and a molding material containing these hydrogenated polymers, a molded article, a resin film, a resin sheet, a multilayer laminate, a packing material, a molded article for medical supplies, a blister molding sheet, a blister molded article, and a multilayer blow-molded container made of these hydrogenated polymers are also disclosed.
摘要:
A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of main-chain carbon-carbon double bonds of a ring-open polymer obtained by ring-opening polymerization of 2-norbornene. The hydrogenated norbornene ring-open polymer has a weight average molecular weight determined by gel permeation chromatography (GPC) of 50,000 to 200,000, a molecular weight distribution of 1.5 to 10.0, and a melting point of 110 to 145° C. A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of carbon-carbon double bonds of a ring-open polymer obtained by ring-opening copolymerization of 2-norbornene and a substituent-containing norbornene monomer, wherein the proportion of a repeating unit (A) derived from the 2-norbornene with respect to all repeating units is 90 to 99 wt % and the proportion of a repeating unit (B) derived from the substituent-containing norbornene monomer with respect to all repeating units is 1 to 10 wt %. A resin composition and a molding material.