公开(公告)号：US4122052A

公开(公告)日：1978-10-24

申请号：US774549

申请日：1977-03-04

申请人： Tetsuo Aihara ,  Yasuharu Nakayama ,  Yoshio Yamashita ,  Tadashi Watanabe ,  Isao Toyomoto

发明人： Tetsuo Aihara ,  Yasuharu Nakayama ,  Yoshio Yamashita ,  Tadashi Watanabe ,  Isao Toyomoto

IPC分类号： C08F2/30 ,  C09D4/06 ,  C09D7/45 ,  C08L91/00

CPC分类号： C09D7/02 ,  C08F2/30 ,  C09D4/06

摘要： An emulsion composition prepared by the emulsion polymerization of a polymerizable vinyl monomer in the presence of an emulsifier characterized in that the emulsifier is a neutralized copolymer of (A) a monomer prepared by being allowed at least one glycidyl ester of arcylic acid and methacrylic acid to react with at least one fatty acid of drying oil fatty acid and semi-drying oil fatty acid, (B) .alpha.,.beta.-ethylenically unsaturated acid and (C) an unsaturated monomer containing substantially no carboxyl group and having a Q value of at least 0.1 as determined by Q-e theory.

摘要翻译： 通过在乳化剂存在下通过可聚合乙烯基单体的乳液聚合制备的乳液组合物，其特征在于所述乳化剂是（A）通过使至少一种甲酰胺和甲基丙烯酸的至少一种缩水甘油酯与甲基丙烯酸制备的单体的中和共聚物， 与干性油脂肪酸和半干性油脂肪酸的至少一种脂肪酸反应，（B）α，β-烯键式不饱和酸和（C）基本上不含羧基并且具有至少Q值的不饱和单体 0.1由Qe理论确定。

公开(公告)号：US3993612A

公开(公告)日：1976-11-23

申请号：US559770

申请日：1975-03-19

申请人： Tetsuo Aihara ,  Tadashi Watanabe ,  Yasuharu Nakayama ,  Yoshio Yamashita ,  Isao Toyomoto

发明人： Tetsuo Aihara ,  Tadashi Watanabe ,  Yasuharu Nakayama ,  Yoshio Yamashita ,  Isao Toyomoto

IPC分类号： C08J3/02 ,  C08F220/28 ,  C08L13/00 ,  C08L33/06 ,  C09D4/00 ,  C09D121/00 ,  C09D133/14 ,  C09D157/00 ,  C09D201/00 ,  C09D201/02 ,  C09D201/08 ,  C08L91/00

CPC分类号： C09D133/14 ,  C08F220/28 ,  C09D157/00 ,  C08L13/00 ,  C08L33/06

摘要： In an aqueous coating composition comprising a vinyl polymer emulsion prepared by subjecting a vinyl monomer to emulsion polymerization in an aqueous medium in the presence of maleinized polybutadiene used as a dispersion stabilizer, an improvement which is characterized in that at least one copolymer is further incorporated, said copolymer being composed of (A) at least one monomer prepared by reacting one glycidyl ester of acrylic acid and methacrylic acid with at least one fatty acid of drying oil fatty acid and semi-drying oil fatty acid, (B) at least one .alpha.,.beta.-ethylenically unsaturated acid and (C) at least one unsaturated monomer containing substantially no carboxyl group and having a Q value of at least 0.1 as determined by Q-e theory.

摘要翻译： 在包含乙烯基聚合物乳液的水性涂料组合物中，其改进在于进一步引入至少一种共聚物，该乙烯基聚合物乳液是通过使乙烯基单体在含水介质中进行乳液聚合而制备的，所述聚合物乳液在用作分散稳定剂的马来化聚丁二烯存在下， 所述共聚物由（A）至少一种通过丙烯酸缩水甘油酯和甲基丙烯酸与干性油脂肪酸和半干性油脂肪酸的至少一种脂肪酸反应制备的单体，（B）至少一种α ，β-烯键式不饱和酸和（C）至少一种不含羧基的不饱和单体，并通过Qe理论确定Q值至少为0.1。

公开(公告)号：US4073758A

公开(公告)日：1978-02-14

申请号：US718767

申请日：1976-08-30

申请人： Yasuharu Nakayama ,  Tadashi Watanabe ,  Yoshio Yamashita ,  Tetsuo Aihara ,  Isao Toyomoto

发明人： Yasuharu Nakayama ,  Tadashi Watanabe ,  Yoshio Yamashita ,  Tetsuo Aihara ,  Isao Toyomoto

IPC分类号： C08F2/00 ,  C08F2/24 ,  C08J3/02 ,  C09D5/00 ,  C09D5/02 ,  C09D157/00 ,  C08L63/10

CPC分类号： C09D157/00 ,  C08F2/24

摘要： An emulsion composition prepared by the emulsion polymerization of a polymerizable vinyl monomer in the presence of an emulsifier characterized in that the emusifier is a neutralized maleate, partial maleate, fumarate or partial fumarate of an addition polymerization polymer having as a side chain a drying oil fatty acid residue and/or semi-drying oil fatty acid residue linked to the main chain of the polymer by an ester bond.

摘要翻译： 通过在乳化剂存在下通过可聚合乙烯基单体的乳液聚合制备的乳液组合物，其特征在于，所述乳化剂是中和的马来酸盐，部分马来酸盐，富马酸盐或部分富马酸盐，所述加聚聚合物具有作为侧链的干性油脂肪 通过酯键与聚合物的主链连接的酸残基和/或半干性油脂肪酸残基。

公开(公告)号：US4312797A

公开(公告)日：1982-01-26

申请号：US160739

申请日：1980-06-18

申请人： Tetsuo Aihara ,  Yasuharu Nakayama ,  Kuninosuke Nakanishi ,  Yoshio Yamashita ,  Isao Toyomoto

发明人： Tetsuo Aihara ,  Yasuharu Nakayama ,  Kuninosuke Nakanishi ,  Yoshio Yamashita ,  Isao Toyomoto

IPC分类号： C08F220/00 ,  C08F220/04 ,  C08F220/10 ,  C08F220/40 ,  C08F242/00 ,  C08L33/10 ,  C09D133/04 ,  C09D133/06 ,  C09D133/14 ,  C08L91/00 ,  C09D3/80 ,  C09D5/02

CPC分类号： C09D133/064 ,  C08F220/40 ,  C08F242/00 ,  C09D133/14 ,  C08L33/10 ,  Y10T428/31692 ,  Y10T428/31855 ,  Y10T428/31935 ,  Y10T428/31938

摘要： An aqueous coating composition comprising a resin in a water-soluble or water-dispersible form as a film-forming component, said resin being a copolymer of (A) a fatty acid-modified acrylic monomer comprising the reaction product of an unsaturated fatty acid having at least two non-conjugated double bonds with a hydroxyl-containing acrylic or methacrylic ester, (B) an .alpha.,.beta.-ethylenically unsaturated carboxylic acid, and (C) an unsaturated monomer having a Q value, determined by the Q-e theory, of at least 0.1.

摘要翻译： 一种水性涂料组合物，其包含水溶性或水分散形式的树脂作为成膜组分，所述树脂是（A）脂肪酸改性的丙烯酸单体的共聚物，其包含不饱和脂肪酸的反应产物，其具有 至少两个具有含羟基的丙烯酸或甲基丙烯酸酯的非共轭双键，（B）α，β-烯键式不饱和羧酸和（C）具有由Qe理论确定的Q值的不饱和单体， 至少0.1。

公开(公告)号：US4134956A

公开(公告)日：1979-01-16

申请号：US539442

申请日：1975-01-08

申请人： Yoshinori Suzuki ,  Akihiko Asayama ,  Fumio Dohi ,  Takaharu Takahashi ,  Isao Toyomoto

发明人： Yoshinori Suzuki ,  Akihiko Asayama ,  Fumio Dohi ,  Takaharu Takahashi ,  Isao Toyomoto

IPC分类号： B32B13/04 ,  C04B28/04 ,  C04B41/50 ,  C04B41/52 ,  C04B41/65 ,  C04B41/70 ,  C09D1/06 ,  B28B1/16

CPC分类号： C04B41/009 ,  C04B28/04 ,  C04B41/5079 ,  C04B41/52 ,  C04B41/65 ,  C04B41/70 ,  C04B2111/00482 ,  Y10S264/57

摘要： A decorative coating layer, unified with the succulent and fragile surface of a concrete board, is formed by a method comprising laminating an inorganic and hydraulic coating material on the surface of an unhardened concrete board placed in a mold, and immediately thereafter heat-curing the thus coated concrete board. According to this method, beautifully dressed precast concrete boards can be mass-produced by a shortened process with improved efficiency of operation.

摘要翻译： 通过以下方法形成与混凝土板的多汁且脆弱的表面一体的装饰涂层，该方法包括将无机和液压涂料层压在放置在模具中的未硬化混凝土板的表面上，然后立即热固化 从而涂层混凝土板。 根据该方法，通过缩短工艺可以大幅度地生产精美的预制混凝土板，提高了操作效率。