公开(公告)号：US20110111288A1

公开(公告)日：2011-05-12

申请号：US13002090

申请日：2009-12-01

申请人： Tetsuo Nishida ,  Megumi Tomisaki ,  Kazuhiko Shogami ,  Hideki Nakashima ,  Hirofumi Suzuki ,  Takashi Fujii

发明人： Tetsuo Nishida ,  Megumi Tomisaki ,  Kazuhiko Shogami ,  Hideki Nakashima ,  Hirofumi Suzuki ,  Takashi Fujii

IPC分类号： H01M10/02 ,  C01B25/10 ,  H01M10/0561

CPC分类号： H01M10/052 ,  C01B25/455 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/0025 ,  H01M2300/0091 ,  Y02E60/122 ,  Y02P70/54

摘要： To provide a technique for simply and easily producing a high-purity difluorophosphate and provide a production process of an electrolytic solution using the obtained difluorophosphate, an electrolytic solution and a secondary battery.A process for producing a difluorophosphate, comprising the following step (1) or (2): (1) reacting (A) at least one member selected from the group consisting of oxoacids, oxoacid anhydrides and oxyhalides of phosphorus with (B) a hexafluorophosphate in the presence of hydrogen fluoride, or (2) reacting at least one halide selected from the group consisting of alkali metal halides, alkaline earth metal halides, aluminum halides and onium halides with difluorophosphoric acid in the presence of a hexafluorophosphate. Also, a nonaqueous electrolytic solution containing the obtained difluorophosphate, and a nonaqueous electrolytic secondary battery containing the nonaqueous electrolytic solution.

公开(公告)号：US09203106B2

公开(公告)日：2015-12-01

申请号：US13110564

申请日：2011-05-18

申请人： Tetsuo Nishida ,  Megumi Tomisaki ,  Kazuhiko Shogami ,  Hideki Nakashima ,  Hirofumi Suzuki ,  Takashi Fujii

发明人： Tetsuo Nishida ,  Megumi Tomisaki ,  Kazuhiko Shogami ,  Hideki Nakashima ,  Hirofumi Suzuki ,  Takashi Fujii

IPC分类号： H01M10/02 ,  H01M10/052 ,  C01B25/455 ,  H01M10/0569 ,  H01M10/0567

CPC分类号： H01M10/052 ,  C01B25/455 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/0025 ,  H01M2300/0091 ,  Y02E60/122 ,  Y02P70/54

摘要： To provide a technique for simply and easily producing a high-purity difluorophosphate and provide a production process of an electrolytic solution using the obtained difluorophosphate, an electrolytic solution and a secondary battery.A process for producing a difluorophosphate, comprising the following step (1) or (2): (1) reacting (A) at least one member selected from the group consisting of oxoacids, oxoacid anhydrides and oxyhalides of phosphorus with (B) a hexafluorophosphate in the presence of hydrogen fluoride, or (2) reacting at least one halide selected from the group consisting of alkali metal halides, alkaline earth metal halides, aluminum halides and onium halides with difluorophosphoric acid in the presence of a hexafluorophosphate. Also, a nonaqueous electrolytic solution containing the obtained difluorophosphate, and a nonaqueous electrolytic secondary battery containing the nonaqueous electrolytic solution.

摘要翻译： 提供一种简单且容易地生产高纯度二氟磷酸盐的技术，并提供使用所得二氟磷酸盐，电解液和二次电池的电解液的生产方法。 一种制备二氟磷酸盐的方法，包括以下步骤（1）或（2）：（1）使（A）选自含氧酸，含氧酸酐和磷卤氧化物中的至少一种与（B）六氟磷酸盐 在氟化氢存在下，或（2）在六氟磷酸盐存在下使选自碱金属卤化物，碱土金属卤化物，卤化铝和卤化铪中的至少一种卤化物与二氟磷酸反应。 另外，含有所得二氟磷酸盐的非水电解液和含有非水电解液的非水电解二次电池。

公开(公告)号：US20110223488A1

公开(公告)日：2011-09-15

申请号：US13110564

申请日：2011-05-18

申请人： Tetsuo Nishida ,  Megumi Tomisaki ,  Kazuhiko Shogami ,  Hideki Nakashima ,  Hirofumi Suzuki ,  Takashi Fujii

发明人： Tetsuo Nishida ,  Megumi Tomisaki ,  Kazuhiko Shogami ,  Hideki Nakashima ,  Hirofumi Suzuki ,  Takashi Fujii

IPC分类号： H01M10/02

CPC分类号： H01M10/052 ,  C01B25/455 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/0025 ,  H01M2300/0091 ,  Y02E60/122 ,  Y02P70/54

摘要： To provide a technique for simply and easily producing a high-purity difluorophosphate and provide a production process of an electrolytic solution using the obtained difluorophosphate, an electrolytic solution and a secondary battery.A process for producing a difluorophosphate, comprising the following step (1) or (2): (1) reacting (A) at least one member selected from the group consisting of oxoacids, oxoacid anhydrides and oxyhalides of phosphorus with (B) a hexafluorophosphate in the presence of hydrogen fluoride, or (2) reacting at least one halide selected from the group consisting of alkali metal halides, alkaline earth metal halides, aluminum halides and onium halides with difluorophosphoric acid in the presence of a hexafluorophosphate. Also, a nonaqueous electrolytic solution containing the obtained difluorophosphate, and a nonaqueous electrolytic secondary battery containing the nonaqueous electrolytic solution.

公开(公告)号：US09028786B2

公开(公告)日：2015-05-12

申请号：US13113541

申请日：2011-05-23

申请人： Tetsuo Nishida ,  Megumi Tomisaki ,  Kazuhiko Shogami ,  Hideki Nakashima ,  Hirofumi Suzuki ,  Takashi Fujii

发明人： Tetsuo Nishida ,  Megumi Tomisaki ,  Kazuhiko Shogami ,  Hideki Nakashima ,  Hirofumi Suzuki ,  Takashi Fujii

IPC分类号： C01B25/10 ,  H01M10/02 ,  H01M10/052 ,  C01B25/455 ,  H01M10/0569 ,  H01M10/0567

CPC分类号： H01M10/052 ,  C01B25/455 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/0025 ,  H01M2300/0091 ,  Y02E60/122 ,  Y02P70/54

摘要： To provide a technique for simply and easily producing a high-purity difluorophosphate and provide a production process of an electrolytic solution using the obtained difluorophosphate, an electrolytic solution and a secondary battery.A process for producing a difluorophosphate, comprising the following step (1) or (2): (1) reacting (A) at least one member selected from the group consisting of oxoacids, oxoacid anhydrides and oxyhalides of phosphorus with (B) a hexafluorophosphate in the presence of hydrogen fluoride, or (2) reacting at least one halide selected from the group consisting of alkali metal halides, alkaline earth metal halides, aluminum halides and onium halides with difluorophosphoric acid in the presence of a hexafluorophosphate. Also, a nonaqueous electrolytic solution containing the obtained difluorophosphate, and a nonaqueous electrolytic secondary battery containing the nonaqueous electrolytic solution.

公开(公告)号：US08293411B2

公开(公告)日：2012-10-23

申请号：US13002090

申请日：2009-12-01

申请人： Tetsuo Nishida ,  Megumi Tomisaki ,  Kazuhiko Shogami ,  Hideki Nakashima ,  Hirofumi Suzuki ,  Takashi Fujii

发明人： Tetsuo Nishida ,  Megumi Tomisaki ,  Kazuhiko Shogami ,  Hideki Nakashima ,  Hirofumi Suzuki ,  Takashi Fujii

IPC分类号： C01B25/10

CPC分类号： H01M10/052 ,  C01B25/455 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/0025 ,  H01M2300/0091 ,  Y02E60/122 ,  Y02P70/54

摘要： To provide a technique for simply and easily producing a high-purity difluorophosphate and provide a production process of an electrolytic solution using the obtained difluorophosphate, an electrolytic solution and a secondary battery.A process for producing a difluorophosphate, comprising the following step (1) or (2): (1) reacting (A) at least one member selected from the group consisting of oxoacids, oxoacid anhydrides and oxyhalides of phosphorus with (B) a hexafluorophosphate in the presence of hydrogen fluoride, or (2) reacting at least one halide selected from the group consisting of alkali metal halides, alkaline earth metal halides, aluminum halides and onium halides with difluorophosphoric acid in the presence of a hexafluorophosphate. Also, a nonaqueous electrolytic solution containing the obtained difluorophosphate, and a nonaqueous electrolytic secondary battery containing the nonaqueous electrolytic solution.

摘要翻译： 提供一种简单且容易地生产高纯度二氟磷酸盐的技术，并提供使用所得二氟磷酸盐，电解液和二次电池的电解液的生产方法。 一种制备二氟磷酸盐的方法，包括以下步骤（1）或（2）：（1）使（A）选自含氧酸，含氧酸酐和磷卤氧化物中的至少一种与（B）六氟磷酸盐 在氟化氢存在下，或（2）在六氟磷酸盐存在下使选自碱金属卤化物，碱土金属卤化物，卤化铝和卤化铪中的至少一种卤化物与二氟磷酸反应。 另外，含有所得二氟磷酸盐的非水电解液和含有非水电解液的非水电解二次电池。

公开(公告)号：US20110223089A1

公开(公告)日：2011-09-15

申请号：US13113541

申请日：2011-05-23

申请人： Tetsuo NISHIDA ,  Megumi Tomisaki ,  Kazuhiko Shogami ,  Hideki Nakashima ,  Hirofumi Suzuki ,  Takashi Fujii

发明人： Tetsuo NISHIDA ,  Megumi Tomisaki ,  Kazuhiko Shogami ,  Hideki Nakashima ,  Hirofumi Suzuki ,  Takashi Fujii

IPC分类号： C01B25/10

CPC分类号： H01M10/052 ,  C01B25/455 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/0025 ,  H01M2300/0091 ,  Y02E60/122 ,  Y02P70/54

摘要： To provide a technique for simply and easily producing a high-purity difluorophosphate and provide a production process of an electrolytic solution using the obtained difluorophosphate, an electrolytic solution and a secondary battery.A process for producing a difluorophosphate, comprising the following step (1) or (2): (1) reacting (A) at least one member selected from the group consisting of oxoacids, oxoacid anhydrides and oxyhalides of phosphorus with (B) a hexafluorophosphate in the presence of hydrogen fluoride, or (2) reacting at least one halide selected from the group consisting of alkali metal halides, alkaline earth metal halides, aluminum halides and onium halides with difluorophosphoric acid in the presence of a hexafluorophosphate. Also, a nonaqueous electrolytic solution containing the obtained difluorophosphate, and a nonaqueous electrolytic secondary battery containing the nonaqueous electrolytic solution.

摘要翻译： 提供一种简单且容易地生产高纯度二氟磷酸盐的技术，并提供使用所得二氟磷酸盐，电解液和二次电池的电解液的生产方法。 一种制备二氟磷酸盐的方法，包括以下步骤（1）或（2）：（1）使（A）选自含氧酸，含氧酸酐和磷卤氧化物中的至少一种与（B）六氟磷酸盐 在氟化氢存在下，或（2）在六氟磷酸盐存在下使选自碱金属卤化物，碱土金属卤化物，卤化铝和卤化铪中的至少一种卤化物与二氟磷酸反应。 另外，含有所得二氟磷酸盐的非水电解液和含有非水电解液的非水电解二次电池。

公开(公告)号：US20110123873A1

公开(公告)日：2011-05-26

申请号：US12926313

申请日：2010-11-09

申请人： Tetsuo Nishida ,  Yasutaka Tashiro ,  Megumi Tomisaki ,  Masashi Yamamoto ,  Kazutaka Hirano ,  Akihiro Nabeshima ,  Hiroaki Tokuda ,  Kenji Sato ,  Takashi Higono

发明人： Tetsuo Nishida ,  Yasutaka Tashiro ,  Megumi Tomisaki ,  Masashi Yamamoto ,  Kazutaka Hirano ,  Akihiro Nabeshima ,  Hiroaki Tokuda ,  Kenji Sato ,  Takashi Higono

IPC分类号： H01M10/0567 ,  C07D207/06 ,  H01G9/022 ,  H01M10/0569

CPC分类号： C07D207/08 ,  H01G9/038 ,  H01G11/60 ,  H01G11/62 ,  H01M6/164 ,  H01M6/166 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/0025 ,  Y02E60/13 ,  Y02T10/7011 ,  Y02T10/7022

摘要： A quaternary ammonium salt of the formula (1), a composition containing the quaternary ammonium salt and an organic solvent, and an electrochemical device using the salt wherein R1 and R2 are both methyl and X− is BF4− or N(CF3SO2)2−.

摘要翻译： 式（1）的季铵盐，含有季铵盐和有机溶剂的组合物和使用盐的电化学装置，其中R 1和R 2都是甲基，X-是BF 4 - 或N（CF 3 SO 2）2 - 。

公开(公告)号：US07854854B2

公开(公告)日：2010-12-21

申请号：US11795030

申请日：2006-01-12

申请人： Tetsuo Nishida ,  Kazutaka Hirano ,  Megumi Tomisaki ,  Akihiro Nabeshima ,  Yoshinobu Abe ,  Hiroaki Tokuda ,  Akinori Oka

发明人： Tetsuo Nishida ,  Kazutaka Hirano ,  Megumi Tomisaki ,  Akihiro Nabeshima ,  Yoshinobu Abe ,  Hiroaki Tokuda ,  Akinori Oka

IPC分类号： H01L31/04 ,  H01G9/038

CPC分类号： H01G9/038 ,  C07D295/08 ,  H01G9/2013 ,  H01G11/62 ,  H01M10/056 ,  H01M2300/0025 ,  Y02E10/542 ,  Y02E60/13 ,  Y02P70/521

摘要： A quaternary ammonium salt of the formula (1), electrolytic solution and electrochemical device using the salt wherein R1 is straight-chain or branched alkyl having 1 to 4 carbon atoms, R2 is straight-chain or branched alkyl having 1 to 3 carbon atoms, and X− is N(CN)2−, SCN−, NO3−, NCO− or NO2−.

摘要翻译： 式（1）的季铵盐，电解液和使用盐的电化学装置，其中R1是具有1至4个碳原子的直链或支链烷基，R2是具有1至3个碳原子的直链或支链烷基， 并且X-是N（CN）2 - ，SCN-，NO 3 - ，NCO-或NO 2 - 。

公开(公告)号：US07875732B2

公开(公告)日：2011-01-25

申请号：US11795036

申请日：2006-01-12

申请人： Tetsuo Nishida ,  Kazutaka Hirano ,  Megumi Tomisaki ,  Yasutaka Tashiro ,  Hitoshi Tsurumaru ,  Akihiro Nabeshima ,  Yoshinobu Abe ,  Hiroaki Tokuda ,  Akinori Oka

发明人： Tetsuo Nishida ,  Kazutaka Hirano ,  Megumi Tomisaki ,  Yasutaka Tashiro ,  Hitoshi Tsurumaru ,  Akihiro Nabeshima ,  Yoshinobu Abe ,  Hiroaki Tokuda ,  Akinori Oka

IPC分类号： C07D207/08

CPC分类号： H01G9/038 ,  C07D295/08 ,  H01G11/62 ,  H01M10/056 ,  H01M10/0568 ,  H01M10/0569 ,  Y02E60/13

摘要： A quaternary ammonium salt of the formula (1) wherein R1 is straight-chain or branched alkyl having 1 to 4 carbon atoms, R2 is straight-chain or branched alkyl having 1 to 3 carbon atoms, and X− is CF3CO2−, CF3SO3BF3−, ClBF3−, AlF4—, CF3BF3−, C2F5BF3—, N(SO2F)2−, PF6−, AsF6— or SbF6−.

摘要翻译： 式（1）的季铵盐，其中R 1是具有1至4个碳原子的直链或支链烷基，R 2是具有1至3个碳原子的直链或支链烷基，X是CF 3 CO 2 - ，CF 3 SO 3 BF 3 - ，ClBF3-，AlF4-，CF3BF3-，C2F5BF3-，N（SO2F）2-，PF6-，AsF6-或SbF6-。

公开(公告)号：US07834197B2

公开(公告)日：2010-11-16

申请号：US10563125

申请日：2004-06-30

申请人： Tetsuo Nishida ,  Yasutaka Tashiro ,  Megumi Tomisaki ,  Masashi Yamamoto ,  Kazutaka Hirano ,  Akihiro Nabeshima ,  Hiroaki Tokuda ,  Kenji Sato ,  Takashi Higono

发明人： Tetsuo Nishida ,  Yasutaka Tashiro ,  Megumi Tomisaki ,  Masashi Yamamoto ,  Kazutaka Hirano ,  Akihiro Nabeshima ,  Hiroaki Tokuda ,  Kenji Sato ,  Takashi Higono

IPC分类号： C07D207/08

CPC分类号： C07D207/08 ,  H01G9/038 ,  H01G11/60 ,  H01G11/62 ,  H01M6/164 ,  H01M6/166 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/0025 ,  Y02E60/13 ,  Y02T10/7011 ,  Y02T10/7022

摘要： A quaternary ammonium salt of the formula (1), electrolytic solution and electrochemical device using the salt wherein R1 is straight-chain or branched alkyl having 1 to 4 carbon atoms, R2 is methyl or ethyl, and X− is a fluorine-containing anion.

摘要翻译： 式（1）的季铵盐，电解液和使用盐的电化学装置，其中R1是具有1-4个碳原子的直链或支链烷基，R2是甲基或乙基，X-是含氟阴离子 。