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1.发明申请公开(公告)号：US20150329462A1
公开(公告)日：2015-11-19
申请号：US14812113
申请日：2015-07-29
CPC分类号： C07C51/48 , B01J27/1806 , C07C51/377 , C07C51/44 , C07C51/46 , C07C51/47 , C07C57/04
摘要： Processes for the purification of bio-based acrylic acid to crude and glacial acrylic acid are provided. The bio-based acrylic acid is produced from hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof. The purification includes some or all of the following processes: extraction, drying, distillation, and melt crystallization. The produced glacial or crude acrylic acid contains hydroxypropionic, hydroxypropionic acid derivatives, or mixtures thereof as an impurity.
摘要翻译： 提供了将生物基丙烯酸纯化成粗制和冰丙烯酸的方法。 生物基丙烯酸由羟基丙酸，羟基丙酸衍生物或其混合物制备。 纯化包括一些或全部以下方法：萃取，干燥，蒸馏和熔融结晶。 产生的冰或粗丙烯酸含有羟基丙酸，羟基丙酸衍生物或其作为杂质的混合物。
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2.发明申请公开(公告)号：US20150031912A1
公开(公告)日：2015-01-29
申请号：US14511192
申请日：2014-10-10
IPC分类号： C07C51/377
CPC分类号： C07C51/48 , A61F13/53 , A61F13/534 , A61F2013/530489 , A61F2013/530496 , B01J27/16 , B01J27/1806 , B01J27/1811 , B01J27/1817 , B01J27/1853 , B01J27/1856 , B01J27/186 , B01J27/187 , B01J27/188 , B01J27/195 , B01J27/198 , B01J27/25 , B01J35/023 , B01J37/0036 , B01J37/04 , B01J37/08 , C07C51/09 , C07C51/377 , C07C51/44 , C07C57/04 , C08F2/10
摘要： Processes for the catalytic dehydration of hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof to acrylic acid, acrylic acid derivatives, or mixtures thereof with high yield and selectivity and without significant conversion to undesired side products, such as, acetaldehyde, propanoic acid, and acetic acid, are provided.
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公开(公告)号：US20130274513A1
公开(公告)日：2013-10-17
申请号：US13760483
申请日：2013-02-06
IPC分类号： C07C51/377 , C07C51/09
CPC分类号： C07C51/48 , A61F13/53 , A61F13/534 , A61F2013/530489 , A61F2013/530496 , B01J27/16 , B01J27/1806 , B01J27/1811 , B01J27/1817 , B01J27/1853 , B01J27/1856 , B01J27/186 , B01J27/187 , B01J27/188 , B01J27/195 , B01J27/198 , B01J27/25 , B01J35/023 , B01J37/0036 , B01J37/04 , B01J37/08 , C07C51/09 , C07C51/377 , C07C51/44 , C07C57/04 , C08F2/10
摘要： Processes for the catalytic dehydration of hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof to acrylic acid, acrylic acid derivatives, or mixtures thereof with high yield and selectivity and without significant conversion to undesired side products, such as, acetaldehyde, propanoic acid, and acetic acid, are provided.
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4.发明授权公开(公告)号：US09714208B2
公开(公告)日：2017-07-25
申请号：US13760472
申请日：2013-02-06
IPC分类号： C07C51/377 , C07C51/48 , B01J27/18 , B01J27/187 , B01J27/25 , C07C51/09 , C07C57/04 , A61F13/534 , C08F2/10 , B01J27/16 , B01J27/185 , B01J27/186 , B01J27/188 , B01J27/195 , B01J27/198 , B01J35/02 , B01J37/00 , B01J37/04 , B01J37/08 , C07C51/44 , A61F13/53
CPC分类号： C07C51/48 , A61F13/53 , A61F13/534 , A61F2013/530489 , A61F2013/530496 , B01J27/16 , B01J27/1806 , B01J27/1811 , B01J27/1817 , B01J27/1853 , B01J27/1856 , B01J27/186 , B01J27/187 , B01J27/188 , B01J27/195 , B01J27/198 , B01J27/25 , B01J35/023 , B01J37/0036 , B01J37/04 , B01J37/08 , C07C51/09 , C07C51/377 , C07C51/44 , C07C57/04 , C08F2/10
摘要： Methods for catalytically dehydrating hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof to acrylic acid, acrylic acid derivatives, or mixtures thereof with high yield and selectivity and without significant conversion to undesired side products, such as, acetaldehyde, propionic acid, and acetic acid, are provided. The catalysts are mixed condensed phosphates.
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公开(公告)号：US09630901B2
公开(公告)日：2017-04-25
申请号：US13760527
申请日：2013-02-06
发明人： Jane Ellen Godlewski , Janette Villalobos , Dimitris Ioannis Collias , Axel Meyer , Peter Dziezok , Juan Estaban Velasquez
IPC分类号： A61F13/15 , C07C51/48 , B01J27/18 , B01J27/187 , B01J27/25 , C07C51/377 , C07C51/09 , C07C57/04 , A61F13/534 , C08F2/10 , B01J27/16 , B01J27/185 , B01J27/186 , B01J27/188 , B01J27/195 , B01J27/198 , B01J35/02 , B01J37/00 , B01J37/04 , B01J37/08 , C07C51/44 , A61F13/53
CPC分类号： C07C51/48 , A61F13/53 , A61F13/534 , A61F2013/530489 , A61F2013/530496 , B01J27/16 , B01J27/1806 , B01J27/1811 , B01J27/1817 , B01J27/1853 , B01J27/1856 , B01J27/186 , B01J27/187 , B01J27/188 , B01J27/195 , B01J27/198 , B01J27/25 , B01J35/023 , B01J37/0036 , B01J37/04 , B01J37/08 , C07C51/09 , C07C51/377 , C07C51/44 , C07C57/04 , C08F2/10
摘要： Bio-based glacial acrylic acid, produced from hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof and having impurities of hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof, is polymerized to poly(acrylic acid) or superabsorbent polymer using the same processes as petroleum-derived glacial acrylic acid.
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6.发明申请Process For Production Of Acrylic Acid Or Its Derivatives From Hydroxypropionic Acid Or Its Derivatives 审中-公开丙烯酸或其衍生物由羟基丙酸或其衍生物生产的方法公开(公告)号：US20150031913A1
公开(公告)日：2015-01-29
申请号：US14511195
申请日：2014-10-10
IPC分类号： C07C51/377
CPC分类号： C07C51/48 , A61F13/53 , A61F13/534 , A61F2013/530489 , A61F2013/530496 , B01J27/16 , B01J27/1806 , B01J27/1811 , B01J27/1817 , B01J27/1853 , B01J27/1856 , B01J27/186 , B01J27/187 , B01J27/188 , B01J27/195 , B01J27/198 , B01J27/25 , B01J35/023 , B01J37/0036 , B01J37/04 , B01J37/08 , C07C51/09 , C07C51/377 , C07C51/44 , C07C57/04 , C08F2/10
摘要： Processes for the catalytic dehydration of hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof to acrylic acid, acrylic acid derivatives, or mixtures thereof with high yield and selectivity and without significant conversion to undesired side products, such as, acetaldehyde, propanoic acid, and acetic acid, are provided.
摘要翻译： 将羟基丙酸，羟基丙酸衍生物或其混合物催化脱水至丙烯酸，丙烯酸衍生物或其混合物的方法，具有高产率和选择性，并且不显着转化为不期望的副产物，例如乙醛，丙酸和 乙酸。
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公开(公告)号：US20130274697A1
公开(公告)日：2013-10-17
申请号：US13760527
申请日：2013-02-06
发明人： Jane Ellen Godlewski , Janette Villalobos , Dimitris Ioannis Collias , Axel Meyer , Peter Dziezok , Juan Estaban Velasquez
IPC分类号： C08F2/10 , A61F13/534
CPC分类号： C07C51/48 , A61F13/53 , A61F13/534 , A61F2013/530489 , A61F2013/530496 , B01J27/16 , B01J27/1806 , B01J27/1811 , B01J27/1817 , B01J27/1853 , B01J27/1856 , B01J27/186 , B01J27/187 , B01J27/188 , B01J27/195 , B01J27/198 , B01J27/25 , B01J35/023 , B01J37/0036 , B01J37/04 , B01J37/08 , C07C51/09 , C07C51/377 , C07C51/44 , C07C57/04 , C08F2/10
摘要： Bio-based glacial acrylic acid, produced from hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof and having impurities of hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof, is polymerized to poly(acrylic acid) or superabsorbent polymer using the same processes as petroleum-derived glacial acrylic acid.
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公开(公告)号：US09809527B2
公开(公告)日：2017-11-07
申请号：US14511195
申请日：2014-10-10
IPC分类号： C07C51/377 , C07C51/48 , B01J27/18 , B01J27/187 , B01J27/25 , C07C51/09 , C07C57/04 , A61F13/534 , C08F2/10 , B01J27/16 , B01J27/185 , B01J27/186 , B01J27/188 , B01J27/195 , B01J27/198 , B01J35/02 , B01J37/00 , B01J37/04 , B01J37/08 , C07C51/44 , A61F13/53
CPC分类号： C07C51/48 , A61F13/53 , A61F13/534 , A61F2013/530489 , A61F2013/530496 , B01J27/16 , B01J27/1806 , B01J27/1811 , B01J27/1817 , B01J27/1853 , B01J27/1856 , B01J27/186 , B01J27/187 , B01J27/188 , B01J27/195 , B01J27/198 , B01J27/25 , B01J35/023 , B01J37/0036 , B01J37/04 , B01J37/08 , C07C51/09 , C07C51/377 , C07C51/44 , C07C57/04 , C08F2/10
摘要： Processes for the catalytic dehydration of hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof to acrylic acid, acrylic acid derivatives, or mixtures thereof with high yield and selectivity and without significant conversion to undesired side products, such as, acetaldehyde, propanoic acid, and acetic acid, are provided.
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公开(公告)号：US20130274520A1
公开(公告)日：2013-10-17
申请号：US13838823
申请日：2013-03-15
CPC分类号： C07C51/48 , B01J27/1806 , C07C51/377 , C07C51/44 , C07C51/46 , C07C51/47 , C07C57/04
摘要： Processes for the purification of bio-based acrylic acid to crude and glacial acrylic acid are provided. The bio-based acrylic acid is produced from hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof. The purification includes some or all of the following processes: extraction, drying, distillation, and melt crystallization. The produced glacial or crude acrylic acid contains hydroxypropionic, hydroxypropionic acid derivatives, or mixtures thereof as an impurity.
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公开(公告)号：US20130274518A1
公开(公告)日：2013-10-17
申请号：US13760505
申请日：2013-02-06
CPC分类号： B01J27/1806 , A61F13/53 , A61F13/534 , A61F2013/530489 , A61F2013/530496 , B01J27/16 , B01J27/1811 , B01J27/1817 , B01J27/1853 , B01J27/1856 , B01J27/186 , B01J27/187 , B01J27/188 , B01J27/195 , B01J27/198 , B01J27/25 , B01J35/023 , B01J37/0036 , B01J37/04 , B01J37/08 , C07C51/09 , C07C51/377 , C07C51/44 , C07C51/48 , C07C57/04 , C08F2/10
摘要： Processes for the purification of bio-based acrylic acid to crude and glacial acrylic acid are provided. The bio-based acrylic acid is produced from hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof. The purification includes some or all of the following processes: extraction, drying, distillation, and melt crystallization. The produced glacial or crude acrylic acid contains hydroxypropionic, hydroxypropionic acid derivatives, or mixtures thereof as an impurity.
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