公开(公告)号：US20170182486A1

公开(公告)日：2017-06-29

申请号：US15129853

申请日：2015-03-30

申请人： The University of Chicago

发明人： Wenbin Lin, Ph.D. ,  Kuntal Manna ,  Teng Zhang

IPC分类号： B01J31/16 ,  C07F5/02 ,  C07F7/18 ,  C07C5/03 ,  C07C41/20 ,  C07D207/04 ,  C07D207/06 ,  C07C209/02 ,  B01J31/18 ,  C07C37/07

CPC分类号： B01J31/1691 ,  B01J31/18 ,  B01J31/1815 ,  B01J2531/16 ,  B01J2531/48 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/842 ,  B01J2531/845 ,  B01J2531/847 ,  C07C5/03 ,  C07C37/07 ,  C07C41/20 ,  C07C209/02 ,  C07D207/04 ,  C07D207/06 ,  C07F5/025 ,  C07F7/1876 ,  Y02P20/544

摘要： Metal-organic framework (MOFs) compositions based on nitrogen donor-based organic bridging ligands, including ligands based on 1,3-diketimine (NacNac), bipyridines and salicylaldimine, were synthesized and then post-synthetically metalated with metal precursors, such as complexes of first row transition metals. Metal complexes of the organic bridging ligands could also be directly incorporated into the MOFs. The MOFs provide a versatile family of recyclable and reusable single-site solid catalysts for catalyzing a variety of asymmetric organic transformations. The solid catalysts can also be integrated into a flow reactor or a supercritical fluid reactor.