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    Adhesive sheet based on nitrile rubber blends for attaching metal parts to plastics
    2.
    发明授权
    Adhesive sheet based on nitrile rubber blends for attaching metal parts to plastics 失效
    基于丁腈橡胶混合物的粘合片，用于将金属部件连接到塑料上

    公开(公告)号：US07923510B2

    公开(公告)日：2011-04-12

    申请号：US11996519

    申请日：2006-07-27

    申请人： Marc Husemann ,  Frank Hannemann ,  Matthias Koop ,  Thilo Dollase ,  Thorsten Krawinkel

    发明人： Marc Husemann ,  Frank Hannemann ,  Matthias Koop ,  Thilo Dollase ,  Thorsten Krawinkel

    IPC分类号： C08L9/02 ,  C08L61/04 ,  C08L61/14 ,  C08L63/00 ,  C08L63/02 ,  C08L63/04 ,  C08L75/04

    CPC分类号： C08L9/02 ,  C08L63/00 ,  C08L2205/02 ,  C09J7/10 ,  C09J2409/00 ,  Y10T428/2813 ,  C08L2666/02

    摘要： Heat-activable adhesive sheet of an adhesive comprising a blend of at least three synthetic nitrile rubber compositions S1, S2 and S3, each of which comprises at least one synthetic nitrile rubber, and at least one reactive resin which is capable of crosslinking with itself, with other reactive resins and/or with the nitrile rubbers of synthetic rubber compositions S1, S2 and S3, in which a) the blend of the heat-activable sheet being microphase-separated, characterized by at least three different glass transition temperatures in a DSC, b) at least one of said glass transition temperatures being greater than 10° C. and at least one of said glass transition temperature lower than −20° C., c) the nitrile rubber or rubbers S1 having an acrylonitrile fraction of greater than/equal to 35%, d) the nitrile rubber or rubbers S2 having an acrylonitrile fraction of greater than 25% and less than 35%, e) the nitrile rubber S3 having an acrylonitrile fraction of less than/equal to 25%.

    摘要翻译： 包含至少三种合成腈橡胶组合物S1，S2和S3的共混物的粘合剂的热可活化粘合片，每种合成腈橡胶组合物包含至少一种合成腈橡胶和至少一种能与其自身交联的反应性树脂， 与其它反应性树脂和/或与合成橡胶组合物S1，S2和S3的丁腈橡胶相结合，其中a）可热活化的片材的共混物被微相分离，其特征在于DSC中至少三种不同的玻璃化转变温度 b）所述玻璃化转变温度中的至少一个大于10℃，所述玻璃化转变温度中的至少一个低于-20℃，c）腈橡胶或橡胶S1的丙烯腈分数大于 /等于35％，d）丙烯腈分数大于25％且小于35％的丁腈橡胶或橡胶S2，e）丙烯腈分数小于或等于25％的丁腈橡胶S3。

    Adhesive Sheet Based on Nitrile Rubber Blends for Attaching Metal Parts to Plastics
    4.
    发明申请
    Adhesive Sheet Based on Nitrile Rubber Blends for Attaching Metal Parts to Plastics 失效
    基于用于将金属零件连接到塑料的腈橡胶混合物的粘合片

    公开(公告)号：US20080166554A1

    公开(公告)日：2008-07-10

    申请号：US11996519

    申请日：2006-07-27

    申请人： Marc Husemann ,  Frank Hannemann ,  Matthias Koop ,  Thilo Dollase ,  Thorsten Krawinkel

    发明人： Marc Husemann ,  Frank Hannemann ,  Matthias Koop ,  Thilo Dollase ,  Thorsten Krawinkel

    IPC分类号： B32B25/04

    CPC分类号： C08L9/02 ,  C08L63/00 ,  C08L2205/02 ,  C09J7/10 ,  C09J2409/00 ,  Y10T428/2813 ,  C08L2666/02

    摘要： Heat-activable adhesive sheet of an adhesive comprising a blend of at least three synthetic nitrile rubber compositions S1, S2 and S3, each of which comprises at least one synthetic nitrile rubber, and at least one reactive resin which is capable of crosslinking with itself, with other reactive resins and/or with the nitrile rubbers of synthetic rubber compositions S1, S2 and S3, in which a) the blend of the heat-activable sheet being microphase-separated, characterized by at least three different glass transition temperatures in a DSC, b) at least one of said glass transition temperatures being greater than 10° C. and at least one of said glass transition temperature lower than −20° C., c) the nitrile rubber or rubbers S1 having an acrylonitrile fraction of greater than/equal to 35%, d) the nitrile rubber or rubbers S2 having an acrylonitrile fraction of greater than 25% and less than 35%, e) the nitrile rubber S3 having an acrylonitrile fraction of less than/equal to 25%.

    摘要翻译： 包含至少三种合成腈橡胶组合物S1，S2和S3的共混物的粘合剂的热可活化粘合片，每种合成腈橡胶组合物包含至少一种合成腈橡胶和至少一种能与其自身交联的反应性树脂， 与其它反应性树脂和/或与合成橡胶组合物S1，S2和S3的丁腈橡胶相结合，其中a）可热活化的片材的共混物被微相分离，其特征在于DSC中至少三种不同的玻璃化转变温度 b）所述玻璃化转变温度中的至少一个大于10℃，所述玻璃化转变温度中的至少一个低于-20℃，c）腈橡胶或橡胶S1的丙烯腈分数大于 /等于35％，d）丙烯腈分数大于25％且小于35％的丁腈橡胶或橡胶S2，e）丙烯腈分数小于或等于25％的丁腈橡胶S3。

    Strippable systems based on acrylic block copolymers
    6.
    发明授权
    Strippable systems based on acrylic block copolymers 有权
    基于丙烯酸嵌段共聚物的可剥离体系

    公开(公告)号：US06723407B2

    公开(公告)日：2004-04-20

    申请号：US10075482

    申请日：2002-02-13

    申请人： Thilo Dollase ,  Marc Husemann ,  Bernd Lühmann

    发明人： Thilo Dollase ,  Marc Husemann ,  Bernd Lühmann

    IPC分类号： B32B3300

    CPC分类号： C09J153/00 ,  C08F293/005 ,  C08L53/00 ,  C08L53/02 ,  C08L2666/24 ,  C09J153/02 ,  Y10T428/14 ,  Y10T428/1452 ,  Y10T428/24942 ,  Y10T428/2495 ,  Y10T428/24959

    摘要： Strippable systems comprising at least one pressure sensitive adhesive based on at least one block copolymer, wherein said at least one block copolymer is based at least in part on (meth)acrylic acid derivatives, the block copolymers containing at least the unit P(A)-P(B)-P(A) composed of at least one polymer block P(B) and at least two polymer blocks P(A), where P(A) independently of one another represent homopolymer or copolymer blocks of monomers A, the polymer blocks P(A) each having a softening temperature in the range from +20° C. to +175° C., P(B) represents a homopolymer or copolymer block of monomers B, the polymer block P(B) having a softening temperature in the range from −100° C. to +10° C., and the polymer blocks P(A) and P(B) are not homogeneously miscible with one another.

    摘要翻译： 包括至少一种基于至少一种嵌段共聚物的压敏粘合剂的可剥离体系，其中所述至少一种嵌段共聚物至少部分基于（甲基）丙烯酸衍生物，所述嵌段共聚物至少含有单元P（A） 由至少一个聚合物嵌段P（B）和至少两个聚合物嵌段P（A）组成的-P（B）-P（A），其中P（A）彼此独立地表示单体A的均聚物或共聚物嵌段， 聚合物嵌段P（A）各自具有+ 20℃至+ 175℃的软化温度，P（B）表示单体B的均聚物或共聚物嵌段，聚合物嵌段P（B）具有 软化温度在-100℃至+ 10℃的范围内，聚合物嵌段P（A）和P（B）彼此不能均匀地混溶。

    Self-adhesive article
    7.
    发明申请
    Self-adhesive article 审中-公开
    自粘物品

    公开(公告)号：US20060154098A1

    公开(公告)日：2006-07-13

    申请号：US10537469

    申请日：2003-11-11

    申请人： Thilo Dollase ,  Marc Husemann

    发明人： Thilo Dollase ,  Marc Husemann

    IPC分类号： B32B27/30 ,  B32B7/12

    CPC分类号： C09J153/00 ,  C09J7/21 ,  C09J7/38 ,  C09J7/387 ,  C09J2400/283 ,  C09J2433/00 ,  Y10T428/28 ,  Y10T428/2839 ,  Y10T428/2843 ,  Y10T428/31935

    摘要： A self-adhesive article made from a sheet or strip support at least partly coated on at least one side with a pressure-sensitive adhesive material based on polyacrylate, comprising at least one polyacrylate block copolymer with a sequence of hard polymer blocks [P(A)], having a glass transition temperature of not more than 10° C., preferably of 0 to −80° C. and of soft polymer blocks [P(B)], having a glass transition temperature of more than 10° C., preferably 20 to 175° C. A microstructuring is thus generated, which permits the exchange of the smallest adhering and non-adhering regions and thus generates the desired easily stuck and easily removed adhesive action such as required for self-adhesive note pads.

    摘要翻译： 至少部分地用基于聚丙烯酸酯的压敏粘合剂材料至少部分地涂覆有片状或带状载体的自粘物品，其包含至少一种具有一定硬聚合物嵌段的聚丙烯酸酯嵌段共聚物[P（A ）]，玻璃化转变温度为10℃以下，优选为0〜-80℃，玻璃化转变温度为10℃以上的软质聚合物嵌段[P（B）]。 ，优选为20至175℃。因此产生微结构，其允许最小粘附和非粘附区域的交换，从而产生所需的容易粘贴和容易去除的粘合剂作用，例如自粘贴纸垫所需要的。

    Adhesive materials having a high refractive index based on acrylate block copolymers
    8.
    发明申请
    Adhesive materials having a high refractive index based on acrylate block copolymers 有权
    基于丙烯酸酯嵌段共聚物具有高折射率的粘合材料

    公开(公告)号：US20060057372A1

    公开(公告)日：2006-03-16

    申请号：US10522233

    申请日：2003-06-24

    申请人： Thilo Dollase ,  Marc Husemann

    发明人： Thilo Dollase ,  Marc Husemann

    IPC分类号： B32B27/32 ,  B32B27/30 ,  B32B7/12

    CPC分类号： C09J153/00 ,  C08F293/005 ,  C08L2666/02 ,  C08L2666/24 ,  Y10T428/1082 ,  Y10T428/2891 ,  Y10T428/31645 ,  Y10T428/31935

    摘要： A pressure-sensitive adhesive based on at least 50% of one or more block copolymers, at least one block copolymer being composed at least in part on the basis of (meth)acrylic acid derivatives, the at least one block copolymer comprising at least the unit P(A)-P(B)-P(A), comprising at least one polymer block P(B) and at least two polymer blocks P(A), where P(A) independently of one another represent homopolymer or copolymer blocks made up of monomers of group A, the (co)polymer blocks P(A) each having a softening temperature in the range from 0° C. to +175° C., P(B) represents a homopolymer or copolymer block comprising monomers of group B, the (co)polymer block P(B) having a softening temperature in the range from −130° C. to +10° C., and the (co)polymer blocks P(A) and P(B) are not homogeneously miscible with one another at 25° C., characterized in that the adhesive has a refractive index nd,a of nd,a≧1.52 at 25° C., at least one of the (co)polymer blocks P(A) have a refractive index nd,A of nd,A≧1.58 at 25° C., and the (co)polymer block P(B) has a refractive index nd,B of nd,B≧1.43 at 25° C.

    摘要翻译： 基于至少50％的一种或多种嵌段共聚物的压敏粘合剂，至少一种嵌段共聚物至少部分基于（甲基）丙烯酸衍生物构成，所述至少一种嵌段共聚物至少包含 单元P（A）-P（B）-P（A），其包含至少一个聚合物嵌段P（B）和至少两个聚合物嵌段P（A），其中P（A）彼此独立地表示均聚物或共聚物 由组A的单体构成的嵌段，（共）聚合物嵌段P（A）各自具有0℃至+ 175℃的软化温度，P（B）表示均聚物或共聚物嵌段，其包含 B组单体，（共）聚合物嵌段P（B）的软化温度在-130℃至+ 10℃的范围内，和（共）聚合物嵌段P（A）和P（B ）在25℃下不能彼此均匀混溶，其特征在于t

    Adhesive materials having a high refractive index based on acrylate block copolymers
    10.
    发明授权
    Adhesive materials having a high refractive index based on acrylate block copolymers 有权
    基于丙烯酸酯嵌段共聚物具有高折射率的粘合材料

    公开(公告)号：US07758933B2

    公开(公告)日：2010-07-20

    申请号：US10522233

    申请日：2003-06-24

    申请人： Thilo Dollase ,  Marc Husemann

    发明人： Thilo Dollase ,  Marc Husemann

    IPC分类号： B32B27/30 ,  C08F293/00

    CPC分类号： C09J153/00 ,  C08F293/005 ,  C08L2666/02 ,  C08L2666/24 ,  Y10T428/1082 ,  Y10T428/2891 ,  Y10T428/31645 ,  Y10T428/31935

    摘要： A pressure-sensitive adhesive based on at least 50% of one or more block copolymers, at least one block copolymer being composed at least in part on the basis of (meth)acrylic acid derivatives, the at least one block copolymer comprising at least the unit P(A)-P(B)-P(A), comprising at least one polymer block P(B) and at least two polymer blocks P(A), where P(A) independently of one another represent homopolymer or copolymer blocks made up of monomers of group A, the (co)polymer blocks P(A) each having a softening temperature in the range from 0° C. to +175° C., P(B) represents a homopolymer or copolymer block comprising monomers of group B, the (co)polymer block P(B) having a softening temperature in the range from −130° C. to +10° C., and the (co)polymer blocks P(A) and P(B) are not homogeneously miscible with one another at 25° C., characterized in that the adhesive has a refractive index nd,a of nd,a≧1.52 at 25° C., at least one of the (co)polymer blocks P(A) have a refractive index nd,A of nd,A≧1.58 at 25° C., and the (co)polymer block P(B) has a refractive index nd,B of nd,B≧1.43 at 25° C.

    摘要翻译： 基于至少50％的一种或多种嵌段共聚物的压敏粘合剂，至少一种嵌段共聚物至少部分基于（甲基）丙烯酸衍生物构成，所述至少一种嵌段共聚物至少包含 单元P（A）-P（B）-P（A），其包含至少一个聚合物嵌段P（B）和至少两个聚合物嵌段P（A），其中P（A）彼此独立地表示均聚物或共聚物 由组A的单体构成的嵌段，（共）聚合物嵌段P（A）各自具有0℃至+ 175℃的软化温度，P（B）表示均聚物或共聚物嵌段，其包含 B组单体，（共）聚合物嵌段P（B）的软化温度在-130℃至+ 10℃的范围内，和（共）聚合物嵌段P（A）和P（B ）在25℃下不能彼此均匀地混溶，其特征在于粘合剂在25℃下具有折射率nd，a，a≥1.52，至少一种（共）聚合物嵌段P（ A）有一个refrac （共）聚合物嵌段P（B）的折射率nd，B，nd，B≥1.43，在25℃。