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公开(公告)号：US08529859B2
公开(公告)日：2013-09-10
申请号：US13043072
申请日：2011-03-08
CPC分类号： C04B35/447 , C01B25/32 , C01B25/455 , C04B35/62268 , C04B2235/3208 , C04B2235/3212 , C04B2235/3213 , C04B2235/3215 , C04B2235/3224 , C04B2235/3229 , C04B2235/44 , C04B2235/442 , C04B2235/444 , C04B2235/445 , C04B2235/447 , C04B2235/5276 , C04B2235/5292 , C30B7/00 , C30B29/10 , C30B29/22
摘要： The present invention provides a method of crystallizing Yb:C-FAP [Yb3+:Ca5(PO4)3F], by dissolving the Yb:C-FAP in an acidic solution, following by neutralizing the solution. The present invention also provides a method of forming crystalline Yb:C-FAP by dissolving the component ingredients in an acidic solution, followed by forming a supersaturated solution.
摘要翻译： 本发明提供通过将Yb：C-FAP溶解在酸性溶液中，然后中和溶液而使Yb：C-FAP [Yb3 +：Ca5（PO4）3F]结晶的方法。 本发明还提供了通过将组分成分溶解在酸性溶液中形成结晶Yb：C-FAP，然后形成过饱和溶液的方法。
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公开(公告)号：US20110224065A1
公开(公告)日：2011-09-15
申请号：US13043072
申请日：2011-03-08
IPC分类号： C04B35/50
CPC分类号： C04B35/447 , C01B25/32 , C01B25/455 , C04B35/62268 , C04B2235/3208 , C04B2235/3212 , C04B2235/3213 , C04B2235/3215 , C04B2235/3224 , C04B2235/3229 , C04B2235/44 , C04B2235/442 , C04B2235/444 , C04B2235/445 , C04B2235/447 , C04B2235/5276 , C04B2235/5292 , C30B7/00 , C30B29/10 , C30B29/22
摘要： The present invention provides a method of crystallizing Yb:C-FAP [Yb3+:Ca5(PO4)3F], by dissolving the Yb:C-FAP in an acidic solution, following by neutralizing the solution. The present invention also provides a method of forming crystalline Yb:C-FAP by dissolving the component ingredients in an acidic solution, followed by forming a supersaturated solution.
摘要翻译： 本发明提供通过将Yb：C-FAP溶解在酸性溶液中，然后中和溶液而使Yb：C-FAP [Yb3 +：Ca5（PO4）3F]结晶的方法。 本发明还提供了通过将组分成分溶解在酸性溶液中形成结晶Yb：C-FAP，然后形成过饱和溶液的方法。
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3.发明授权Optical amplifier operating at 1.3 microns useful for telecommunications and based on dysprosium-doped metal chloride host materials 失效工作在1.3微米的光放大器可用于电信和基于镝掺杂的金属氯化物主体材料
公开(公告)号：US5694500A
公开(公告)日：1997-12-02
申请号：US546851
申请日：1995-10-23
申请人： Ralph H. Page , Kathleen I. Schaffers , Stephen A. Payne , William F. Krupke , Raymond J. Beach
发明人： Ralph H. Page , Kathleen I. Schaffers , Stephen A. Payne , William F. Krupke , Raymond J. Beach
CPC分类号： H01S3/16 , G02B6/102 , H01S3/094092 , H01S3/094096 , H01S3/1606
摘要： Dysprosium-doped metal chloride materials offer laser properties advantageous for use as optical amplifiers in the 1.3 .mu.m telecommunications fiber optic network. The upper laser level is characterized by a millisecond lifetime, the host material possesses a moderately low refractive index, and the gain peak occurs near 1.31 .mu.m. Related halide materials, including bromides and iodides, are also useful. The Dy.sup.3+ -doped metal chlorides can be pumped with laser diodes and yield 1.3 .mu.m signal gain levels significantly beyond those currently available.
摘要翻译： 掺杂镝的金属氯化物材料提供有利于在1.3微米电信光纤网络中用作光放大器的激光特性。 上激光水平的特征在于毫秒的寿命，主体材料具有适度的低折射率，增益峰出现在1.31μm附近。 相关的卤化物物质，包括溴化物和碘化物，也是有用的。 Dy3 +掺杂的金属氯化物可以用激光二极管泵浦，并且产生1.3μm的信号增益水平显着超过目前可用的。
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4.发明授权公开(公告)号：US07378042B2
公开(公告)日：2008-05-27
申请号：US11652442
申请日：2007-01-10
CPC分类号： G02F1/3551 , C09K11/778 , G02F1/37
摘要： A material for harmonic generation has been made by substitutional changes to the crystal LaCa4 (BO3)3 also known as LaCOB in the form Re1xRe2yRe3zCa4(B03)3O where Re1 and Re2, (rare earth ion 1 and rare earth ion 2) are selected from the group consisting of Sc, Yttrium, La, Ce, Pr, Nd, Sm, Eu, Gd, Th, Dy, Ho, Er, Tm, Yb, and Lu; Re3 is Lanthanum; and x+y+z=1.
摘要翻译： 用于谐波产生的材料已经通过对Re1形式的LaCa 4（BO 3 3）3 3（也称为LaCOB）的替代改变进行 （3×3）3（3）（3）（3）3 其中Re1和Re2（稀土离子1和稀土离子2）选自Sc，Yttrium，La，Ce，Pr，Nd，Sm，Eu，Gd，Th，Dy， Ho，Er，Tm，Yb和Lu; Re3是镧; x + y + z = 1。
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公开(公告)号：US5677921A
公开(公告)日：1997-10-14
申请号：US409236
申请日：1995-03-24
CPC分类号： H01S3/16 , H01S3/1095 , H01S3/1618 , H01S3/1666
摘要： A new class of solid state laser crystals and lasers are formed from Yb-doped borate fluoride host crystals. The general formula for the host crystals is MM'(BO.sub.3)F, where M, M' are monovalent, divalent aria trivalent metal cations. A particular embodiment of the invention is Yb-doped BaCaBO.sub.3 F (Yb:BCBF). BCBF and some of the related derivative crystals are capable of nonlinear frequency conversion, whereby the fundamental of the laser is converted to a longer or shorter wavelength. In this way, these new crystals can simultaneously serve as self-frequency doubling crystals and laser materials within the laser resonator.
摘要翻译： 由掺杂硼酸的硼酸盐主体晶体形成新的固态激光晶体和激光器。 主体晶体的通式为MM'（BO3）F，其中M，M'为单价，二价咏叹调三价金属阳离子。 本发明的一个具体实施方案是Yb掺杂的BaCaBO3F（Yb：BCBF）。 BCBF和一些相关的衍生晶体能够进行非线性频率转换，从而将激光的基极转换为更长或更短的波长。 这样，这些新晶体可以同时用作激光谐振器内的自激倍频晶体和激光材料。
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6.发明授权公开(公告)号：US07260124B1
公开(公告)日：2007-08-21
申请号：US11652424
申请日：2007-01-10
CPC分类号： G02F1/3551 , C30B15/00 , C30B29/10 , G02F1/37 , H01S3/0092 , H01S3/109 , H01S3/1618
摘要： A material for harmonic generation has been made by substitutional changes to the crystal LaCa4(BO3)3 also known as LaCOB in the form Re1xRe2yRe3zCa4(B03)3O where Re1 and Re2, (rare earth ion 1 and rare earth ion 2) are selected from the group consisting of Sc, Yttrium, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu; Re3 is Lanthanum; and x+y+z=1.
摘要翻译： 用于谐波产生的材料已经通过对Re1形式的LaCa 4（BO 3 3）3 3（也称为LaCOB）的替代改变进行 （3×3）3（3）（3）（3）3 其中Re1和Re2（稀土离子1和稀土离子2）选自Sc，Yttrium，La，Ce，Pr，Nd，Sm，Eu，Gd，Tb，Dy， Ho，Er，Tm，Yb和Lu; Re3是镧; x + y + z = 1。
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7.发明授权公开(公告)号：US07179405B2
公开(公告)日：2007-02-20
申请号：US10261902
申请日：2002-10-01
CPC分类号： G02F1/3551 , C30B15/00 , C30B29/10 , G02F1/37 , H01S3/0092 , H01S3/109 , H01S3/1618
摘要： A material for harmonic generation has been made by substitutional changes to the crystal LaCa4 (BO3)3 also known as LaCOB in the form Re1xRe2yRe3zCa4(BO3)3O where Re1 and Re2, (rare earth ion 1 and rare earth ion 2) are selected from the group consisting of Sc, Yttrium, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu; Re3 is Lanthanum; and x+y+z=1.
摘要翻译： 用于谐波产生的材料已经通过对Re1形式的LaCa 4（BO 3 3）3 3（也称为LaCOB）的替代改变进行 （3）3（3）3（3）3（3）3 其中Re1和Re2（稀土离子1和稀土离子2）选自Sc，Yttrium，La，Ce，Pr，Nd，Sm，Eu，Gd，Tb，Dy， Ho，Er，Tm，Yb和Lu; Re3是镧; x + y + z = 1。
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8.发明授权Low-phonon-frequency chalcogenide crystalline hosts for rare earth lasers operating beyond three microns 失效用于超过三微米的稀土激光器的低声子频率硫族化物晶体主机
公开(公告)号：US6047013A
公开(公告)日：2000-04-04
申请号：US235650
申请日：1999-01-22
申请人： Stephen A. Payne , Ralph H. Page , Kathleen I. Schaffers , Michael C. Nostrand , William F. Krupke , Peter G. Schunemann
发明人： Stephen A. Payne , Ralph H. Page , Kathleen I. Schaffers , Michael C. Nostrand , William F. Krupke , Peter G. Schunemann
IPC分类号： H01S3/16
CPC分类号： H01S3/16 , H01S3/1603 , H01S3/163
摘要： The invention comprises a RE-doped MA.sub.2 X.sub.4 crystalline gain medium, where M includes a divalent ion such as Mg, Ca, Sr, Ba, Pb, Eu, or Yb; A is selected from trivalent ions including Al, Ga, and In; X is one of the chalcogenide ions S, Se, and Te; and RE represents the trivalent rare earth ions. The MA.sub.2 X.sub.4 gain medium can be employed in a laser oscillator or a laser amplifier. Possible pump sources include diode lasers, as well as other laser pump sources. The laser wavelengths generated are greater than 3 microns, as becomes possible because of the low phonon frequency of this host medium. The invention may be used to seed optical devices such as optical parametric oscillators and other lasers.
摘要翻译： 本发明包括RE掺杂的MA2X4晶体增益介质，其中M包括二价离子如Mg，Ca，Sr，Ba，Pb，Eu或Yb; A选自包括Al，Ga和In的三价离子; X是硫属元素离子S，Se和Te之一; RE表示三价稀土离子。 MA2X4增益介质可用于激光振荡器或激光放大器。 可能的泵浦源包括二极管激光器以及其他激光泵源。 所产生的激光波长大于3微米，因为该主机介质的低声子频率是可能的。 本发明可以用于种子光学装置，例如光参量振荡器和其它激光器。
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