摘要:
A method and corrosion inhibitor for inhibiting corrosion of metal equipment in an aqueous medium comprising components selected from the group consisting of Skeletonema costatum, fish, other algae, and a combination thereof. The method comprises incorporating into the medium a corrosion inhibiting amount of a water soluble corrosion inhibitor comprising an N-ethoxy, 2-substituted imidazoline. The N-ethoxy substituent comprises a quantity of ethylene oxide effective to render the imidazoline water soluble. The corrosion inhibitor is rendered more environmentally compatible by shortening the number of carbon atoms in the fatty acid chain at the 2-position of the imidazoline. The fatty acid chain consists essentially about 18 carbon atoms or less, preferably about 10 carbon atoms or less, most preferably from about 6 to about 8 carbon atoms. As the number of carbon atoms in the fatty acid chain is reduced, the efficacy of the corrosion inhibitor is increased by combination with a wetting agent, preferably an ethoxylated alcohol having from about 8 to about 10 carbon atoms.
摘要:
A method for inhibiting corrosion in an aqueous medium is disclosed. The method comprises incorporating into the medium an amount of a water-soluble corrosion inhibitor sufficient to inhibit corrosion. The corrosion inhibitor comprises an N-ethoxy, 2-substituted imidazoline, the N-ethoxy substituent having from one to about thirty ethoxy units and the 2-substituent being an unsaturated or polyunsaturated fatty chain of from about six to about thirty carbons. If the medium is sweet, the inhibitor further comprises a phosphate ester derived from a water-soluble oxyethylated, straight chain alcohol of from about two to about thirty carbons. Corrosion inhibitor compositions useful in such method are also disclosed.
摘要:
A method for inhibiting corrosion in an aqueous medium is disclosed. The method comprises incorporating into the medium an amount of a water-soluble corrosion inhibitor sufficient to inhibit corrosion. The corrosion inhibitor comprises an N-ethoxy,2-substituted imidazoline, the N-ethoxy substituent having from one to about thirty ethoxy units and the 2-substituent being an unsaturated or polyunsaturated fatty chain of from about six to about thirty carbons. If the medium is sweet, the inhibitor further comprises a phosphate ester derived from a water-soluble oxyethylated, straight chain alcohol of from about two to about thirty carbons. Corrosion inhibitor compositions useful in such method are also disclosed.
摘要:
A method for inhibiting corrosion of a metal surface bearing a corrosion product including ferrous ions is disclosed. The method comprises applying to the surface a salt of an ethoxylated amine and a reaction product of an alcohol and a fatty acid maleic anhydride adduct produced by a reaction between maleic anhydride and an unsaturated fatty acid. Related compositions are also disclosed.
摘要:
A method for inhibiting corrosion of a metal surface in a liquid medium is described. The method comprises incorporating into the medium a corrosion inhibiting amount of a combination of a surfactant that forms a bilayer on the metal surface in the fluid and a corrosion inhibitor that solubilizes in the medium in the presence of the surfactant. The amount of surfactant is sufficient to produce a bilayer on the metal surface in the medium. The combination isa. an anionic surfactant that forms a bilayer on the metal surface and a cationic corrosion inhibitor;b. a cationic surfactant that forms a bilayer on the metal surface and an anionic corrosion inhibitor;c. an ionic surfactant that forms a bilayer on the metal surface and an ionic corrosion inhibitor having a pendent, generally straight chain hydrocarbon or substituted hydrocarbon moiety of from about 10 to about 18 carbon atoms; ord. an ionic surfactant that forms a bilayer on the metal surface and a non-ionic corrosion inhibitor.Related compositions and methods are also disclosed.
摘要:
A novel method for preparing an aryl-substituted fatty acid or fatty ester is disclosed. According to the method, an olefinic composition selected from among mono-unsaturated fatty acids, mono-unsaturated fatty esters and mixtures thereof is introduced to a reaction zone comprising a liquid aromatic hydrocarbon and a catalytic amount of a clay catalyst to produce a reaction that is allowed to proceed for a time and at a temperature sufficient to produce a reaction product comprising a desired yield of aryl-substituted fatty acid or fatty ester. Preferably, the introduction of the olefinic composition is conducted slowly, such as over a period of one to four, more preferably, two to four, hours. Related methods and compositions, including xylylstearic acid, are also disclosed.
摘要:
This invention relates to novel highly branched amines and to a process of preparing same which comprises:(1) the preparation of a vinylimine from branched aldehydes and ammonia;(2) the dimerization and intermolecular condensation of such vinylimines to cyclic diamines; and(3) hydrolysis of such cyclic diamines to other diamines.
摘要:
This invention relates to the following:(1) An amino-containing composition characterized by polymercapto groups,(2) A polyamino-containing composition characterized by mercapto or polymercapto groups,(3) A composition characterized by the presence ofA. a mercapto or polymercapto groups, andB. nitrogen-containing group characterized by at least one of the following:1. an amido or a polyamido group,2. a cyclic amidine or a polycyclic amidine group,3. an epihalohydrin-derived amino-containing group.This invention also relates to the use of the above compositions as corrosion inhibitors.
摘要:
This invention relates to hexahydropyrimidines (HHP) and to the preparation of HHP by the reduction of tetrahydropyrimidines (THP). HHP is preferably prepared by reacting carbonyls, such as ketones and aldehydes, with ammonia in the presence of ammonium formate to form THP and then reducing THP to HHP. The preferred carbonyl is a cycloalkylene ketone such as cyclohexyl ketone or substituted cyclohexyl ketone.