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公开(公告)号：US08222406B2
公开(公告)日：2012-07-17
申请号：US12564509
申请日：2009-09-22
IPC分类号： C07D413/00
CPC分类号： C07D263/10 , Y02P20/582
摘要： Provided is a process for preparing a heterocycle by catalytic reaction of an aromatic dinitrile with an amino alcohol, wherein the process includes: initially charging into a reaction vessel the amino alcohol and a catalyst to produce a reaction mixture; adding the aromatic dinitrile into the reaction mixture, which is maintained at a reaction temperature, wherein no solvent other than the amino alcohol of formula (III) is added to the reaction mixture prior to and/or during the catalytic reaction; and after completion of the catalytic reaction, completely replacing, or substantially completely replacing, unreacted amino alcohol with a nonpolar solvent to obtain the heterocycle, wherein the unreacted amino alcohol is present in an amount of not more than 20 wt. %, preferably 3-10 wt. % or less, based on a total weight of the heterocycle.
摘要翻译： 提供了通过芳族二腈与氨基醇的催化反应制备杂环的方法，其中该方法包括：首先将氨基醇和催化剂装入反应容器中以产生反应混合物; 将芳族二腈加入反应混合物中，其保持在反应温度下，其中在催化反应之前和/或催化反应期间，将不超过式（III）的氨基醇的溶剂加入到反应混合物中; 并且在催化反应完成后，用非极性溶剂完全替代或基本上完全替代未反应的氨基醇，得到杂环，其中未反应的氨基醇的存在量不超过20wt。 ％，优选3-10wt。 ％以下，基于杂环的总重量。
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公开(公告)号：US20080214864A1
公开(公告)日：2008-09-04
申请号：US11961109
申请日：2007-12-20
IPC分类号： C07C205/01
CPC分类号： C07C209/68 , C07C211/09
摘要： A continuous process for decarboxylating carboxylic acids proceeds by I.) initially charging a carbonyl compound as a catalyst in a solvent at reaction temperature, to obtain a catalyst solution; II.) metering a carboxylic acid into the catalyst solution as an aqueous solution, aqueous suspension or as a water-comprising solid, to obtain a reaction mixture; and III.) continuously removing a mixture of CO2, solvent, water and a reaction product or mixture of reaction products from the reaction mixture as a vapor.
摘要翻译： 羧酸脱羧的连续方法由I.）在反应温度下首先将羰基化合物作为催化剂在溶剂中加入，得到催化剂溶液; II。）将羧酸作为水溶液，水性悬浮液或作为含水固体计量到催化剂溶液中，以获得反应混合物; 和III。）作为蒸气连续地从反应混合物中除去CO 2 CO 2，溶剂，水和反应产物或反应产物的混合物的混合物。
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公开(公告)号：US07485756B2
公开(公告)日：2009-02-03
申请号：US11961109
申请日：2007-12-20
IPC分类号： C07C209/00
CPC分类号： C07C209/68 , C07C211/09
摘要： A continuous process for decarboxylating carboxylic acids proceeds by I.) initially charging a carbonyl compound as a catalyst in a solvent at reaction temperature, to obtain a catalyst solution; II.) metering a carboxylic acid into the catalyst solution as an aqueous solution, aqueous suspension or as a water-comprising solid, to obtain a reaction mixture; and III.) continuously removing a mixture of CO2, solvent, water and a reaction product or mixture of reaction products from the reaction mixture as a vapor.
摘要翻译： 羧酸脱羧的连续方法由I.）在反应温度下首先将羰基化合物作为催化剂在溶剂中加入，得到催化剂溶液; II。）将羧酸作为水溶液，水性悬浮液或作为含水固体计量到催化剂溶液中，以获得反应混合物; 和III。）作为蒸气连续地从反应混合物中除去CO 2，溶剂，水和反应产物或反应产物的混合物的混合物。
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公开(公告)号：US07652180B2
公开(公告)日：2010-01-26
申请号：US11359696
申请日：2006-02-23
IPC分类号： C07C17/00
CPC分类号： B01J31/181 , C07C17/16 , C07C19/01
摘要： The invention relates to a process for preparing alkyl chlorides by reacting alcohols with gaseous hydrogen chloride in the presence of a catalyst, wherein the catalyst comprises at least one compound of the structure: wherein R1 is a linear alkyl group having from 1 to 20 carbon atoms, R2, R3, and R4 is selected from a hydrogen, an alkyl, an alkenyl, an aralkyl or an alkylaryl group from 1 to 20 carbon atoms, wherein the substituents of R2, R3, and R4 are all identical, are all different or two of the substituents of R2, R3, and R4 type are identical.
摘要翻译： 本发明涉及一种通过在催化剂存在下使醇与气态氯化氢反应制备烷基氯的方法，其中催化剂包含至少一种结构的化合物：其中R1是具有1-20个碳原子的直链烷基 R2，R3和R4选自1至20个碳原子的氢，烷基，烯基，芳烷基或烷芳基，其中R2，R3和R4的取代基全部相同，都是不同的或 R2，R3和R4型的两个取代基是相同的。
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