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1.发明授权公开(公告)号：US06897276B2
公开(公告)日：2005-05-24
申请号：US10421235
申请日：2003-04-23
申请人： Thomas R. Boussie , Gary M. Diamond , Christopher Goh , Anne M. LaPointe , Margarete K. Leclerc , James A. W. Shoemaker
发明人： Thomas R. Boussie , Gary M. Diamond , Christopher Goh , Anne M. LaPointe , Margarete K. Leclerc , James A. W. Shoemaker
IPC分类号： C07D213/32 , B01J31/00 , C07C43/23 , C07C217/80 , C07C323/12 , C07C323/18 , C07D209/86 , C07D213/70 , C07F5/00 , C07F7/00 , C07F9/00 , C07F9/50 , C08F4/44 , C08F4/60 , C08F4/602 , C08F4/64 , C08F4/642 , C08F4/645 , C08F4/659 , C08F10/00 , C08F110/06 , C08F210/02 , C08F210/16
CPC分类号： C08F10/00 , B01J31/223 , B01J31/2243 , B01J31/226 , B01J2531/0266 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07C37/055 , C07C37/62 , C07C39/367 , C07C41/16 , C07C41/26 , C07C41/30 , C07C43/23 , C07C215/74 , C07C217/80 , C07C323/20 , C07C2603/18 , C07C2603/24 , C07C2603/74 , C07D209/86 , C07F7/003 , C07F9/5022 , C08F4/65908 , C08F4/65912 , C08F110/06 , C08F210/02 , C08F210/16 , C08F212/08 , C08F4/6592 , C08F4/64186 , C08F2500/03 , C08F210/14 , C08F4/64196 , C08F4/64193 , C08F4/659 , C07C43/225 , C07C39/15 , C07C39/38 , C07C43/2055
摘要： New ligands, compositions, metal-ligand complexes and arrays with bridged bis-aromatic ligands are disclosed that catalyze the polymerization of monomers into polymers. These catalysts with metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts also polymerize propylene into isotactic polypropylene.
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2.发明授权Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom 有权桥联双芳族配体，催化剂，聚合方法和聚合物公开(公告)号：US06841502B2
公开(公告)日：2005-01-11
申请号：US10421212
申请日：2003-04-23
申请人： Thomas R. Boussie , Oliver Brümmer , Gary M. Diamond , Christopher Goh , Anne M. LaPointe , Margarete K. Leclerc , James A. W. Shoemaker
发明人： Thomas R. Boussie , Oliver Brümmer , Gary M. Diamond , Christopher Goh , Anne M. LaPointe , Margarete K. Leclerc , James A. W. Shoemaker
IPC分类号： C07D213/32 , B01J31/00 , C07C43/23 , C07C217/80 , C07C323/12 , C07C323/18 , C07D209/86 , C07D213/70 , C07F5/00 , C07F7/00 , C07F9/00 , C07F9/50 , C08F4/44 , C08F4/60 , C08F4/602 , C08F4/64 , C08F4/642 , C08F4/645 , C08F4/659 , C08F10/00 , C08F110/06 , C08F210/02 , C08F210/16
CPC分类号： C08F10/00 , B01J31/223 , B01J31/2243 , B01J31/226 , B01J2531/0266 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07C37/055 , C07C37/62 , C07C39/367 , C07C41/16 , C07C41/26 , C07C41/30 , C07C43/23 , C07C215/74 , C07C217/80 , C07C323/20 , C07C2603/18 , C07C2603/24 , C07C2603/74 , C07D209/86 , C07F7/003 , C07F9/5022 , C08F4/65908 , C08F4/65912 , C08F110/06 , C08F210/02 , C08F210/16 , C08F212/08 , C08F4/6592 , C08F4/64186 , C08F2500/03 , C08F210/14 , C08F4/64196 , C08F4/64193 , C08F4/659 , C07C43/225 , C07C39/15 , C07C39/38 , C07C43/2055
摘要： New ligands and compositions with bridged bis-aromatic ligands are disclosed that catalyze the polymerization of monomers into polymers. These catalysts with metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts also polymerize propylene into isotactic polypropylene.
摘要翻译： 公开了具有桥连双芳族配体的新配体和组合物，其催化单体聚合成聚合物。 这些具有金属中心的催化剂具有高性能特征，包括较高的共聚单体引入到乙烯/烯烃共聚物中，其中这种烯烃是例如1-辛烯，丙烯或苯乙烯。 催化剂还将丙烯聚合成全同立构聚丙烯。
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3.发明授权Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom 有权桥联双芳族配体，催化剂，聚合方法和聚合物公开(公告)号：US07659415B2
公开(公告)日：2010-02-09
申请号：US11775095
申请日：2007-07-09
申请人： Thomas R. Boussie , Oliver Brummer , Gary M. Diamond , Christopher Goh , Anne M. LaPointe , Margarete K. Leclerc , James A. W. Shoemaker
发明人： Thomas R. Boussie , Oliver Brummer , Gary M. Diamond , Christopher Goh , Anne M. LaPointe , Margarete K. Leclerc , James A. W. Shoemaker
CPC分类号： C08F10/00 , B01J31/223 , B01J31/2243 , B01J31/226 , B01J2531/0266 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07C37/055 , C07C37/62 , C07C39/367 , C07C41/16 , C07C41/26 , C07C41/30 , C07C43/23 , C07C215/74 , C07C217/80 , C07C323/20 , C07C2603/18 , C07C2603/24 , C07C2603/74 , C07D209/86 , C07F7/003 , C07F9/5022 , C08F4/65908 , C08F4/65912 , C08F110/06 , C08F210/02 , C08F210/16 , C08F212/08 , C08F4/6592 , C08F4/64186 , C08F2500/03 , C08F210/14 , C08F4/64196 , C08F4/64193 , C08F4/659 , C07C43/225 , C07C39/15 , C07C39/38 , C07C43/2055
摘要： New ligands and compositions with bridged bis-aromatic ligands are disclosed that catalyze the polymerization of monomers into polymers. These catalysts with metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts also polymerize propylene into isotactic polypropylene.
摘要翻译： 公开了具有桥连双芳族配体的新配体和组合物，其催化单体聚合成聚合物。 这些具有金属中心的催化剂具有高性能特征，包括较高的共聚单体引入到乙烯/烯烃共聚物中，其中这种烯烃是例如1-辛烯，丙烯或苯乙烯。 催化剂还将丙烯聚合成全同立构聚丙烯。
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4.发明授权Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom 有权桥联双芳族配体，催化剂，聚合方法和聚合物公开(公告)号：US07241715B2
公开(公告)日：2007-07-10
申请号：US11436145
申请日：2006-05-16
申请人： Thomas R. Boussie , Oliver Brümmer , Gary M. Diamond , Christopher Goh , Anne M. LaPointe , Margarete K. Leclerc , James A. W. Shoemaker
发明人： Thomas R. Boussie , Oliver Brümmer , Gary M. Diamond , Christopher Goh , Anne M. LaPointe , Margarete K. Leclerc , James A. W. Shoemaker
CPC分类号： C08F10/00 , B01J31/223 , B01J31/2243 , B01J31/226 , B01J2531/0266 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07C37/055 , C07C37/62 , C07C39/367 , C07C41/16 , C07C41/26 , C07C41/30 , C07C43/23 , C07C215/74 , C07C217/80 , C07C323/20 , C07C2603/18 , C07C2603/24 , C07C2603/74 , C07D209/86 , C07F7/003 , C07F9/5022 , C08F4/65908 , C08F4/65912 , C08F110/06 , C08F210/02 , C08F210/16 , C08F212/08 , C08F4/6592 , C08F4/64186 , C08F2500/03 , C08F210/14 , C08F4/64196 , C08F4/64193 , C08F4/659 , C07C43/225 , C07C39/15 , C07C39/38 , C07C43/2055
摘要： New ligands and compositions with bridged bis-aromatic ligands are disclosed that catalyze the polymerization of monomers into polymers. These catalysts with metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts also polymerize propylene into isotactic polypropylene.
摘要翻译： 公开了具有桥连双芳族配体的新配体和组合物，其催化单体聚合成聚合物。 这些具有金属中心的催化剂具有高性能特征，包括较高的共聚单体引入到乙烯/烯烃共聚物中，其中这种烯烃是例如1-辛烯，丙烯或苯乙烯。 催化剂还将丙烯聚合成全同立构聚丙烯。
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5.发明授权Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom 有权桥联双芳族配体，催化剂，聚合方法和聚合物公开(公告)号：US07030256B2
公开(公告)日：2006-04-18
申请号：US11034410
申请日：2005-01-12
申请人： Thomas R. Boussie , Gary M. Diamond , Christopher Goh , Anne M. LaPointe , Margarete K. Leclerc , James A. W. Shoemaker
发明人： Thomas R. Boussie , Gary M. Diamond , Christopher Goh , Anne M. LaPointe , Margarete K. Leclerc , James A. W. Shoemaker
CPC分类号： C08F10/00 , B01J31/223 , B01J31/2243 , B01J31/226 , B01J2531/0266 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07C37/055 , C07C37/62 , C07C39/367 , C07C41/16 , C07C41/26 , C07C41/30 , C07C43/23 , C07C215/74 , C07C217/80 , C07C323/20 , C07C2603/18 , C07C2603/24 , C07C2603/74 , C07D209/86 , C07F7/003 , C07F9/5022 , C08F4/65908 , C08F4/65912 , C08F110/06 , C08F210/02 , C08F210/16 , C08F212/08 , C08F4/6592 , C08F4/64186 , C08F2500/03 , C08F210/14 , C08F4/64196 , C08F4/64193 , C08F4/659 , C07C43/225 , C07C39/15 , C07C39/38 , C07C43/2055
摘要： New ligands, compositions, metal-ligand complexes and arrays with bridged bis-aromatic ligands are disclosed that catalyze the polymerization of monomers into polymers. These catalysts with metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts also polymerize propylene into isotactic polypropylene.
摘要翻译： 公开了新配体，组合物，金属 - 配体络合物和具有桥连双芳族配体的阵列，其催化单体聚合成聚合物。 这些具有金属中心的催化剂具有高性能特征，包括较高的共聚单体引入到乙烯/烯烃共聚物中，其中这种烯烃是例如1-辛烯，丙烯或苯乙烯。 催化剂还将丙烯聚合成全同立构聚丙烯。
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6.发明授权Methods of copolymerizing ethylene and isobutylene and polymers made thereby 失效共聚乙烯和异丁烯的方法以及由此制备的聚合物公开(公告)号：US06828397B2
公开(公告)日：2004-12-07
申请号：US09992760
申请日：2001-11-06
申请人： Thomas R. Boussie , Gary M. Diamond , Christopher Goh , Keith A. Hall , Anne M. LaPointe , Margarete K. Leclerc , Cheryl Lund , Vince Murphy
发明人： Thomas R. Boussie , Gary M. Diamond , Christopher Goh , Keith A. Hall , Anne M. LaPointe , Margarete K. Leclerc , Cheryl Lund , Vince Murphy
IPC分类号： C08F444
CPC分类号： C07D213/74 , B01J2219/00722 , C07B2200/11 , C07D213/38 , C07D213/61 , C07D213/68 , C07F7/00 , C07F7/003 , C07F9/58 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/02 , C08F210/16 , C40B40/14 , C08F4/659 , C08F4/65904 , C08F2500/15 , C08F2500/02 , C08F210/10 , C08F212/08 , C08F210/14 , C08F4/64144 , C08F4/64113 , C08F4/64044
摘要： New ligands, compositions, metal-ligand complexes and arrays with pyridyl-amine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.
摘要翻译： 公开了新配体，组合物，金属 - 配体络合物和具有吡啶基 - 胺配体的阵列，其催化单体聚合成聚合物。 这些具有铪金属中心的这些催化剂中的某些具有高性能特征，包括较高的共聚单体引入到乙烯/烯烃共聚物中，其中这种烯烃是例如1-辛烯，异丁烯或苯乙烯。 某些催化剂在各种聚合条件下在溶液过程中将丙烯聚合成高分子量全同立构聚丙烯是特别有效的。
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公开(公告)号：US06965004B2
公开(公告)日：2005-11-15
申请号：US10850585
申请日：2004-05-20
申请人： Oliver Brümmer , Gary M. Diamond , Christopher Goh , Anne M. LaPointe , Margarete K. Leclerc , James Longmire , James A. W. Shoemaker
发明人： Oliver Brümmer , Gary M. Diamond , Christopher Goh , Anne M. LaPointe , Margarete K. Leclerc , James Longmire , James A. W. Shoemaker
IPC分类号： C07D249/06 , C07F7/00 , C08F4/06 , C08F4/642 , C08F4/659 , C08F210/02 , C08F212/08 , C08F4/44
CPC分类号： C08F210/02 , C07D249/06 , C07F7/00 , C07F7/003 , C08F4/65908 , C08F4/65912 , C08F4/659 , C08F4/64 , C08F212/08 , C08F2500/03
摘要： Metal-ligand complexes that are useful as precursors to catalysts for the polymerization of olefins are provided. Certain of the catalysts are particularly effective at polymerizing ethylene and styrene into copolymers having novel properties, including a low molecular weight and close comparison between vinyl and methyl end groups.
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8.发明授权Ethylene-styrene copolymers and phenol-triazole type complexes, catalysts, and processes for polymerizing 失效乙烯 - 苯乙烯共聚物和苯酚 - 三唑型络合物，催化剂和聚合方法公开(公告)号：US06933355B2
公开(公告)日：2005-08-23
申请号：US10850600
申请日：2004-05-20
申请人： Oliver Brümmer , Gary M. Diamond , Christopher Goh , Anne M. LaPointe , Margarete K. Leclerc , James Longmire , James A. W. Shoemaker
发明人： Oliver Brümmer , Gary M. Diamond , Christopher Goh , Anne M. LaPointe , Margarete K. Leclerc , James Longmire , James A. W. Shoemaker
IPC分类号： C07D249/06 , C07F7/00 , C08F4/06 , C08F4/642 , C08F4/659 , C08F210/02 , C08F4/44 , C07D227/02
CPC分类号： C08F210/02 , C07D249/06 , C07F7/00 , C07F7/003 , C08F4/65908 , C08F4/65912 , C08F4/659 , C08F4/64 , C08F212/08 , C08F2500/03
摘要： Metal-ligand complexes that are useful as precursors to catalysts for the polymerization of olefins are provided. Certain of the catalysts are particularly effective at polymerizing ethylene and styrene into copolymers having novel properties, including a low molecular weight and close comparison between vinyl and methyl end groups.
摘要翻译： 提供了可用作烯烃聚合催化剂前体的金属 - 配体络合物。 某些催化剂特别有效地将乙烯和苯乙烯聚合成具有新特性的共聚物，包括低分子量和乙烯基和甲基端基之间的紧密比较。
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9.发明授权公开(公告)号：US07074870B2
公开(公告)日：2006-07-11
申请号：US11234712
申请日：2005-09-23
申请人： Oliver Brümmer , Gary M. Diamond , Christopher Goh , Anne M. LaPointe , Margarete K. Leclerc , James Longmire , James A. W. Shoemaker
发明人： Oliver Brümmer , Gary M. Diamond , Christopher Goh , Anne M. LaPointe , Margarete K. Leclerc , James Longmire , James A. W. Shoemaker
IPC分类号： C08F212/08 , C08F4/44
CPC分类号： C08F210/02 , C07D249/06 , C07F7/00 , C07F7/003 , C08F4/65908 , C08F4/65912 , C08F4/659 , C08F4/64 , C08F212/08 , C08F2500/03
摘要： Metal-ligand complexes that are useful as precursors to catalysts for the polymerization of olefins are provided. Certain of the catalysts are particularly effective at polymerizing ethylene and styrene into copolymers having novel properties, including a low molecular weight and close comparison between vinyl and methyl end groups.
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10.发明授权公开(公告)号：US06794514B2
公开(公告)日：2004-09-21
申请号：US10121300
申请日：2002-04-12
申请人： Oliver Brümmer , Gary M. Diamond , Christopher Goh , Anne M. LaPointe , Margarete K. Leclerc , James A. W. Shoemaker
发明人： Oliver Brümmer , Gary M. Diamond , Christopher Goh , Anne M. LaPointe , Margarete K. Leclerc , James A. W. Shoemaker
IPC分类号： C07D22702
CPC分类号： C08F210/02 , C07D249/06 , C07F7/00 , C07F7/003 , C08F4/65908 , C08F4/65912 , C08F4/659 , C08F4/64 , C08F212/08 , C08F2500/03
摘要： Metal-ligand complexes that are useful as precursors to catalysts for the polymerization of olefins are provided. Certain of the catalysts are particularly effective at polymerizing ethylene and styrene into copolymers having novel properties, including a low molecular weight and close comparison between vinyl and methyl end groups.
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