公开(公告)号：US20120157711A1

公开(公告)日：2012-06-21

申请号：US13330974

申请日：2011-12-20

申请人： Thomas Schaub ,  Donata Maria Fries ,  Rocco Paciello ,  Klaus-Dieter Mohl ,  Martin Schäfer ,  Stefan Rittinger ,  Petra Deckert ,  Peter Bassler

发明人： Thomas Schaub ,  Donata Maria Fries ,  Rocco Paciello ,  Klaus-Dieter Mohl ,  Martin Schäfer ,  Stefan Rittinger ,  Petra Deckert ,  Peter Bassler

IPC分类号： C07C53/02

CPC分类号： C07C51/412 ,  C07C51/02 ,  C07C51/41 ,  C07C51/44 ,  C07C51/48 ,  C07C53/02 ,  C07C53/06

摘要： The present invention relates to a process for preparing formic acid by reacting carbon dioxide (1) with hydrogen (2) in a hydrogenation reactor (I) in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine comprising at least 12 carbon atoms per molecule and a polar solvent comprising one or more monoalcohols selected from among methanol, ethanol, propanols and butanols, to form formic acid/amine adducts as intermediates which are subsequently thermally dissociated, where a tertiary amine having a boiling point which is at least 5° C. higher than that of formic acid is used and a reaction mixture comprising the polar solvent, the formic acid/amine adducts, the tertiary amine and the catalyst is formed in the reaction in the hydrogenation reactor (I) and is discharged from the reactor as output (3).

摘要翻译： 本发明涉及一种通过使二氧化碳（1）与氢（2）在氢化反应器（I）中在含有周期表第8,9或10族元素的催化剂存在下反应来制备甲酸的方法 ，每分子含有至少12个碳原子的叔胺和包含一种或多种选自甲醇，乙醇，丙醇和丁醇的一元醇的极性溶剂，以形成甲酸/胺加合物作为随后热解离的中间体，其中第三 使用沸点比甲酸高至少5℃的胺，并且在反应中形成包含极性溶剂，甲酸/胺加合物，叔胺和催化剂的反应混合物 氢化反应器（I），并作为输出（3）从反应器排出。

公开(公告)号：US20130012739A1

公开(公告)日：2013-01-10

申请号：US13542791

申请日：2012-07-06

申请人： Thomas Schaub ,  Donata Maria Fries ,  Rocco Paciello ,  Peter Bassler ,  Martin Schäfer ,  Stefan Rittinger

发明人： Thomas Schaub ,  Donata Maria Fries ,  Rocco Paciello ,  Peter Bassler ,  Martin Schäfer ,  Stefan Rittinger

IPC分类号： C07C51/15

CPC分类号： C07C51/44 ,  C07C51/48 ,  C07C51/487 ,  C07C53/02

摘要： A process for preparing formic acid by reacting carbon dioxide with hydrogen in a hydrogenation reactor in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine and a polar solvent to form formic acid-amine adducts which are subsequently dissociated thermally into formic acid and tertiary amine.

摘要翻译： 在含有元素周期表第8,9或10族元素的催化剂存在下，在氢化反应器中使二氧化碳与氢反应制备甲酸的方法，叔胺和极性溶剂以形成甲酸 - 胺 加成物随后被热分解成甲酸和叔胺。

公开(公告)号：US20130190532A1

公开(公告)日：2013-07-25

申请号：US13721296

申请日：2012-12-20

申请人： Daniel Schneider ,  Klaus-Dieter Mohl ,  Martin Schäfer ,  Donata Maria Fries ,  Joaquim Henrique Teles ,  Peter Bassler ,  Stefan Rittinger ,  Thomas Schaub

发明人： Daniel Schneider ,  Klaus-Dieter Mohl ,  Martin Schäfer ,  Donata Maria Fries ,  Joaquim Henrique Teles ,  Peter Bassler ,  Stefan Rittinger ,  Thomas Schaub

IPC分类号： C07C51/44

CPC分类号： C07C51/44 ,  C07C51/02 ,  C07C53/06 ,  C07C53/02

摘要： Process for obtaining formic acid by thermal separation of a stream comprising formic acid and a tertiary amine (I), in which a liquid stream comprising formic acid, tertiary amine (I) and water is produced by combining tertiary amine (I) and a formic acid source in the presence of water, water and organic decomposition products of the tertiary amine (I) are removed and formic acid is removed by distillation from the resulting liquid stream in a distillation apparatus, wherein the stream comprising water and organic decomposition products of the tertiary amine (I) which have been separated off is separated into two liquid phases, the upper liquid phase is removed and the lower, water-comprising liquid phase is recirculated to the formic acid source.

摘要翻译： 通过热分离包含甲酸和叔胺（I）的流来获得甲酸的方法，其中包含甲酸，叔胺（I）和水的液体流通过将叔胺（I）和甲酸 在水，水和叔胺（I）的有机分解产物存在下，酸源，在蒸馏装置中从所得液流中蒸馏除去甲酸，其中包含水和有机分解产物的流 已经分离出的叔胺（I）分离成两个液相，去除上部液相，将含较低水的液相再循环至甲酸源。

公开(公告)号：US07786317B2

公开(公告)日：2010-08-31

申请号：US12159404

申请日：2006-12-18

申请人： Hans-Georg Goebbel ,  Peter Bassler ,  Joaquim Henrique Teles ,  Peter Rudolf ,  Ulrich Mueller ,  Anna Forlin ,  Malte Schulz ,  Meinolf Weidenbach

发明人： Hans-Georg Goebbel ,  Peter Bassler ,  Joaquim Henrique Teles ,  Peter Rudolf ,  Ulrich Mueller ,  Anna Forlin ,  Malte Schulz ,  Meinolf Weidenbach

IPC分类号： C07D301/12

CPC分类号： C07D301/12

摘要： The present invention provides a process for the epoxidation of propene which comprises reacting propene with hydrogen peroxide in the presence of methanol as solvent and a titanium zeolite catalyst, the process further comprising separating propylene oxide from the reaction mixture to obtain a mixture comprising methanol, water, at least one carboxylic acid and at least one carbonyl compound, wherein the at least one carboxylic acid is at least partially neutralized, said process optionally comprising a hydrogenation stage.

摘要翻译： 本发明提供丙烯环氧化方法，其包括在甲醇作为溶剂和钛沸石催化剂的存在下使丙烯与过氧化氢反应，该方法还包括从反应混合物中分离环氧丙烷以获得包含甲醇，水 ，至少一种羧酸和至少一种羰基化合物，其中所述至少一种羧酸被至少部分中和，所述方法任选地包含氢化阶段。

公开(公告)号：US07566800B2

公开(公告)日：2009-07-28

申请号：US10586481

申请日：2005-01-27

申请人： Jens Scheidel ,  Christian Miller ,  Robert Baumann ,  Tim Jungkamp ,  Michael Bartsch ,  Gerd Haderlein ,  Hermann Luyken ,  Wolfgang Siegel ,  Peter Bassler

发明人： Jens Scheidel ,  Christian Miller ,  Robert Baumann ,  Tim Jungkamp ,  Michael Bartsch ,  Gerd Haderlein ,  Hermann Luyken ,  Wolfgang Siegel ,  Peter Bassler

IPC分类号： C07D291/00

CPC分类号： C07C253/30 ,  Y02P20/127 ,  C07C255/07

摘要： The invention relates to a method for isomerization of pentene nitrile in an educt flow, wherein isomerization is performed on a homogeneously dissolved catalyst.

摘要翻译： 本发明涉及一种在流出物流中异戊烯腈的方法，其中异构化在均匀溶解的催化剂上进行。

公开(公告)号：US07408073B2

公开(公告)日：2008-08-05

申请号：US10532096

申请日：2003-10-23

申请人： Peter Bassler ,  Hans-Georg Goebbel ,  Joaquim Henrique Teles ,  Peter Rudolf

发明人： Peter Bassler ,  Hans-Georg Goebbel ,  Joaquim Henrique Teles ,  Peter Rudolf

IPC分类号： C07D301/12

CPC分类号： C07D301/12

摘要： Process for the continuous recirculation of the olefin which has not been reacted in the epoxidation of olefins by means of hydroperoxide to give oxiranes and is present in the offgas stream formed during the epoxidation, which comprises the steps (i) to (iii) (i) compressing and cooling the offgas stream, (ii) seperating the olefin from the offgas stream obtain in step (i) by distillation, (iii) epoxidizing the olefin seperating off in step (ii) by means of hydroperoxide.

摘要翻译： 通过氢过氧化物在烯烃的环氧化中未反应的烯烃的连续再循环以产生环氧乙烷并存在于环氧化期间形成的废气流中的方法，其包括步骤（i）至（iii）（i 压缩和冷却废气流，（ii）通过蒸馏在步骤（i）中从废气流中分离出烯烃，（iii）通过氢过氧化物环化在步骤（ii）中分离出的烯烃。

公开(公告)号：US20060247459A1

公开(公告)日：2006-11-02

申请号：US10554209

申请日：2004-04-21

申请人： Wolfram Stuer ,  Jens Scheidel ,  Peter Bassler

发明人： Wolfram Stuer ,  Jens Scheidel ,  Peter Bassler

IPC分类号： C07F17/02 ,  C07C69/02 ,  C07C253/30

CPC分类号： C07C67/303 ,  C07C67/343 ,  C07C69/44 ,  C07C69/54

摘要： A process for hydrogenating a monoolefinically unsaturated compound which bears at least two functional groups which are each independently selected from the group consisting of nitrile group, carboxylic acid group, carboxylic ester group, carboxamide group to a saturated compound which bears the same at least two functional groups, in the presence of a rhodium-containing compound, as a catalyst, which is homogeneous with respect to the reaction mixture.

摘要翻译： 将含有至少两个官能团的单烯属不饱和化合物氢化的方法，所述化合物各自独立地选自腈基，羧酸基，羧酸酯基，羧酰胺基团，其饱和化合物与至少两个官能团 在含铑化合物的存在下，作为催化剂，其相对于反应混合物是均匀的。

公开(公告)号：US20060201798A1

公开(公告)日：2006-09-14

申请号：US10553537

申请日：2004-04-15

申请人： Michael Bartsch ,  Robert Baumann ,  Gerd Haderlein ,  Miguel Flores ,  Tim Jungkamp ,  Hermann Luyken ,  Jens Scheidel ,  Wolfgang Siegel ,  Dagmar Kunsmann-Keitel ,  Peter Bassler

发明人： Michael Bartsch ,  Robert Baumann ,  Gerd Haderlein ,  Miguel Flores ,  Tim Jungkamp ,  Hermann Luyken ,  Jens Scheidel ,  Wolfgang Siegel ,  Dagmar Kunsmann-Keitel ,  Peter Bassler

IPC分类号： C01C3/04

CPC分类号： C07C253/10 ,  B01J2219/0011 ,  C01C3/0295 ,  C07C255/04

摘要： A process for dewatering hydrocyanic acid by distillation, which comprises distilling crude hydrocyanic acid containing from 50 to 99.9% by weight of HCN, from 0.1 to 40% by weight of water, from 0 to 15% by weight of carbon oxides and optionally from 0.01 to 1% by weight of an involatile stablilizer, at a pressure of from 1 bar to 2.5 bar, a bottom temperature of from 100° C. to 130° C. and a top temperature of from 25° C. to 54° C., in the absence of a volatile stabilizer, in a distillation column to obtain a top draw stream containing purified, anhydrous hydrocyanic acid and carbon oxides and a bottom draw stream comprising water and, where appropriate, the involatile stabilizer.

摘要翻译： 一种通过蒸馏使氢氰酸脱水的方法，该方法包括将含有50-99.9重量％HCN的粗制氢氰酸，0.1-40重量％的水，0-15重量％的碳氧化物和任选的0.01 至1重量％的非挥发性固化剂，压力为1巴至2.5巴，底部温度为100℃至130℃，顶部温度为25℃至54℃。 在不存在挥发性稳定剂的情况下，在蒸馏塔中获得含有纯化的无水氢氰酸和碳氧化物的顶部牵引流和包含水的底部牵引流，以及适当时的非挥发性稳定剂。

公开(公告)号：US20060167286A1

公开(公告)日：2006-07-27

申请号：US10526939

申请日：2003-09-16

申请人： Ulrich Mueller ,  Georg Krug ,  Peter Bassler ,  Hans-Georg Gobbel ,  Peter Rudolf ,  Joaquim Teles

发明人： Ulrich Mueller ,  Georg Krug ,  Peter Bassler ,  Hans-Georg Gobbel ,  Peter Rudolf ,  Joaquim Teles

IPC分类号： B01J29/04 ,  C07D301/19

CPC分类号： C07D301/19 ,  B01J29/89 ,  B01J37/10 ,  B01J2229/36 ,  B01J2229/40 ,  C07D301/12 ,  Y02P20/125

摘要： The present invention relates to a process for treating a solid material containing at least one zeolite and being at least partly crystalline or treating a shaped body obtained from said solid material wherein said solid material or shaped body is brought in contact with a composition containing water after at least one of the following steps of an integrated process for producing a solid material or a shaped body containing at least one zeolite: (i) after step (II) of separating the at least partly crystalline solid material from its mother liquor or (ii) after step (S) of shaping said solid material into a shaped body or (iii) after a step (C) of calcining said solid material or said shaped body. The present invention furthermore relates to the solid material obtainable by the inventive process and the shaped body obtainable by the inventive process. The present invention also relates to the use of the solid material or the shaped body as mentioned above as a catalyst in chemical reactions, in particular in reactions of compounds containing at least one C-C double bond with at least one hydroperoxide.

摘要翻译： 本发明涉及一种用于处理含有至少一种沸石并且至少部分结晶的固体材料或处理由所述固体材料获得的成形体的方法，其中所述固体材料或成形体与含有水的组合物接触 用于生产固体材料或含有至少一种沸石的成形体的整合方法中的至少一个步骤：（i）在从母液中分离出至少部分结晶固体材料的步骤（II）之后，或（ii ）在将所述固体材料成形为成形体的步骤（S）之后或（iii）在煅烧所述固体材料或所述成形体的步骤（C）之后。 本发明还涉及可通过本发明方法获得的固体材料和通过本发明方法获得的成形体。 本发明还涉及如上所述的固体材料或成形体作为化学反应中的催化剂，特别是在含有至少一个C-C双键的化合物与至少一种氢过氧化物的反应中的用途。

公开(公告)号：US20050240037A1

公开(公告)日：2005-10-27

申请号：US10521359

申请日：2003-07-22

申请人： Peter Bassler ,  Hans-Georg Gobbel ,  Joaquin Teles ,  Peter Rudolf

发明人： Peter Bassler ,  Hans-Georg Gobbel ,  Joaquin Teles ,  Peter Rudolf

IPC分类号： B01D3/14 ,  B01D3/42 ,  C07D301/32 ,  C07D301/19

CPC分类号： B01D3/141 ,  B01D3/146 ,  B01D3/4222 ,  C07D301/32

摘要： Process for the continuously operated distillation of the solvent used in the synthesis of an oxirane by reaction of a hydroperoxide with an organic compound, wherein the mixture comprising the solvent which is obtained in the synthesis and subsequent work-up is separated in a dividing wall column into a low-boiling fraction, an intermediate-boiling fraction and a high-boiling fraction and the solvent is taken off as intermediate-boiling fraction from the side offtake of the column.

摘要翻译： 用于通过氢过氧化物与有机化合物的反应合成环氧乙烷的溶剂的连续蒸馏方法，其中将包含在合成和后续后处理中获得的溶剂的混合物在分隔壁塔中分离 进入低沸点馏分，中间沸点馏分和高沸点馏分，溶剂作为中间沸点馏分从塔的出料侧取出。