Preparation of crosslinkable water-soluble or water-dispersible compositions and radiation-sensitive mixtures obtainable therefrom
    1.
    发明授权
    Preparation of crosslinkable water-soluble or water-dispersible compositions and radiation-sensitive mixtures obtainable therefrom 失效
    制备可交联的水溶性或水分散性组合物和由其获得的辐射敏感性混合物

    公开(公告)号:US06368772B1

    公开(公告)日:2002-04-09

    申请号:US09324713

    申请日:1999-06-03

    IPC分类号: G03C173

    CPC分类号: G03F7/0388

    摘要: Process for functionalizing a water-soluble or water-dispersible polymeric organic binder, in which unmodified, water-soluble or water-dispersible polymeric organic binders are reacted with one or more polar aprotic swelling agents which are compatible with the binder, with thorough mixing with one or more compounds which have groups capable of free radical polymerization, compositions obtainable thereby and radiation-sensitive mixtures which contain, as essential components, the above composition, at least one photopolymerization initiator, if required one or more ethylenically unsaturated, photopolymerizable low molecular weight compounds which are compatible with the polymeric binder and further conventional additives and/or assistants, and radiation-sensitive letterpress or relief printing plates which can be produced therefrom.

    摘要翻译: 官能化水溶性或水分散性聚合物有机粘合剂的方法,其中未改性的水溶性或水分散性聚合物有机粘合剂与一种或多种与粘合剂相容的极性非质子溶胀剂反应,与 具有能够进行自由基聚合的基团的一种或多种化合物,由此获得的组合物和含有作为必要组分的上述组合物的辐射敏感性混合物,如果需要,至少一种光聚合引发剂一种或多种烯属不饱和的可光聚合的低分子量 与聚合物粘合剂和其它常规添加剂和/或辅助剂相容的化合物,以及可由其生产的辐射敏感凸版印刷版或凸版印刷版。

    Photosensitive, flexo printing element and method for the production of newspaper flexo printing plates
    7.
    发明授权
    Photosensitive, flexo printing element and method for the production of newspaper flexo printing plates 有权
    感光柔版印刷元件和生产报纸柔版印刷版的方法

    公开(公告)号:US07235346B2

    公开(公告)日:2007-06-26

    申请号:US10485201

    申请日:2002-07-18

    IPC分类号: G03F7/028 G03F7/032 G03F7/11

    摘要: The present invention relates to a photosensitive flexographic printing element for the production of flexographic newspaper printing plates, comprising at least a flexible, metallic support, an adhesive layer applied thereto, a photopolymerizable layer which can be developed in organic media and which itself comprises at least one elastomeric binder, ethylenically unsaturated monomers, a photoinitiator or photoinitiator system and a plasticizer, a transparent substrate layer, and optionally a removable protective film, where the total thickness of the flexographic printing element is from 300 to 1000 μm, the elastomeric binder has a weight average molecular weight Mw of from 80,000 to 150,000 g/mol and a Shore A hardness of from 50 to 80, and the amount of plasticizer is from 5 to 50% by weight, based on the amount of all constituents of the photopolymerizable layer, and to a process for the production of flexographic newspaper printing plates by imagewise exposure of the flexographic printing element to actinic light, followed by development and drying at from 105 to 160° C.

    摘要翻译: 本发明涉及一种用于生产柔版印刷印版的感光性柔性版印刷元件,其至少包括柔性金属支撑体,施加到其上的粘合剂层,可在有机介质中显影的可光聚合层,并且其本身至少包括 一种弹性粘合剂,烯属不饱和单体,光引发剂或光引发剂体系和增塑剂,透明基材层和任选的可除去的保护膜,其中柔性版印刷元件的总厚度为300至1000μm,弹性粘合剂具有 重量平均分子量M w s为80,000至150,000g / mol,肖氏A硬度为50至80,增塑剂的量为5至50重量%,基于 的可光聚合层的所有组分,以及通过成像曝光生产柔版印刷版印刷版的方法 柔性版印刷元件进行光化,然后在105至160℃下显影和干燥。

    Material for gravure recording by means of coherent electromagnetic radiation and printing plate therewith
    9.
    发明授权
    Material for gravure recording by means of coherent electromagnetic radiation and printing plate therewith 失效
    通过相干电磁辐射凹版印刷的材料和印版

    公开(公告)号:US06214521B1

    公开(公告)日:2001-04-10

    申请号:US09382149

    申请日:1999-08-24

    IPC分类号: G03C173

    摘要: A material for gravure recording by means of coherent electromagnetic radiation for letterpress printing, consisting of a substrate and a crosslinkable layer, with or without a release layer and/or cover sheet, the layer containing at least one ethylenically unsaturated compound, a polymerization initiator and at least one polymeric binder which consists of polyvinyl alcohol and/or at least one copolymer having a substantial proportion of the structural unit and containing a filler having a ceiling temperature of less than 800K, in particular less than 600K, e.g. polystyrene, polymethyl methacrylate, poly(ethylene)ketone, polyoxymethylene or poly(&agr;-methylstyrene), in particular having a spherical or roughly spherical form with a maximum dimension of about 5-10 &mgr;m. The material is very suitable for laser-engravable letterpress printing plates.

    摘要翻译: 用于通过用于凸版印刷的相干电磁辐射的凹版记录的材料,由具有或不具有剥离层和/或覆盖片的基底和可交联层组成,所述层含有至少一种烯键式不饱和化合物,聚合引发剂和 至少一种聚合物粘合剂,其由聚乙烯醇和/或至少一种共聚物组成,所述共聚物具有相当大比例的结构单元,并且含有顶部温度小于800K,特别是小于600K的填料,例如 聚苯乙烯,聚甲基丙烯酸甲酯,聚(乙烯)酮,聚甲醛或聚(α-甲基苯乙烯),特别是具有约5-10μm的最大尺寸的球形或粗球形。 该材料非常适合激光雕刻凸版印刷版。