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    Liquid cleaner composition for removing polymeric materials from a surface
    1.
    发明授权
    Liquid cleaner composition for removing polymeric materials from a surface 失效
    用于从表面去除聚合材料的液体清洁剂组合物

    公开(公告)号：US5176986A

    公开(公告)日：1993-01-05

    申请号：US356933

    申请日：1989-05-25

    申请人： Thomas Telser ,  Wolfgang Huemmer ,  Horst Koch ,  Karl-Rudolf Kurtz ,  Heinz-Ulrich Werther ,  Beinhard Schneider

    发明人： Thomas Telser ,  Wolfgang Huemmer ,  Horst Koch ,  Karl-Rudolf Kurtz ,  Heinz-Ulrich Werther ,  Beinhard Schneider

    IPC分类号： G03F7/00 ,  C11D3/43 ,  C11D10/02 ,  C11D17/00 ,  G03F7/30 ,  G03F7/32

    CPC分类号： G03F7/32 ,  C11D3/43

    摘要： A new liquid cleaner composition is provided for the mild and gentle removal of polymeric materials from sufaces without leaving any residues. The said new cleaner composition is an emulsion of the water-in-oil type comprising an aqueous phase finely dispersed in a continuous phase selected from the group consisting of nonflammable, fire-retardant, high-boiling, and fire-retardant and high-boiling organic phases, the volume ratio of the finely dispersed aqueous phase to the continuous organic phase being in the range of from 90:10 to 10:90. The new liquid cleaner composition can contain alcohols, surface-active agents and further useful additives. The new liquid cleaner composition is most preferably used in the process for preparing photopolymerized flexographic relief printing plates as the developer for washing out the non-irradiated and thus non-photopolymerized areas of the imagewise irradiated relief-forming recording layers of the said flexographic relief printing plates.

    摘要翻译： 提供了一种新的液体清洁剂组合物，用于从表面温和和温和地除去聚合材料，而不留下任何残留物。 所述新型清洁剂组合物是油包水型的乳液，其包含精细分散在连续相中的水相，所述连续相选自不可燃，阻燃，高沸点，阻燃和高沸点 有机相，细分散水相与连续有机相的体积比在90:10至10:90的范围内。 新的液体清洁剂组合物可以含有醇，表面活性剂和其它有用的添加剂。 新的液体清洗剂组合物最优选用于制备光聚合柔版印刷印版的方法，作为用于洗出所述柔性印版印刷的图像照射的浮雕形成记录层的未经照射且因此非光聚合区域的显影剂 盘子

    Photosensitive recording element having a recording layer and a top layer possessing different solubility properties, and its development in one operation
    2.
    发明授权
    Photosensitive recording element having a recording layer and a top layer possessing different solubility properties, and its development in one operation 失效
    具有记录层和具有不同溶解度特性的顶层的感光记录元件及其在一次操作中的发展

    公开(公告)号：US6040116A

    公开(公告)日：2000-03-21

    申请号：US892350

    申请日：1997-07-14

    申请人： Thomas Telser ,  Wolfgang Huemmer ,  Karl-Rudolf Kurtz

    发明人： Thomas Telser ,  Wolfgang Huemmer ,  Karl-Rudolf Kurtz

    IPC分类号： G03F7/09 ,  G03F7/32

    CPC分类号： G03F7/092 ,  G03F7/32

    摘要： A novel photosensitive recording element having a dimensionally stable substrate (A), a photopolymerizable relief-forming recording layer (B), which may consist of two or more individual layers (B), and an optically transparent top layer (C) firmly adhering to the surface of (B) is used for the production of a flexographic relief printing plate. Imagewise exposure of the photopolymerizable relief-forming recording layer (B) of the novel photosensitive recording element to actinic light results in a difference between the solubilities of its exposed and unexposed parts, so that its unexposed parts can be washed out (developed) with a solvent. On the other hand, the optically transparent top layer (C) of the novel photosensitive recording element is insoluble or nonswellable in the relevant solvent. The imagewise exposed novel photosensitive recording element can nevertheless be developed in one operation with the aid of an emulsion of the water-in-oil or oil-in-water type. These emulsions are also suitable for developing imagewise exposed photosensitive recording elements whose photopolymerizable relief-forming recording layer (B) consist of two or more individual layers (B) having different solubility properties. In this case too, development is effected in one operation.

    摘要翻译： 具有尺寸稳定的基板（A），可由两个以上的单层（B）构成的光聚合性凸版形成记录层（B）和光学透明的顶层（C）的新颖的光敏记录元件， （B）的表面用于生产柔版印刷印版。 新型感光记录元件的光致聚合缓冲形成记录层（B）的图像曝光与光化光导致其曝光部分和未曝光部分的溶解度之间的差异，使得其未曝光部分可以用 溶剂。 另一方面，新型光敏记录元件的光学透明顶层（C）在相关溶剂中是不溶的或不可溶的。 借助于油包水型或水包油型的乳液，可以在一次操作中开发成像曝光的新型光敏记录元件。 这些乳剂也适用于显影成像曝光的感光记录元件，其光聚合缓冲形成记录层（B）由具有不同溶解性的两个或多个单层（B）组成。 在这种情况下，开发也是在一个操作中实现的。

    Polymer ammonium salts
    4.
    发明授权
    Polymer ammonium salts 失效
    聚合物铵盐

    公开(公告)号：US4900795A

    公开(公告)日：1990-02-13

    申请号：US200951

    申请日：1988-06-02

    申请人： Gerhard Hoffmann ,  Wolfgang Huemmer ,  Horst Koch ,  Dieter Littmann

    发明人： Gerhard Hoffmann ,  Wolfgang Huemmer ,  Horst Koch ,  Dieter Littmann

    IPC分类号： C08F8/00 ,  C08F2/48 ,  C08F8/44 ,  C08F290/00 ,  C08F299/00

    CPC分类号： C08F8/44

    摘要： In polymer ammonium salts which are formed from a copolymer (A) which can be modified by a polymer-analogous reaction and from one or more amines (B), the copolymer (A) is obtainable by copolymerization of a monomer mixture of(a.sub.1) ethylene,(a.sub.2) acrylic acid and/or methacrylic acid, and(a.sub.3) one or more further monomers from the group consisting of the vinyl esters, vinyl ethers, acrylates, methacrylates, acrylamides and methacrylamides, and the amines (B) are selected from the group consisting of the(b.sub.1) cyclic amines of the general formula I ##STR1## and/or from the group consisting of the (b.sub.2) open-chain amines of the general formula II ##STR2## and/or from the group consisting of (b.sub.3) 1,4-thiazine, N,N',N"-trisvinylmelamine and N,N',N"-triallylmelamine, Z, R.sup.1, R.sup.2 and R.sup.3 having the meanings stated in the description.

    摘要翻译： 在由可通过聚合物 - 类似反应改性的共聚物（A）和一种或多种胺（B）形成的聚合物铵盐中，共聚物（A）可通过（a1）的单体混合物共聚获得， 乙烯，（a2）丙烯酸和/或甲基丙烯酸，和（a3）选自乙烯基酯，乙烯基醚，丙烯酸酯，甲基丙烯酸酯，丙烯酰胺和甲基丙烯酰胺和胺（B）的一种或多种其它单体 从由通式I的（b1）环胺和/或由通式II II的（b2）开链胺和/或由 由（b3）1,4-噻嗪，N，N'，N“ - 三乙烯基三聚氰胺和N，N'，N” - 三烯丙基三聚氰胺组成的组，Z，R 1，R 2和R 3具有说明书中所述的含义。

    Photosensitive recording element
    10.
    发明授权
    Photosensitive recording element 失效
    感光记录元素

    公开(公告)号：US5112723A

    公开(公告)日：1992-05-12

    申请号：US476939

    申请日：1990-02-08

    申请人： Wolfgang Huemmer ,  Walter Dobler ,  Dieter Littmann

    发明人： Wolfgang Huemmer ,  Walter Dobler ,  Dieter Littmann

    IPC分类号： G03F7/004 ,  G03F7/027 ,  G03F7/031 ,  G03F7/032

    CPC分类号： G03F7/027 ,  G03F7/032

    摘要： In a photosensitive recording element which contains at least one photopolymerizable recording layer (B) consisting ofb.sub.1) at least one partially of virtually completely hydrolyzed poly(vinyl alkanecarboxylate) and/or at least one partially or virtually completely hydrolyzed vinyl alkanecarboxylate/alkylene oxide graft copolymer as a binder,b.sub.2) at least one photopolymerization initiator,b.sub.3) at least one photopolymerizable olefinically unsaturated compound (monomer) which is compatible with the binder (b.sub.1), and/or photopolymerizable olefinically unsaturated radicals which are bonded as side radicals and/or terminal radicals to the binder (b.sub.1), andb.sub.4) at least two assistants, at least one of the said assistants (b.sub.4) has been selected from the group consisting ofb.sub.41) the isoalloxazines and the alloxazines, and at least one of the other assistants has been selected from the group consisting ofb.sub.42) the potassium salt of N-nitrosocyclohexylhydroxlamine, N-nitrosodiphenylamine and hydroquinone monomethyl ether,the amounts used of the assistants (b.sub.41) and (b.sub.42) being from 0.01 to 6% by weight, based on the total weight of the photopolymerizable recording layer (B), and the weight ratio (b.sub.41) : B.sub.42) being from 1:2 to 1:1,000.

    摘要翻译： 在含有至少一种可光聚合记录层（B）的光敏记录元件中，所述光致聚合记录层（B）由b1）至少部分实质上完全水解的聚（乙烯基链烷羧酸酯）和/或至少一种部分或几乎完全水解的乙烯基烷羧酸酯/烯化氧接枝 共聚物作为粘合剂，b2）至少一种光聚合引发剂，b3）与粘合剂（b1）相容的至少一种可光聚合的烯属不饱和化合物（单体）和/或可光聚合的烯属不饱和基团作为侧基键合和/ 或末端基团，和b4）至少两种助剂，所述助剂（b4）中的至少一种选自b41）异卤代氮杂和氧氟烷，并且至少一种 其他助剂选自b42）N-亚硝基环己基羟胺的钾盐，N-亚硝基二苯胺和水解剂 （b41）和（b42）的助剂（b41）和（b42）所用的量为0.01-6重量％，基于可光聚合记录层（B）的总重量和重量比（b41）：B42） 从1：2到1：1,000。