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1.发明授权
公开(公告)号：US5176986A
公开(公告)日：1993-01-05
申请号：US356933
申请日：1989-05-25
申请人： Thomas Telser , Wolfgang Huemmer , Horst Koch , Karl-Rudolf Kurtz , Heinz-Ulrich Werther , Beinhard Schneider
发明人： Thomas Telser , Wolfgang Huemmer , Horst Koch , Karl-Rudolf Kurtz , Heinz-Ulrich Werther , Beinhard Schneider
摘要： A new liquid cleaner composition is provided for the mild and gentle removal of polymeric materials from sufaces without leaving any residues. The said new cleaner composition is an emulsion of the water-in-oil type comprising an aqueous phase finely dispersed in a continuous phase selected from the group consisting of nonflammable, fire-retardant, high-boiling, and fire-retardant and high-boiling organic phases, the volume ratio of the finely dispersed aqueous phase to the continuous organic phase being in the range of from 90:10 to 10:90. The new liquid cleaner composition can contain alcohols, surface-active agents and further useful additives. The new liquid cleaner composition is most preferably used in the process for preparing photopolymerized flexographic relief printing plates as the developer for washing out the non-irradiated and thus non-photopolymerized areas of the imagewise irradiated relief-forming recording layers of the said flexographic relief printing plates.
摘要翻译： 提供了一种新的液体清洁剂组合物，用于从表面温和和温和地除去聚合材料，而不留下任何残留物。 所述新型清洁剂组合物是油包水型的乳液，其包含精细分散在连续相中的水相，所述连续相选自不可燃，阻燃，高沸点，阻燃和高沸点 有机相，细分散水相与连续有机相的体积比在90:10至10:90的范围内。 新的液体清洁剂组合物可以含有醇，表面活性剂和其它有用的添加剂。 新的液体清洗剂组合物最优选用于制备光聚合柔版印刷印版的方法，作为用于洗出所述柔性印版印刷的图像照射的浮雕形成记录层的未经照射且因此非光聚合区域的显影剂 盘子
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公开(公告)号：US5061606A
公开(公告)日：1991-10-29
申请号：US425491
申请日：1989-10-20
CPC分类号： G03F7/325
摘要： The present invention relates to an improved process for preparing a photopolymerized flexographic relief printing plate or a photoresist from a photosensitive element comprising a photopolymerizable layer consisting essentially of(A) at least one polymer as the binder,(B) at least one photopolymerizable monomer compatible with said binder (A) and(C) one photoinitiator, by(i) imagewise exposing said photopolymerizable layer of said element to actinic light and(ii) washing out the unexposed, non-photopolymerized parts of said layer with a developer, thereby obtaining a photopolymerized flexographic relief printing plate or a photoresist.The improvement of said process comprises: washing out the non-photopolymerized parts of the irradiated photopolymerizable layer with the developer which consists essentially of at least one hydrogenated petroleum fraction having a flashpoint above 45.degree. C. and a boiling range of from 160.degree. to 220.degree. C., 0 to 2% by weight, based on the developer, of at least one surface active compound and 0 to 10% by weight, based on the developer, of a monoterpene. In a preferred embodiment the improved process makes use of a developer which contains, in addition to the abovementioned components, 5 to 20 vol. %, based on the developer, of an alcohol selected from the group consisting of alcohols with 4 to 8 carbon atoms.
摘要翻译： 本发明涉及一种由感光元件制备光聚合柔版印刷印版或光致抗蚀剂的改进方法，该光敏元件包括基本上由（A）至少一种聚合物作为粘合剂组成的可光聚合层，（B）至少一种可光聚合单体相容性 所述粘合剂（A）和（C）一种光引发剂，通过（i）将所述元件的所述可光聚合层成像曝光于光化光，和（ii）用显影剂洗涤所述层的未曝光的非光聚合部分，从而获得 光聚合柔版印刷版或光致抗蚀剂。 所述方法的改进包括：用显影剂洗涤照射的可光聚合层的非光聚合部分，该显影剂基本上由至少一种闪点在45℃以上且沸点范围为160至220℃的氢化石油馏分组成 0至2重量％，基于显色剂的至少一种表面活性化合物和0至10重量％，基于显影剂，单萜。 在优选的实施方案中，改进的方法使用显影剂，除了上述组分之外，还含有5至20体积％ 基于显色剂的选自由具有4至8个碳原子的醇组成的组的醇。
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3.发明授权Photosensitive recording element having a recording layer and a top layer possessing different solubility properties, and its development in one operation 失效具有记录层和具有不同溶解度特性的顶层的感光记录元件及其在一次操作中的发展
公开(公告)号：US6040116A
公开(公告)日：2000-03-21
申请号：US892350
申请日：1997-07-14
摘要： A novel photosensitive recording element having a dimensionally stable substrate (A), a photopolymerizable relief-forming recording layer (B), which may consist of two or more individual layers (B), and an optically transparent top layer (C) firmly adhering to the surface of (B) is used for the production of a flexographic relief printing plate. Imagewise exposure of the photopolymerizable relief-forming recording layer (B) of the novel photosensitive recording element to actinic light results in a difference between the solubilities of its exposed and unexposed parts, so that its unexposed parts can be washed out (developed) with a solvent. On the other hand, the optically transparent top layer (C) of the novel photosensitive recording element is insoluble or nonswellable in the relevant solvent. The imagewise exposed novel photosensitive recording element can nevertheless be developed in one operation with the aid of an emulsion of the water-in-oil or oil-in-water type. These emulsions are also suitable for developing imagewise exposed photosensitive recording elements whose photopolymerizable relief-forming recording layer (B) consist of two or more individual layers (B) having different solubility properties. In this case too, development is effected in one operation.
摘要翻译： 具有尺寸稳定的基板（A），可由两个以上的单层（B）构成的光聚合性凸版形成记录层（B）和光学透明的顶层（C）的新颖的光敏记录元件， （B）的表面用于生产柔版印刷印版。 新型感光记录元件的光致聚合缓冲形成记录层（B）的图像曝光与光化光导致其曝光部分和未曝光部分的溶解度之间的差异，使得其未曝光部分可以用 溶剂。 另一方面，新型光敏记录元件的光学透明顶层（C）在相关溶剂中是不溶的或不可溶的。 借助于油包水型或水包油型的乳液，可以在一次操作中开发成像曝光的新型光敏记录元件。 这些乳剂也适用于显影成像曝光的感光记录元件，其光聚合缓冲形成记录层（B）由具有不同溶解性的两个或多个单层（B）组成。 在这种情况下，开发也是在一个操作中实现的。
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公开(公告)号：US5035981A
公开(公告)日：1991-07-30
申请号：US475802
申请日：1990-02-06
申请人： Karl-Rudolf Kurtz , Horst Koch , Thomas Telser , Helmut Bach
发明人： Karl-Rudolf Kurtz , Horst Koch , Thomas Telser , Helmut Bach
CPC分类号： G03F7/092 , Y10S430/162
摘要： In a process for preparing a photopolymer printing plate, relief plate or photoresist from a photosensitive recording element containingA) a photopolymerizable relief-forming layer which can be developed with liquid developer after imagewise exposure to actinic light,B) a top layer which consists of polymers forming films of high tensile strength, adheres firmly to the photopolymerizable relief-forming layer (A) and is soluble or swellable in the liquid developers andC) a cover sheet which can readily be peeled off from the top layer (B), comprising peeling off the cover sheet (C) from the top layer (B), imagewise exposing to actinic light and developing the relief-forming layer (A), the formation of an electrostatic charge on top of the photosensitive recording element being prevented by incorporating into the element a top layer (B) containing specific tertiary amines and/or amides and/or specific quaternary ammonium salts.
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5.发明授权Optically transparent polymer alloy and its use in molding materials, moldings, films, coatings, adhesives and photosensitive recording elements 失效光学透明聚合物合金及其在模塑材料，模具，薄膜，涂料，粘合剂和感光记录元素中的应用
公开(公告)号：US5147757A
公开(公告)日：1992-09-15
申请号：US759979
申请日：1991-09-17
申请人： Karl-Rudolf Kurtz , Horst Koch , Thomas Telser
发明人： Karl-Rudolf Kurtz , Horst Koch , Thomas Telser
IPC分类号： G02B1/04 , C08F2/44 , C08F2/50 , C08L23/08 , C08L23/16 , C08L33/02 , C09D123/02 , C09D123/16 , C09J123/16
摘要： A novel optically transparent polymer alloy comprisesA) at least one elastomer which contains ethylene and propylene as copolymerized units andB) at least one elastomer which contains ethylene and (meth)acrylic acid as copolymerized units,and is used as a molding material or for the production of molding materials, moldings, films, coatings, adhesives and photosensitive recording elements.
摘要翻译： 一种新颖的光学透明聚合物合金包括A）至少一种含有乙烯和丙烯作为共聚单元的弹性体，以及B）至少一种含有乙烯和（甲基）丙烯酸作为共聚单元的弹性体，并且用作模塑材料或用作 成型材料，模制品，薄膜，涂料，粘合剂和感光记录元件的生产。
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公开(公告)号：US4946758A
公开(公告)日：1990-08-07
申请号：US264893
申请日：1988-10-31
申请人： Karl-Rudolf Kurtz , Horst Koch , Thomas Telser , Helmut Bach
发明人： Karl-Rudolf Kurtz , Horst Koch , Thomas Telser , Helmut Bach
CPC分类号： G03F7/092 , Y10S430/162
摘要： In a photosensitive recording material comprising(A) a photopolymerizable relief-forming layer which can be developed with liquid developer after imagewise exposure to actinic light,(B) a top layer which consists of polymers forming films of high tensile strength, adheres firmly to the photopolymerizable relief-forming layer (A) and is soluble or swellable in the liquid developers and(C) a cover sheet which can readily be peeled off from the top layer (B),the top layer (B) contains specific tertiary amines and/or amides and/or specific quaternary ammonium salts of the type defined in more detail in the claims.Photopolymerized printing plates, relief plates or photoresists are produced by a process in which this recording material is used.
摘要翻译： 在光敏记录材料中，包括（A）在成像曝光于光化光后可与液体显影剂一起显影的可光聚合的凸版形成层，（B）由形成具有高拉伸强度的薄膜的聚合物构成的顶层， 光聚合性浮雕形成层（A），并且在液体显影剂中可溶或溶胀，（C）可以容易地从顶层（B）剥离的覆盖片，顶层（B）含有特定的叔胺和/ 或酰胺和/或特定季铵盐，其在权利要求中更详细地定义。 通过使用该记录材料的方法制造光聚合印刷版，凸版或光致抗蚀剂。
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公开(公告)号：US5049478A
公开(公告)日：1991-09-17
申请号：US412995
申请日：1989-09-26
申请人： Horst Koch , Karl-Rudolf Kurtz , Thomas Telser , Manfred Zuerger
发明人： Horst Koch , Karl-Rudolf Kurtz , Thomas Telser , Manfred Zuerger
CPC分类号： G03F7/16 , Y10S430/11 , Y10S430/111
摘要： A novel, improved continuous process for the production of a photosensitive recording element is described, whose photopolymerizable recording layer (A) consists of two or more individual strata (a.sub.n) lying one on top of the other and firmly bonded to one another. The individual strata (a.sub.n) may be of the same or roughly the same composition or of different compositions. In the novel, improved continuous process, the mixtures (a.sub.n) used for the production of the individual strate (a.sub.n) are prepared separately from one another and melted and, as separate molten material streams (a.sub.n), are combined even before entering the nip of a calender, without the said streams mixing as a result of turbulence. During, before or directly after they have been combined, the molten material streams (a.sub.n) are formed into molten sheet-like structures (a.sub.n) lying one on top of the other, without the said streams mixing as a result of turbulence. Thereafter, the molten sheet-like structures (a.sub.n) lying one on top of the other are introduced into the calender nip, one or both of the two outer molten sheet-like structures (a.sub.n) in contact with the calender rollers forming a rotating melt bead or rotating bank. In the calender nip itself, the said sheet-like structures (a.sub.n) are then calendered with production of the photopolymerizable recording layer (A) consisting of individual strata (a.sub.n) lying one on top of the other and firmly bonded to one another.
摘要翻译： 描述了用于制备感光记录元件的新型改进的连续方法，其光聚合记录层（A）由两个或更多个单独层叠在一起而彼此牢固地结合的单个层（a）组成。 单个层（a）可以具有相同或大致相同的组成或不同组成。 在该小说中，改进的连续过程中，用于生产单个台阶（a）的混合物（a）彼此分开制备并熔化，并且作为单独的熔融材料流（an）甚至在进入辊隙之前组合 的砑光机，由于湍流，没有所述的流混合。 在组合之前或之后，熔融材料流（a）形成为位于另一个之上的熔融片状结构（a），而不会由于湍流而混合所述流。 此后，将一个位于另一个顶部的熔融片状结构（a）引入砑光辊隙中，两个外熔融片状结构（a）中的一个或两个与砑光辊接触，形成旋转熔体 珠或旋转银行。 在砑光辊隙本身中，随后生产由彼此顶部彼此牢固结合的单个层（a）组成的可光聚合记录层（A），然后压制所述片状结构（a）。
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公开(公告)号：US4994344A
公开(公告)日：1991-02-19
申请号：US306547
申请日：1989-02-03
申请人： Karl-Rudolf Kurtz , Horst Koch , Thomas Telser , Manfred Zuerger
发明人： Karl-Rudolf Kurtz , Horst Koch , Thomas Telser , Manfred Zuerger
CPC分类号： G03F7/027
摘要： A light-sensitive recording element useful for preparing photopolymer flexographic relief printing plates, comprising at least one photopolymerizable recording layer having a thickness of from 0.1 to 7 mm and made up of:from 20 to 99.499% by weight of at least one polymeric binder which may be random ethylene-propylene-alkadiene terpolymers having an ethylene content of from 40 to 80% by weight and a double bond content of from 2 to 20 olefinic double bonds per 1,000 carbon atoms;from 0.001 to 10% by weight of at least one photopolymerization initiator,from 0.5 to 50% by weight of at least one monomer which is compatible with the binder and has at least one photopolymerizable olefinic double bond, andfrom 0.001 to 2% by weight of at least one inhibitor of thermally initiated polymerization and from 0.0001 to 5% by weight of at least one antioxidant as assistants.
摘要翻译： 用于制备感光聚合物柔版印刷版的感光记录元件，其包含至少一种厚度为0.1至7毫米的可光聚合记录层，由以下组成的至少一种聚合物粘合剂为20至99.499重量％ 可以是乙烯含量为40至80重量％且每1,000个碳原子具有2至20个烯属双键的双键含量的无规乙烯 - 丙烯 - 链烯二烯三元共聚物; 0.001至10重量％的至少一种光聚合引发剂，0.5至50重量％的至少一种与粘合剂相容并具有至少一个可光聚合的烯属双键的单体和0.001至2重量％ 的至少一种热引发聚合抑制剂和0.0001-5重量％的至少一种抗氧化剂作助剂。
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9.发明授权Preparation of recording layers and their use for the production of flexographic printing plates 失效记录层的制备及其用于生产柔版印刷版的用途
公开(公告)号：US4940650A
公开(公告)日：1990-07-10
申请号：US331392
申请日：1989-03-31
申请人： Karl-Rudolf Kurtz , Horst Koch , Guenther Schulz
发明人： Karl-Rudolf Kurtz , Horst Koch , Guenther Schulz
IPC分类号： C08F291/02 , C08F291/00 , C08K5/00 , C08K5/01 , C08L21/00 , G03F7/00 , G03F7/004 , G03F7/027
CPC分类号： G03F7/027 , Y10S430/108
摘要： A flexographic printing plate which is resistant to ozone cracking and where the flexible recording layer has an anisotropy factor AF of
摘要翻译： 柔性版印刷版耐臭氧裂纹，柔性记录层的各向异性因子AF小于1.5，由（A）一种或多种弹性粘合剂组成的感光性混合物，（B）（B1） 5至20重量％的一种或多种与（A）相容并含有两个或多个烯属双键的可光聚合有机化合物和（B2）1至15重量％的一种或多种单烯属不饱和有机化合物，它们是 与（A）相容，其均聚物的玻璃化转变温度低于室温，（C）0.1至10重量％的一种或多种光引发剂和（D）0至27重量％的常规助剂和添加剂 ，柔性记录层的各向异性因子AF被定义为在制造过程中从柔性记录层冲裁的2×15cm的条带的100％伸长率的弹性模量的比率 原料板一方面沿着所使用的感光性混合物的流动方向，另一方面与所述方向交叉，然后均匀地曝光。
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10.发明授权
公开(公告)号：US5112725A
公开(公告)日：1992-05-12
申请号：US668337
申请日：1991-03-14
申请人： Karl-Rudolf Kurtz , Horst Koch , Guenther Schulz
发明人： Karl-Rudolf Kurtz , Horst Koch , Guenther Schulz
IPC分类号： C08F291/02 , C08F291/00 , C08K5/00 , C08K5/01 , C08L21/00 , G03F7/00 , G03F7/004 , G03F7/027
CPC分类号： G03F7/027 , Y10S430/108
摘要： A flexographic printing plate which is resistant to ozone cracking and where the flexible recording layer has an anisotropy factor AF of
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