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1.发明申请MULTI-COMPONENT CATALYST SYSTEMS AND POLYMERIZATION PROCESSES FOR FORMING IN-SITU HETEROPHASIC COPOLYMERS AND/OR VARYING THE XYLENE SOLUBLES CONTENT OF POLYOLEFINS 有权多组分催化剂体系和形成异源共聚物的聚合方法和/或改变聚烯烃的二甲苯溶液含量公开(公告)号：US20110269923A1
公开(公告)日：2011-11-03
申请号：US13180672
申请日：2011-07-12
申请人： Tim J. Coffy , Michel Daumerie , Kenneth P. Blackmon , William Gauthier , Jun Tian , Joseph Thorman
发明人： Tim J. Coffy , Michel Daumerie , Kenneth P. Blackmon , William Gauthier , Jun Tian , Joseph Thorman
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F210/06 , Y10S526/943 , C08F4/65904 , C08F210/16 , C08F2500/12 , C08F2500/05
摘要： Embodiments of the invention generally include multi-component catalyst systems, polymerization processes and heterophasic copolymers formed by the processes. The multi-component catalyst system generally includes a first catalyst component selected from Ziegler-Natta catalyst systems including a diether internal electron donor and a metallocene catalyst represented by the general formula XCpACpBMAn, wherein X is a structural bridge, CpA and CpB each denote a cyclopentadienyl group or derivatives thereof, each being the same or different and which may be either substituted or unsubstituted, M is a transition metal and A is an alkyl, hydrocarbyl or halogen group and n is an integer between 0 and 4. The multi-component catalyst system further includes a second catalyst component generally represented by the formula XCpACpBMAn, wherein X is a structural bridge, CpA and CpB each denote a cyclopentadienyl group or derivatives thereof, each being the same or different and which may be either substituted or unsubstituted, M is a transition metal and A is an alkyl, hydrocarbyl or halogen group and n is an integer between 0 and 4 and wherein the second catalyst component exhibits a higher ethylene response than the first catalyst component.
摘要翻译： 本发明的实施方案通常包括通过该方法形成的多组分催化剂体系，聚合方法和多相共聚物。 多组分催化剂体系通常包括选自齐格勒 - 纳塔催化剂体系的第一催化剂组分，其包括二醚内电子给体和由通式XCpACpBMAn表示的茂金属催化剂，其中X是结构桥，CpA和CpB各自表示环戊二烯基 基团或其衍生物，各自相同或不同，并且可以是取代或未取代的，M是过渡金属，A是烷基，烃基或卤素基团，n是0和4之间的整数。多组分催化剂 系统还包括通常由式XCpACpBMAn表示的第二催化剂组分，其中X是结构桥，CpA和CpB各自表示环戊二烯基或其衍生物，各自相同或不同，并且可以是取代或未取代的，M是 过渡金属，A是烷基，烃基或卤素基团，n是0至4之间的整数， nd催化剂组分表现出比第一催化剂组分更高的乙烯响应。
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2.发明申请Multi-component catalyst systems and polymerization processes for forming in-situ heterophasic copolymers and/or varying the xylene solubles content of polyolefins 有权用于形成原位多相共聚物和/或改变二甲苯可溶物的多组分催化剂体系和聚合方法聚烯烃含量公开(公告)号：US20090105433A1
公开(公告)日：2009-04-23
申请号：US11975014
申请日：2007-10-17
申请人： Tim J. Coffy , Michel Daumerie , Kenneth P. Blackmon , William Gauthier , Jun Tian , Joseph Thorman
发明人： Tim J. Coffy , Michel Daumerie , Kenneth P. Blackmon , William Gauthier , Jun Tian , Joseph Thorman
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F210/06 , Y10S526/943 , C08F4/65904 , C08F210/16 , C08F2500/12 , C08F2500/05
摘要： Embodiments of the invention generally include multi-component catalyst systems, polymerization processes and heterophasic copolymers formed by the processes. The multi-component catalyst system generally includes a first catalyst component selected from Ziegler-Natta catalyst systems including a diether internal electron donor and a metallocene catalyst represented by the general formula XCpACpBMAn, wherein X is a structural bridge, CpA and CpB each denote a cyclopentadienyl group or derivatives thereof, each being the same or different and which may be either substituted or unsubstituted, M is a transition metal and A is an alkyl, hydrocarbyl or halogen group and n is an integer between 0 and 4. The multi-component catalyst system further includes a second catalyst component generally represented by the formula XCpACpBMAn, wherein X is a structural bridge, CpA and CpB each denote a cyclopentadienyl group or derivatives thereof, each being the same or different and which may be either substituted or unsubstituted, M is a transition metal and A is an alkyl, hydrocarbyl or halogen group and n is an integer between 0 and 4 and wherein the second catalyst component exhibits a higher ethylene response than the first catalyst component.
摘要翻译： 本发明的实施方案通常包括通过该方法形成的多组分催化剂体系，聚合方法和多相共聚物。 多组分催化剂体系通常包括选自齐格勒 - 纳塔催化剂体系的第一催化剂组分，其包括二醚内电子给体和由通式XCpACpBMAn表示的茂金属催化剂，其中X是结构桥，CpA和CpB各自表示环戊二烯基 基团或其衍生物，各自相同或不同，并且可以是取代或未取代的，M是过渡金属，A是烷基，烃基或卤素基团，n是0和4之间的整数。多组分催化剂 系统还包括通常由式XCpACpBMAn表示的第二催化剂组分，其中X是结构桥，CpA和CpB各自表示环戊二烯基或其衍生物，各自相同或不同，并且可以是取代或未取代的，M是 过渡金属，A是烷基，烃基或卤素基团，n是0至4之间的整数， nd催化剂组分表现出比第一催化剂组分更高的乙烯响应。
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3.发明申请MULTI-COMPONENT CATALYST SYSTEMS AND POLYMERIZATION PROCESSES FOR FORMING IN-SITU HETEROPHASIC COPOLYMERS AND/OR VARYING THE XYLENE SOLUBLES CONTENT OF POLYOLEFINS 有权多组分催化剂体系和形成异源共聚物的聚合方法和/或改变聚烯烃的二甲苯溶液含量公开(公告)号：US20130102743A9
公开(公告)日：2013-04-25
申请号：US13180672
申请日：2011-07-12
申请人： Tim J. Coffy , Michel Daumerie , Kenneth P. Blackmon , William Gauthier , Jun Tian , Joseph Thorman
发明人： Tim J. Coffy , Michel Daumerie , Kenneth P. Blackmon , William Gauthier , Jun Tian , Joseph Thorman
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F210/06 , Y10S526/943 , C08F4/65904 , C08F210/16 , C08F2500/12 , C08F2500/05
摘要： Embodiments of the invention generally include multi-component catalyst systems, polymerization processes and heterophasic copolymers formed by the processes. The multi-component catalyst system generally includes a first catalyst component selected from Ziegler-Natta catalyst systems including a diether internal electron donor and a metallocene catalyst represented by the general formula XCpACpBMAn, wherein X is a structural bridge, CpA and CpB each denote a cyclopentadienyl group or derivatives thereof, each being the same or different and which may be either substituted or unsubstituted, M is a transition metal and A is an alkyl, hydrocarbyl or halogen group and n is an integer between 0 and 4. The multi-component catalyst system further includes a second catalyst component generally represented by the formula XCpACpBMAn, wherein X is a structural bridge, CpA and CpB each denote a cyclopentadienyl group or derivatives thereof, each being the same or different and which may be either substituted or unsubstituted, M is a transition metal and A is an alkyl, hydrocarbyl or halogen group and n is an integer between 0 and 4 and wherein the second catalyst component exhibits a higher ethylene response than the first catalyst component.
摘要翻译： 本发明的实施方案通常包括通过该方法形成的多组分催化剂体系，聚合方法和异相共聚物。 多组分催化剂体系通常包括选自齐格勒 - 纳塔催化剂体系的第一催化剂组分，其包括二醚内电子给体和由通式XCpACpBMAn表示的茂金属催化剂，其中X是结构桥，CpA和CpB各自表示环戊二烯基 基团或其衍生物，各自相同或不同，并且可以是取代或未取代的，M是过渡金属，A是烷基，烃基或卤素基团，n是0和4之间的整数。多组分催化剂 系统还包括通常由式XCpACpBMAn表示的第二催化剂组分，其中X是结构桥，CpA和CpB各自表示环戊二烯基或其衍生物，各自相同或不同，并且可以是取代或未取代的，M是 过渡金属，A是烷基，烃基或卤素基团，n是0至4之间的整数， nd催化剂组分表现出比第一催化剂组分更高的乙烯响应。
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4.发明授权Multi-component catalyst systems and polymerization processes for forming in-situ heterophasic copolymers and/or varying the xylene solubles content of polyolefins 有权用于形成原位多相共聚物和/或改变二甲苯可溶物的多组分催化剂体系和聚合方法聚烯烃含量公开(公告)号：US08003739B2
公开(公告)日：2011-08-23
申请号：US11975014
申请日：2007-10-17
申请人： Tim J. Coffy , Michel Daumerie , Kenneth P. Blackmon , William J. Gauthier , Jun Tian , Joseph L. Thorman
发明人： Tim J. Coffy , Michel Daumerie , Kenneth P. Blackmon , William J. Gauthier , Jun Tian , Joseph L. Thorman
IPC分类号： C08F4/653 , C08F4/6592 , C08F210/02 , C08F210/06 , B01J31/22
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F210/06 , Y10S526/943 , C08F4/65904 , C08F210/16 , C08F2500/12 , C08F2500/05
摘要： Embodiments of the invention generally include multi-component catalyst systems, polymerization processes and heterophasic copolymers formed by the processes. The multi-component catalyst system generally includes a first catalyst component selected from Ziegler-Natta catalyst systems including a diether internal electron donor and a metallocene catalyst represented by the general formula XCpACpBMAn, wherein X is a structural bridge, CpA and CpB each denote a cyclopentadienyl group or derivatives thereof, each being the same or different and which may be either substituted or unsubstituted, M is a transition metal and A is an alkyl, hydrocarbyl or halogen group and n is an integer between 0 and 4. The multi-component catalyst system further includes a second catalyst component generally represented by the formula XCpACpBMAn, wherein X is a structural bridge, CpA and CpB each denote a cyclopentadienyl group or derivatives thereof, each being the same or different and which may be either substituted or unsubstituted, M is a transition metal and A is an alkyl, hydrocarbyl or halogen group and n is an integer between 0 and 4 and wherein the second catalyst component exhibits a higher ethylene response than the first catalyst component.
摘要翻译： 本发明的实施方案通常包括通过该方法形成的多组分催化剂体系，聚合方法和多相共聚物。 多组分催化剂体系通常包括选自齐格勒 - 纳塔催化剂体系的第一催化剂组分，其包括二醚内电子给体和由通式XCpACpBMAn表示的茂金属催化剂，其中X是结构桥，CpA和CpB各自表示环戊二烯基 基团或其衍生物，各自相同或不同，并且可以是取代或未取代的，M是过渡金属，A是烷基，烃基或卤素基团，n是0和4之间的整数。多组分催化剂 系统还包括通常由式XCpACpBMAn表示的第二催化剂组分，其中X是结构桥，CpA和CpB各自表示环戊二烯基或其衍生物，各自相同或不同，并且可以是取代或未取代的，M是 过渡金属，A是烷基，烃基或卤素基团，n是0至4之间的整数， nd催化剂组分表现出比第一催化剂组分更高的乙烯响应。
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公开(公告)号：US09260541B2
公开(公告)日：2016-02-16
申请号：US12782810
申请日：2010-05-19
IPC分类号： C08F2/00 , C08F4/52 , C08F110/06 , C08F10/00 , C08F210/06
CPC分类号： C08F210/06 , C08F10/00 , C08F210/16 , C08F2500/18 , C08F2500/12 , C08F4/642 , C08F4/6465
摘要： A method comprising preparing a multi-component catalyst system comprising a catalyst and a cocatalyst, and adjusting the level of at least one component of the catalyst system to maintain a user-desired level of catalyst activity throughout a process, wherein the component comprises a catalyst activator and wherein the catalyst activator comprises the catalyst or the cocatalyst. A method comprising contacting a polymerization catalyst system comprising a Ziegler-Natta catalyst and a cocatalyst with a catalyst activator at least twice during a polymerization process, wherein the polymerization process is carried out in a reactor system comprising multiple reactor types.
摘要翻译： 一种方法，包括制备包含催化剂和助催化剂的多组分催化剂体系，并调节催化剂体系的至少一种组分的水平以在整个方法中保持用户期望的催化剂活性水平，其中组分包含催化剂 活化剂，其中催化剂活化剂包括催化剂或助催化剂。 一种方法，其包括使聚合催化剂体系包含齐格勒 - 纳塔催化剂和助催化剂与催化剂活化剂在聚合过程中至少两次，其中聚合方法在包括多种反应器类型的反应器系统中进行。
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公开(公告)号：US20100227986A1
公开(公告)日：2010-09-09
申请号：US12782810
申请日：2010-05-19
IPC分类号： C08F2/01
CPC分类号： C08F210/06 , C08F10/00 , C08F210/16 , C08F2500/18 , C08F2500/12 , C08F4/642 , C08F4/6465
摘要： A method comprising preparing a multi-component catalyst system comprising a catalyst and a cocatalyst, and adjusting the level of at least one component of the catalyst system to maintain a user-desired level of catalyst activity throughout a process, wherein the component comprises a catalyst activator and wherein the catalyst activator comprises the catalyst or the cocatalyst. A method comprising contacting a polymerization catalyst system comprising a Ziegler-Natta catalyst and a cocatalyst with a catalyst activator at least twice during a polymerization process, wherein the polymerization process is carried out in a reactor system comprising multiple reactor types.
摘要翻译： 一种方法，包括制备包含催化剂和助催化剂的多组分催化剂体系，并调节催化剂体系的至少一种组分的水平以在整个方法中保持用户期望的催化剂活性水平，其中组分包含催化剂 活化剂，其中催化剂活化剂包括催化剂或助催化剂。 一种方法，其包括使聚合催化剂体系包含齐格勒 - 纳塔催化剂和助催化剂与催化剂活化剂在聚合过程中至少两次，其中聚合方法在包括多种反应器类型的反应器系统中进行。
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公开(公告)号：US20100125124A1
公开(公告)日：2010-05-20
申请号：US12272113
申请日：2008-11-17
CPC分类号： C08F210/06 , C08F10/00 , C08F210/16 , C08F2500/18 , C08F2500/12 , C08F4/642 , C08F4/6465
摘要： A method comprising preparing a multi-component catalyst system comprising a catalyst and a cocatalyst, and adjusting the level of at least one component of the catalyst system to maintain a user-desired level of catalyst activity throughout a process, wherein the component comprises a catalyst activator and wherein the catalyst activator comprises the catalyst or the cocatalyst. A method comprising contacting a polymerization catalyst system comprising a Ziegler-Natta catalyst and a cocatalyst with a catalyst activator at least twice during a polymerization process, wherein the polymerization process is carried out in a reactor system comprising multiple reactor types.
摘要翻译： 一种方法，包括制备包含催化剂和助催化剂的多组分催化剂体系，并调节催化剂体系的至少一种组分的水平以在整个方法中保持用户期望的催化剂活性水平，其中组分包含催化剂 活化剂，其中催化剂活化剂包括催化剂或助催化剂。 一种方法，其包括使聚合催化剂体系包含齐格勒 - 纳塔催化剂和助催化剂与催化剂活化剂在聚合过程中至少两次，其中聚合方法在包括多种反应器类型的反应器系统中进行。
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公开(公告)号：US07902325B2
公开(公告)日：2011-03-08
申请号：US11473358
申请日：2006-06-22
IPC分类号： C08F6/02 , C08F110/06
CPC分类号： C08F110/06 , C08F6/02 , C08L23/10 , C08F2500/12 , C08L23/14
摘要： Polymerization processes are described herein. The polymerization processes generally include introducing a catalyst system to a reaction zone, introducing an olefin monomer to the reaction zone, contacting the olefin monomer with the catalyst system to form a polyolefin and contacting the polyolefin with a quench agent, wherein the quench agent is at least partially soluble in the olefin monomer.
摘要翻译： 本文描述了聚合方法。 聚合方法通常包括将催化剂体系引入反应区，将烯烃单体引入反应区，使烯烃单体与催化剂体系接触以形成聚烯烃并使聚烯烃与骤冷剂接触，其中骤冷剂处于 最少部分溶于烯烃单体。
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9.发明授权Color minimization during melt preparation of polyamides with hypophosphorus acid 失效用低磷酸熔融制备聚酰胺时的颜色最小化
公开(公告)号：US4983718A
公开(公告)日：1991-01-08
申请号：US364360
申请日：1989-06-09
CPC分类号： C08G69/28
摘要： A process for minimizing the formation of color during preparation of polyamides by interchange of diesters of dicarboxylic acids with diamines in the presence of hypophosphorous acid.
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10.发明申请NOVEL COMBINATIONS OF SILANE ELECTRON DONORS FOR USE IN CATALYST COMPOSITIONS 审中-公开用于催化剂组合物的硅烷电子助剂的新组合公开(公告)号：US20120123068A1
公开(公告)日：2012-05-17
申请号：US11846676
申请日：2007-08-29
IPC分类号： C08F4/76
CPC分类号： C08F10/00 , C08F110/06 , C08F4/6465 , C08F2500/18 , C08F2500/12 , C08F2500/04
摘要： Disclosed is a process for preparing an olefinic polymer comprising contacting at least one olefinic C3+ monomer and a catalyst composition comprising a Ziegler-Natta catalyst, dicyclopentyl dimethoxysilane as a first electron donor, and a second electron donor selected from the group consisting of methyl trimethoxysilane, methyl triethoxysilane, dimethyl dimethoxysilane, and mixtures thereof, under reaction conditions suitable to form an olefinic polymer. The polymer prepared using this method may exhibit significantly broadened molecular weight distribution than that achieved using any of the silane compounds alone, and may also exhibit desirable melt flow characteristics and xylene solubles levels.
摘要翻译： 公开了一种制备烯烃聚合物的方法，包括使至少一种烯烃C3 +单体和包含齐格勒 - 纳塔催化剂，二环戊基二甲氧基硅烷作为第一电子给体的催化剂组合物和选自甲基三甲氧基硅烷， 甲基三乙氧基硅烷，二甲基二甲氧基硅烷及其混合物，在适于形成烯烃聚合物的反应条件下进行。 使用该方法制备的聚合物可以显示出比使用任何单独的硅烷化合物实现的分子量分布显着扩大的分子量分布，并且还可以表现出所需的熔体流动特性和二甲苯可溶物水平。
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