Method for producing linear pentenenitrile
    1.
    发明授权
    Method for producing linear pentenenitrile 有权
    线性戊烯腈的制备方法

    公开(公告)号:US08410299B2

    公开(公告)日:2013-04-02

    申请号:US13361783

    申请日:2012-01-30

    IPC分类号: C07C253/30

    摘要: A method for producing 3-pentenenitrile is provided that includes: (a) isomerizing an educt stream containing 2-methyl-3-butenenitrile on at least one dissolved or dispersed isomerization catalyst to form a stream (1), which contains the isomerization catalyst(s), 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile; (b) distilling the stream (1) to obtain a stream (2) as the overhead product, which contains 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile and a stream (3) as the bottom product, which contains the isomerization catalyst(s); (c) distilling the stream (2) to obtain a stream (4) as the overhead product, which is enriched with (Z)-2-methyl-2-butenenitrile in comparison to stream (2), and a stream (5) as the bottom product, which is enriched with 3-pentenenitrile and 2-methyl-3-butenenitrile in comparison to stream (2); (d) distilling stream (5) to obtain a stream (6) as the bottom product, which contains 3-pentenenitrile and a stream (7) as the head product containing 2-methyl-3-butenenitrile.

    摘要翻译: 提供了一种制备3-戊烯腈的方法,其包括:(a)在至少一种溶解或分散的异构化催化剂上使含有2-甲基-3-丁烯腈的流出物异构化以形成含有异构化催化剂( s),2-甲基-3-丁烯腈,3-戊烯腈和(Z)-2-甲基-2-丁烯腈; (b)蒸馏物流(1)以获得作为塔顶产物的物流(2),其含有2-甲基-3-丁烯腈,3-戊烯腈和(Z)-2-甲基-2-丁烯腈和流( 3)作为含有异构化催化剂的底部产物; (c)与料流(2)相比,蒸馏物流(2)以获得作为塔顶产物的物流(4),其与(2)相比富含(Z)-2-甲基-2-丁烯腈, 作为与料流(2)相比富含3-戊烯腈和2-甲基-3-丁烯腈的底部产物; (d)蒸馏物流(5),得到作为底物的物流(6),其含有3-戊烯腈和作为含有2-甲基-3-丁烯腈的头部产物的物流(7)。

    METHOD FOR PRODUCING LINEAR PENTENENITRILE
    2.
    发明申请
    METHOD FOR PRODUCING LINEAR PENTENENITRILE 有权
    生产线性胆固醇的方法

    公开(公告)号:US20120178958A1

    公开(公告)日:2012-07-12

    申请号:US13361783

    申请日:2012-01-30

    IPC分类号: C07C253/30

    摘要: A method for producing 3-pentenenitrile is provided that includes: (a) isomerizing an educt stream containing 2-methyl-3-butenenitrile on at least one dissolved or dispersed isomerisation catalyst to form a stream (1), which contains the isomerisation catalyst(s), 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile; (b) distilling the stream (1) to obtain a stream (2) as the overhead product, which contains 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile and a stream (3) as the bottom product, which contains the isomerisation catalyst(s); (c) distilling the stream (2) to obtain a stream (4) as the overhead product, which is enriched with (Z)-2-methyl-2-butenenitrile in comparison to stream (2), and a stream (5) as the bottom product, which is enriched with 3-pentenenitrile and 2-methyl-3-butenenitrile in comparison to stream (2); (d) distilling stream (5) to obtain a stream (6) as the bottom product, which contains 3-pentenenitrile and a stream (7) as the head product containing 2-methyl-3-butenenitrile.

    摘要翻译: 提供了一种制备3-戊烯腈的方法,其包括:(a)在至少一种溶解或分散的异构化催化剂上异构化含有2-甲基-3-丁烯腈的流出物流以形成含有异构化催化剂( s),2-甲基-3-丁烯腈,3-戊烯腈和(Z)-2-甲基-2-丁烯腈; (b)蒸馏物流(1)以获得作为塔顶产物的物流(2),其含有2-甲基-3-丁烯腈,3-戊烯腈和(Z)-2-甲基-2-丁烯腈和流( 3)作为含有异构化催化剂的底部产物; (c)与料流(2)相比,蒸馏物流(2)以获得作为塔顶产物的物流(4),其与(2)相比富含(Z)-2-甲基-2-丁烯腈, 作为与料流(2)相比富含3-戊烯腈和2-甲基-3-丁烯腈的底部产物; (d)蒸馏物流(5),得到作为底物的物流(6),其含有3-戊烯腈和作为含有2-甲基-3-丁烯腈的头部产物的物流(7)。

    Separation of Nickel(0) Complexes and Phosphorus-Containing Ligands from Nitrile Mixtures
    3.
    发明申请
    Separation of Nickel(0) Complexes and Phosphorus-Containing Ligands from Nitrile Mixtures 审中-公开
    从腈混合物中分离镍(0)络合物和含磷配体

    公开(公告)号:US20080281119A1

    公开(公告)日:2008-11-13

    申请号:US10586493

    申请日:2005-01-27

    IPC分类号: C07C253/34

    CPC分类号: C07C253/34 C07C255/04

    摘要: A process for extractively removing nickel(0) complexes having phosphorus ligands and/or free phosphorus ligands from a reaction effluent of a hydrocyanation of unsaturated mononitriles to dinitriles by extraction by means of a hydrocarbon, a phase separation of the hydrocarbon and of the reaction effluent into two phases being effected at a temperature T (in ° C.),wherein the content of nickel(0) complexes having phosphorus ligands and/or free phosphorus ligands in the reaction effluent of the hydrocyanation, depending on the temperature T, is at least y % by weight and, irrespective of the temperature T, is a maximum of 60% by weight, where the numerical value of the minimum content y is given by the equation y=0.5·T+20 and T is to be used in the equation as a dimensionless numerical value.

    摘要翻译: 一种通过烃的提取将含有磷配体和/或游离磷配位体的镍(0)络合物从不饱和单腈的氢化氰化反应流出物萃取到二腈的方法,烃和反应流出物的相分离 在温度T(℃)下进行两相,其中根据温度T,氢氰化反应流出物中具有磷配体和/或游离磷配体的镍(0)络合物的含量在 最小含量y的数值由等式<?in-line-formula description =“在线式 “end =”lead“?> y = 0.5.T + 20 <?in-line-formula description =”In-line Formulas“end =”tail“?>而T在方程中用作无量纲数字 值。

    Method for Producing Linear Pentenenitrile
    4.
    发明申请
    Method for Producing Linear Pentenenitrile 审中-公开
    生产线性戊烯腈的方法

    公开(公告)号:US20080281120A1

    公开(公告)日:2008-11-13

    申请号:US10586470

    申请日:2005-01-27

    IPC分类号: C07C255/00

    摘要: A process is described for preparing 3-pentenenitrile, characterized by the following process steps: (a) isomerizing a reactant stream which comprises 2-methyl-3-butenenitrile over at least one dissolved or dispersed isomerization catalyst to give a stream 1 which comprises the at least one isomerization catalyst, 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile, (b) distilling stream 1 to obtain a stream 2 as the top product which comprises 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile, and a stream 3 as the bottom product which comprises the at least one isomerization catalyst, (c) distilling stream 2 to obtain a stream 4 as the top product which, compared to stream 2, is enriched in (Z)-2-methyl-2-butenenitrile, based on the sum of all pentenenitriles in stream 2, and a stream 5 as the bottom product which, compared to stream 2, is enriched in 3-pentenenitrile and 2-methyl-3-butenenitrile, based on the sum of all pentenenitriles in stream 2, (d) distilling stream 5 to obtain a stream 6 as the bottom product which comprises 3-pentenenitrile and a stream 7 as the top product which comprises 2-methyl-3-butenenitrile.

    摘要翻译: 描述了制备3-戊烯腈的方法,其特征在于以下方法步骤:(a)在至少一种溶解或分散的异构化催化剂上异构化包含2-甲基-3-丁烯腈的反应物流,得到流1,其包含 至少一种异构化催化剂,2-甲基-3-丁烯腈,3-戊烯腈和(Z)-2-甲基-2-丁烯腈,(b)蒸馏物流1,得到作为顶部产物的物流2,其包含2-甲基 -3-丁烯腈,3-戊烯腈和(Z)-2-甲基-2-丁烯腈,以及作为底部产物的料流3,其包含至少一种异构化催化剂,(c)蒸馏物流2以获得物流4, 与流2相比,基于流2中的所有五烯丙烯的总和和作为底部产物的流5,与流2相比富含(Z)-2-甲基-2-丁烯腈的顶部产物与流2相比较 ,富含3-戊烯腈和2-甲基-3-丁烯腈,基于所有pentenenit (d)蒸馏流5以获得作为底部产物的料流6,其包含3-戊烯腈和作为顶部产物的料流7,其包含2-甲基-3-丁烯腈。