公开(公告)号：US6004477A

公开(公告)日：1999-12-21

申请号：US946731

申请日：1997-10-08

申请人： Kazumoto Nakagawa ,  Tatsuo Iwai ,  Takayuki Watanabe ,  Nahomi Abe ,  Tomoharu Himeshima

发明人： Kazumoto Nakagawa ,  Tatsuo Iwai ,  Takayuki Watanabe ,  Nahomi Abe ,  Tomoharu Himeshima

IPC分类号： A23L3/3436 ,  B01J20/32 ,  C09K15/04

CPC分类号： A23L3/3436 ,  B01J20/06 ,  B01J20/165 ,  B01J20/20 ,  B01J20/2805 ,  B01J20/3204 ,  B01J20/3236 ,  B01J20/3246 ,  B01J20/3287 ,  B01J2220/42 ,  B01J2220/46

摘要： An oxygen absorption composition without requiring moisture in oxygen absorption which comprises an oxygen absorbent comprising, as a principal component, an oligomer in liquid form having an unsaturated group, a number-average molecular weight in the range of 150 to 4,000 and a viscosity in the range of 100 to 4,000 cP such as butadiene oligomer in liquid form and an oxygen absorption-accelerating substance, being supported on a carrier; and an other gas absorbent. The principal component may be replaced with an oligomer in liquid form having an unsaturated group and being incorporated with an oxygen-unabsorptive diluent to adjust the viscosity of the mixture to 10 to 4,000 cP. The composition is enhanced in oxygen absorption capability in every preservation atmosphere from a low humidity to an intermediate and high humidity, easily producible, minimized in gas generation after oxygen absorption and almost free from odor.

摘要翻译： 一种氧吸收组合物，其不需要氧吸收水分，其包含氧吸收剂，其包含作为主要组分的具有不饱和基团的液体形式的低聚物，数均分子量在150至4,000范围内， 范围为100〜4000cP，例如液体形式的丁二烯低聚物和氧吸收促进物质，负载在载体上; 和另一种气体吸收剂。 主要组分可以用具有不饱和基团的液体形式的低聚物代替，并且与不含氧的吸收性稀释剂混合以将混合物的粘度调节至10至4,000cP。 该组合物在从低湿度到中等和高湿度的每个保存气氛中的氧吸收能力增强，易于生产，在吸氧之后的气体产生中几乎没有气味。

公开(公告)号：US6039892A

公开(公告)日：2000-03-21

申请号：US246844

申请日：1999-02-09

申请人： Tomoharu Himeshima ,  Kazumoto Nakagawa ,  Tatsuo Iwai ,  Takayuki Watanabe

发明人： Tomoharu Himeshima ,  Kazumoto Nakagawa ,  Tatsuo Iwai ,  Takayuki Watanabe

IPC分类号： C09K15/04 ,  C09K15/06 ,  C09K15/12 ,  C09K15/18 ,  B01J19/00 ,  C09K15/26

CPC分类号： C09K15/04

摘要： There is disclosed herein an oxygen absorbent composition comprising an organic oxygen absorbent (A) which neither absorbs nor releases moisture and in which an oxidizable main component is supported on a porous silicate having an average pore diameter of 200 to 5,000 .ANG., and a formaldehyde absorbent (B) which neither absorbs nor releases moisture and is at least one of an amine, a thiol and a sulfonic acid that is supported on a porous carrier. According to this invention cultural assets made of organic materials which are required to be kept in a medial humidity atmosphere can be preserved in an atmosphere of a medial humidity, a low oxygen concentration and a low formaldehyde concentration by the use of the disclosed oxygen absorbent composition.

摘要翻译： 本文公开了一种氧吸收剂组合物，其包含既不吸收也不释放水分的有机氧吸收剂（A），其中可氧化的主要成分负载在平均孔径为200至5,000的多孔硅酸盐和甲醛吸收剂 （B），其既不吸收也不释放水分，并且是负载在多孔载体上的胺，硫醇和磺酸中的至少一种。 根据本发明，通过使用所公开的氧吸收剂组合物，可以将需要保持在中间湿度气氛中的由有机材料制成的文化遗产保存在中间湿度，低氧浓度和低甲醛浓度的气氛中 。

公开(公告)号：US06960640B2

公开(公告)日：2005-11-01

申请号：US10416344

申请日：2002-08-27

申请人： Yuichi Yoshimura ,  Motoharu Takeuchi ,  Kazumoto Nakagawa

发明人： Yuichi Yoshimura ,  Motoharu Takeuchi ,  Kazumoto Nakagawa

IPC分类号： C08G18/32 ,  C08G18/38 ,  C08G18/75 ,  G02B1/04 ,  C08G18/52

CPC分类号： G02B1/04 ,  C08G18/3225 ,  C08G18/3237 ,  C08G18/38 ,  C08G18/3855 ,  C08G18/3876 ,  C08G18/758 ,  G02B1/041 ,  C08L75/00

摘要： The composition for optical materials of the present invention comprises a compound having in one molecule at least one structure represented by the following formula (1): wherein R1, R2, R3, R4, X, Y and n are as defined in the disclosure, an amine compound and an isocyanate compound. Resins obtained by curing the composition by polymerization are useful as well-balanced optical materials having a high impact resistance, a high refractive index and a sufficiently high Abbe's number.

摘要翻译： 本发明的光学材料用组合物包含在一分子中具有下述通式（1）表示的至少一种结构的化合物：其中R 1，R 2， R 3，R 4，X，Y和n如本公开所定义，胺化合物和异氰酸酯化合物。 通过聚合固化组合物获得的树脂可用作具有高抗冲击性，高折射率和足够高的阿贝数的均衡的光学材料。

公开(公告)号：US20070149639A1

公开(公告)日：2007-06-28

申请号：US11709158

申请日：2007-02-22

申请人： Hiroshi Horikoshi ,  Kazumoto Nakagawa ,  Motoharu Takeuchi ,  Teruo Kamura

发明人： Hiroshi Horikoshi ,  Kazumoto Nakagawa ,  Motoharu Takeuchi ,  Teruo Kamura

IPC分类号： A61L9/04

CPC分类号： G02B1/04 ,  C08G75/08 ,  C08G79/00 ,  C08K5/0008 ,  C08K2201/007 ,  C08L81/04

摘要： A cured matter obtained by polymerizing and curing a polymerizable composition comprising a compound having at least one episulfide in a molecule is reduced in an odor by adding a perfume to the polymerizable composition comprising the compound having at least one episulfide in a molecule. A cloudiness of the lens is removed by raising a purity of sulfur to 98% or more. A reduction in a chlorine content of the sulfur compound described above to 0.1% by weight or less elevates an oxidation resistance and a light fastness of the high refractive index optical material and improves a color tone thereof. An optical product having a high refractive index and a high-degree transparency is provided by subjecting the composition in advance to deaerating treatment at 0 to 100° C. for one minute to 24 hours under a reduced pressure of 0.001 to 50 torr.

摘要翻译： 通过在包含分子中具有至少一个硫杂环丁烷化合物的可聚合组合物中加入香料，通过聚合和固化包含分子中具有至少一个硫杂环丁烷化合物的聚合性组合物而获得的固化物质变得异味。 通过将硫的纯度提高到98％以上来去除透镜的混浊。 将上述硫化合物的氯含量降低至0.1重量％以下可以提高高折射率光学材料的抗氧化性和耐光性，并提高其色调。 通过在0.001〜50托的减压下，将组合物预先在0〜100℃进行1分钟〜24小时的脱气处理，得到高折射率和高透明度的光学产品。