公开(公告)号：US06482867B1

公开(公告)日：2002-11-19

申请号：US09378636

申请日：1999-08-20

申请人： Tomohiko Kimura ,  Masashi Teramachi ,  Ken Hosoya ,  Yutaka Ohtsu

发明人： Tomohiko Kimura ,  Masashi Teramachi ,  Ken Hosoya ,  Yutaka Ohtsu

IPC分类号： C08F3204

CPC分类号： C08J3/12 ,  B01D15/08 ,  B01J20/26 ,  B01J20/30 ,  C08J2325/02

摘要： There are disclosed a polymer packing material suitable for liquid chromatography and a producing method thereof. The polymer packing material having a polymer particle based on a styrene skeleton with monodispersed particle distribution can be obtained by hydrophilic treatment of an inner surface of a micropore existing in a fine pore of the polymer packing material, or subsequent introduction of a hydrophobic group into the inner hydrophilic surface by chemical modification. A method of producing the polymer packing material suitable for liquid chromatography includes the step of polymerizing glycerol dimethacrylate as a crosslinking agent and 2-ethylhexl methacrylate as a monomer according to a two-step swelling polymerization process. Alternatively, the producing method includes the step of crosslinking and polymerizing only glycerol dimethacrylate to form a polymer, and introducing the hydrophobic group into the polymer by chemical modification.

摘要翻译： 公开了适用于液相色谱的聚合物包装材料及其制造方法。 具有基于具有单分散粒子分布的苯乙烯骨架的聚合物颗粒的聚合物填充材料可以通过亲水处理存在于聚合物填充材料的细孔中的微孔的内表面，或随后将疏水基团引入到 内部亲水表面经化学修饰。 制备适于液相色谱的聚合物包装材料的方法包括根据两步溶胀聚合方法将作为交联剂的甘油二甲基丙烯酸酯和作为单体的2-乙基己基甲基丙烯酸酯聚合的步骤。 或者，制造方法包括仅使甘油二甲基丙烯酸酯交联和聚合以形成聚合物的步骤，并通过化学改性将疏水基团引入聚合物。

公开(公告)号：US09393530B2

公开(公告)日：2016-07-19

申请号：US13261454

申请日：2011-04-05

申请人： Masakazu Minagawa ,  Masashi Teramachi

发明人： Masakazu Minagawa ,  Masashi Teramachi

IPC分类号： B01D67/00 ,  B01D71/34 ,  C08J9/26 ,  B01D69/06 ,  B01D69/08 ,  B01D69/10 ,  B01D71/12 ,  B01D71/40 ,  B01D71/42 ,  B01D71/48 ,  B01D71/56 ,  B01D71/68

CPC分类号： B01D67/0011 ,  B01D67/003 ,  B01D69/06 ,  B01D69/08 ,  B01D69/10 ,  B01D71/12 ,  B01D71/34 ,  B01D71/40 ,  B01D71/42 ,  B01D71/48 ,  B01D71/56 ,  B01D71/68 ,  B01D2323/06 ,  B01D2323/22 ,  B01D2325/20 ,  B01D2325/36 ,  C08J9/26 ,  C08J2201/0464 ,  C08J2327/16

摘要： Disclosed is a process for production of a porous membrane that includes the steps of layering a film-forming dope that contains a polymer (A) that forms a membrane base, a polyvinylpyrrolidone (B) and a solvent (C) into a single layer or two or more layers; immersing the film-forming dope in a solidifying fluid that is a non-solvent with respect to the polymer (A) and is a good solvent with respect to the polyvinylpyrrolidone (B); and removing the polyvinylpyrrolidone (B), wherein the polyvinylpyrrolidone (B) has a K value of 50 to 80, a mass ratio r of the polyvinylpyrrolidone (B) to the polymer (A) is 0.5 or more and less than 1, and the viscosity of the film-forming dope at a membrane production temperature is 100 to 500 Pa·s. Accordingly, by using an appropriate amount of a low-molecular-weight hydrophilic polymer capable of being easily removed, it is possible to produce a porous membrane of a three-dimensional network structure in which macrovoids are suppressed, having high water permeability and superior filtration performance.

摘要翻译： 公开了一种生产多孔膜的方法，其包括以下步骤：将含有形成膜基的聚合物（A），聚乙烯吡咯烷酮（B）和溶剂（C））的成膜原液分层成单层或 两层或多层; 将成膜原液浸渍在相对于聚合物（A）为非溶剂的凝固液中，相对于聚乙烯吡咯烷酮（B）为良好的溶剂; 除去聚乙烯吡咯烷酮（B），其中聚乙烯吡咯烷酮（B）的K值为50〜80，聚乙烯吡咯烷酮（B）与聚合物（A）的质量比r为0.5以上且小于1， 膜生成温度下的成膜原液的粘度为100〜500Pa·s。 因此，通过使用能够容易地除去的适量的低分子量亲水性聚合物，可以制造出抑制大孔，具有高透水性和优异过滤性的三维网状结构的多孔膜 性能。

公开(公告)号：US08752713B2

公开(公告)日：2014-06-17

申请号：US12993709

申请日：2009-05-21

申请人： Masashi Teramachi ,  Kei Murase ,  Toshinori Sumi ,  Yasuo Hiromoto ,  Hiroyuki Fujiki ,  Masaki Kurashina ,  Masakazu Minagawa

发明人： Masashi Teramachi ,  Kei Murase ,  Toshinori Sumi ,  Yasuo Hiromoto ,  Hiroyuki Fujiki ,  Masaki Kurashina ,  Masakazu Minagawa

IPC分类号： B01D29/46 ,  B01D39/14 ,  B32B15/00 ,  B29C47/00

CPC分类号： B01D69/08 ,  B01D61/14 ,  B01D69/02 ,  B01D69/087 ,  B01D2325/02 ,  B01D2325/04 ,  B01D2325/40

摘要： A hollow porous membrane with a reduced cost and excellent separation characteristic, water permeability, and mechanical strength and a process of producing the hollow porous membrane with an excellent adhesive property between a support and a porous membrane layer at a low cost are provided. The hollow porous membrane includes a porous membrane layer in which dense layers are disposed in the vicinities of an outer surface and an inner surface. In the process of producing the hollow porous membrane, membrane-forming dopes of a first membrane-forming dope and a second membrane-forming dope, which contain the material of the porous membrane layer and a solvent, are successively applied and stacked onto the outer circumferential surface of a hollow support and the applied membrane-forming dopes are simultaneously coagulated. In the process of producing the hollow porous membrane, a porous membrane layer is formed by applying a membrane-forming dope containing a material of the porous membrane layer and a solvent to the outer circumferential surface of the hollow support and coagulating the applied dope, and a hollow braid obtained by circularly knitting a yarn formed of multi-filaments is used as the support.

摘要翻译： 提供了一种中空多孔膜，其成本降​​低且分离特性优异，透水性和机械强度，以及以低成本制备支撑体和多孔膜层之间的粘合性优异的中空多孔膜的方法。 中空多孔膜包括多孔膜层，其中致密层设置在外表面和内表面附近。 在制造中空多孔膜的过程中，连续地施加包含多孔膜层和溶剂的材料的第一成膜用原液和第二成膜原液的成膜剂，并层叠在外层 中空支撑体的圆周表面和所施加的成膜涂料同时凝结。 在制造中空多孔膜的过程中，通过将含有多孔膜层和溶剂的成膜原液涂布到中空支撑体的外周面并使涂布液凝结而形成多孔膜层， 使用通过圆形编织由多丝线形成的纱线获得的空心编织物作为支撑体。

公开(公告)号：US20130292860A1

公开(公告)日：2013-11-07

申请号：US13988697

申请日：2011-11-24

申请人： Hiroyuki Fujiki ,  Toshinori Sumi ,  Yasuo Hiromoto ,  Osamu Maehara ,  Masahiro Tanaka ,  Masashi Teramachi

发明人： Hiroyuki Fujiki ,  Toshinori Sumi ,  Yasuo Hiromoto ,  Osamu Maehara ,  Masahiro Tanaka ,  Masashi Teramachi

IPC分类号： D01D5/247

CPC分类号： B01D69/085 ,  B01D69/087 ,  B01D2323/42 ,  B29C48/11 ,  B29C48/29 ,  B29L2031/755 ,  D01D1/09 ,  D01D4/02 ,  D01D4/06 ,  D01D5/24 ,  D01D5/247

摘要： A hollow fiber membrane-spinning nozzle that spins a hollow fiber membrane having a porous membrane layer and a support is provided in which the nozzle includes a resin flow channel through which a membrane-forming resin solution forming the porous membrane layer flows, the resin flow channel includes a liquid storage section that stores the membrane-forming resin solution and a shaping section that shapes the membrane-forming resin solution in a cylindrical shape and satisfies at least one of conditions (a) to (c): (a) the resin flow channel is disposed to cause the membrane-forming resin solution to branch and merge; (b) a delay means for delaying the flow of the membrane-forming resin solution is disposed in the resin flow channel; and (c) the liquid storage section or the shaping section includes branching and merging means for the membrane-forming resin solution therein.

摘要翻译： 提供一种中空纤维膜纺丝喷嘴，其旋转具有多孔膜层和支撑体的中空纤维膜，其中，喷嘴包括树脂流路，形成多孔膜层的成膜树脂溶液通过该树脂流路流动，树脂流 通道包括储存膜形成树脂溶液的液体储存部分和成形部分，其将成膜树脂溶液成形为圆柱形并满足条件（a）至（c）中的至少一个：（a）树脂 设置流路使膜成形树脂溶液分支合并; （b）在树脂流动通道中设置用于延迟成膜树脂溶液的流动的延迟装置; 和（c）液体储存部分或成形部分包括其中的成膜树脂溶液的分支和合并装置。

公开(公告)号：US20130049246A1

公开(公告)日：2013-02-28

申请号：US13261454

申请日：2011-04-05

申请人： Masakazu Minagawa ,  Masashi Teramachi

发明人： Masakazu Minagawa ,  Masashi Teramachi

IPC分类号： C08J9/26

CPC分类号： B01D67/0011 ,  B01D67/003 ,  B01D69/06 ,  B01D69/08 ,  B01D69/10 ,  B01D71/12 ,  B01D71/34 ,  B01D71/40 ,  B01D71/42 ,  B01D71/48 ,  B01D71/56 ,  B01D71/68 ,  B01D2323/06 ,  B01D2323/22 ,  B01D2325/20 ,  B01D2325/36 ,  C08J9/26 ,  C08J2201/0464 ,  C08J2327/16

摘要： Disclosed is a process for production of a porous membrane that includes the steps of layering a film-forming dope that contains a polymer (A) that forms a membrane base, a polyvinylpyrrolidone (B) and a solvent (C) into a single layer or two or more layers; immersing the film-forming dope in a solidifying fluid that is a non-solvent with respect to the polymer (A) and is a good solvent with respect to the polyvinylpyrrolidone (B); and removing the polyvinylpyrrolidone (B), wherein the polyvinylpyrrolidone (B) has a K value of 50 to 80, a mass ratio r of the polyvinylpyrrolidone (B) to the polymer (A) is 0.5 or more and less than 1, and the viscosity of the film-forming dope at a membrane production temperature is 100 to 500 Pa·s. Accordingly, by using an appropriate amount of a low-molecular-weight hydrophilic polymer capable of being easily removed, it is possible to produce a porous membrane of a three-dimensional network structure in which macrovoids are suppressed, having high water permeability and superior filtration performance.

摘要翻译： 公开了一种生产多孔膜的方法，其包括以下步骤：将含有形成膜基的聚合物（A），聚乙烯吡咯烷酮（B）和溶剂（C））的成膜原液分层成单层或 两层或多层; 将成膜原液浸渍在相对于聚合物（A）为非溶剂的凝固液中，相对于聚乙烯吡咯烷酮（B）为良好的溶剂; 除去聚乙烯吡咯烷酮（B），其中聚乙烯吡咯烷酮（B）的K值为50〜80，聚乙烯吡咯烷酮（B）与聚合物（A）的质量比r为0.5以上且小于1， 膜生成温度下的成膜原液的粘度为100〜500Pa·s。 因此，通过使用能够容易地除去的适量的低分子量亲水性聚合物，可以制造出抑制大孔，具有高透水性和优异过滤性的三维网状结构的多孔膜 性能。

公开(公告)号：US20110114553A1

公开(公告)日：2011-05-19

申请号：US12993709

申请日：2009-05-21

申请人： Masashi Teramachi ,  Kei Murase ,  Toshinori Sumi ,  Yasuo Hiromoto ,  Hiroyuki Fujiki ,  Masaki Kurashina ,  Masakazu Minagawa

发明人： Masashi Teramachi ,  Kei Murase ,  Toshinori Sumi ,  Yasuo Hiromoto ,  Hiroyuki Fujiki ,  Masaki Kurashina ,  Masakazu Minagawa

IPC分类号： B01D69/08 ,  D04B1/22 ,  B01D69/10 ,  B05D5/00

CPC分类号： B01D69/08 ,  B01D61/14 ,  B01D69/02 ,  B01D69/087 ,  B01D2325/02 ,  B01D2325/04 ,  B01D2325/40

摘要： A hollow porous membrane with a reduced cost and excellent separation characteristic, water permeability, and mechanical strength and a process of producing the hollow porous membrane with an excellent adhesive property between a support and a porous membrane layer at a low cost are provided. The hollow porous membrane includes a porous membrane layer in which dense layers are disposed in the vicinities of an outer surface and an inner surface. In the process of producing the hollow porous membrane, membrane-forming dopes of a first membrane-forming dope and a second membrane-forming dope, which contain the material of the porous membrane layer and a solvent, are successively applied and stacked onto the outer circumferential surface of a hollow support and the applied membrane-forming dopes are simultaneously coagulated. In the process of producing the hollow porous membrane, a porous membrane layer is formed by applying a membrane-forming dope containing a material of the porous membrane layer and a solvent to the outer circumferential surface of the hollow support and coagulating the applied dope, and a hollow braid obtained by circularly knitting a yarn formed of multi-filaments is used as the support.

摘要翻译： 提供了一种中空多孔膜，其成本降​​低且分离特性优异，透水性和机械强度，以及以低成本制备支撑体和多孔膜层之间的粘合性优异的中空多孔膜的方法。 中空多孔膜包括多孔膜层，其中致密层设置在外表面和内表面附近。 在制造中空多孔膜的过程中，连续地施加包含多孔膜层和溶剂的材料的第一成膜用原液和第二成膜原液的成膜剂，并层叠在外层 中空支撑体的圆周表面和所施加的成膜涂料同时凝结。 在制造中空多孔膜的过程中，通过将含有多孔膜层和溶剂的成膜原液涂敷到中空支撑体的外周面并凝结涂布液而形成多孔膜层， 使用通过圆形编织由多丝线形成的纱线获得的空心编织物作为支撑体。