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公开(公告)号：US4189361A
公开(公告)日：1980-02-19
申请号：US962991
申请日：1978-11-22
申请人： Toru Seita , Takao Satoh , Akihiko Shimizu
发明人： Toru Seita , Takao Satoh , Akihiko Shimizu
CPC分类号： C25B1/46 , C08J5/2293 , C08J2327/12
摘要： An electrolysis of sodium chloride is carried out by using a cation exchange membrane obtained by the following treatment.The cation exchange membrane is prepared by treating one surface of a membrane of a perfluorocarbon polymer having sulfonyl halide groups with a diamine or a polyamine at a temperature of 170.degree. C. to a deterioration temperature of the membrane and immersing a diene derivative having a carboxyl group or a group which can be converted to carboxyl group into the membrane to polymerize the diene derivative and treating the membrane with a water miscible organic solvent having a boiling point of higher than 120.degree. C. in 760 mmHg between smooth plates at 80.degree. C. to 180.degree. C.
摘要翻译： 通过使用通过以下处理获得的阳离子交换膜进行氯化钠的电解。 阳离子交换膜通过将具有磺酰卤基团的全氟化碳聚合物的膜的一个表面与二胺或多胺在170℃的温度下处理至膜的劣化温度并浸渍具有羧基的二烯衍生物 基团或可以转化成羧基的基团，以使二烯衍生物聚合，并在80℃下在平滑板之间的760mmHg的沸点高于120℃的水混溶性有机溶剂处理膜 至180℃
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公开(公告)号：US4431504A
公开(公告)日：1984-02-14
申请号：US373717
申请日：1982-04-30
申请人： Toru Seita , Takao Satoh , Mitsuo Kikuchi
发明人： Toru Seita , Takao Satoh , Mitsuo Kikuchi
CPC分类号： C25B1/46 , C08J5/2281 , C08J2327/12
摘要： A cation-exchange membrane for electrolyzing an aqueous solution of an alkali metal halide in the manufacture of an alkali hydroxide and a halogen. The membrane comprises one layer which occupies 5 to 30% of the total thickness of the membrane and has carboxylic acid groups; another layer which occupies 5 to 30% of the membrane thickness and has weakly acidic groups, the weakly acidic groups occupying 10 to 60% of the total exchange group capacity of the layer; and a further layer which has sulfonic acid groups occupying the middle portion of the membrane.
摘要翻译： 一种用于在碱金属氢氧化物和卤素的制造中电解碱金属卤化物的水溶液的阳离子交换膜。 该膜包含占层膜厚度的5〜30％的一层，具有羧酸基团; 占层膜厚度的5〜30％，弱酸性基团，弱酸性基团占该层总交换容量的10〜60％; 以及具有占据膜的中间部分的磺酸基团的另外的层。
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3.发明授权Process for producing cation exchange membrane by impregnating a diene monomer having carboxylic acid groups into a fluorinated membrane having cation exchange groups and polymerizing 失效通过将具有羧酸基团的二烯单体浸渍到具有阳离子交换基团并且聚合的氟化膜中来生产阳离子交换膜的方法
公开(公告)号：US4189540A
公开(公告)日：1980-02-19
申请号：US4535
申请日：1979-01-18
申请人： Toru Seita , Kenji Takahashi , Shunichi Asami , Akihiko Shimizu
发明人： Toru Seita , Kenji Takahashi , Shunichi Asami , Akihiko Shimizu
IPC分类号： B01J47/12 , C08J5/22 , C25B13/08 , C08F259/08 , C08F265/02 , C08F273/00
CPC分类号： C25B13/08 , C08J5/2281 , C08J2327/12 , C08J2353/02
摘要： A cation exchange membrane is produced by impregnating a diene derivative having carboxylic acid group and/or carboxylic acid convertible group into a cation exchange membrane of a fluorinated polymer having at least one type cation exchange groups having lower acidity than that of sulfonic acid group wherein a ratio of sulfonic acid groups to total cation exchange groups on one surface (A surface layer) is higher than that of the other surface (B surface layer); performing a partial polymerization of the diene derivative and dipping the resulting membrane into an organic solvent which is miscible with water and has a boiling point of higher than 30.degree. C. at 760 mmHg; holding the membrane between a pair of smooth plates; and heating the membrane at 50.degree. to 180.degree. C.; and if the diene derivative having carboxylic acid convertible group is used, converting said groups into carboxylic acid groups.
摘要翻译： 通过将具有羧酸基和/或羧酸可转换基团的二烯衍生物浸渍到具有比磺酸基的酸性低的至少一种阳离子交换基团的氟化聚合物的阳离子交换膜中来制备阳离子交换膜，其中a 一个表面（A表面层）上的磺酸基与总阳离子交换基团的比例高于另一个表面（B表面层）的比例。 进行二烯衍生物的部分聚合并将所得膜浸入与水混溶并在760mmHg下具有高于30℃的沸点的有机溶剂; 将膜保持在一对光滑的板之间; 并在50℃至180℃加热膜。 并且如果使用具有羧酸可转换基团的二烯衍生物，则将所述基团转化为羧酸基团。
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4.发明授权Method of improving characteristic of cation-exchange membrane by swelling in water miscible organic solvent and treating further with hydrochloric acid 失效通过在水溶性有机溶剂中溶胀改善阳离子交换膜的特性并用盐酸进一步处理的方法
公开(公告)号：US4174426A
公开(公告)日：1979-11-13
申请号：US913364
申请日：1978-06-07
申请人： Shunichi Asami , Toru Seita , Akihiko Shimizu
发明人： Shunichi Asami , Toru Seita , Akihiko Shimizu
CPC分类号： C08J5/2293 , C08J2327/12
摘要： A homogeneous cation-exchange membrane made of one or more fluorinated polymer having cation-exchangeable groups is swollen with a water miscible organic solvent and then the solvent is removed from the swollen membrane and then membrane is treated with hydrochloric acid.The cation-exchange membrane of the fluorinated polymer having cation-exchangeable groups is modified to reduce the permeability of hydroxyl group ions by swelling it and removing the water-miscible organic solvent and then, treating it with hydrochloric acid.
摘要翻译： 由具有阳离子可交换基团的一种或多种含氟聚合物制成的均匀的阳离子交换膜用水混溶性有机溶剂溶胀，然后从溶胀膜中除去溶剂，然后用盐酸处理膜。 具有阳离子交换性基团的氟化聚合物的阳离子交换膜被改性以通过溶胀来降低羟基离子的渗透性并除去水混溶性有机溶剂，然后用盐酸处理。
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公开(公告)号：US4693796A
公开(公告)日：1987-09-15
申请号：US792629
申请日：1985-10-25
申请人： Toru Seita , Takao Satoh , Mitsuo Kikuchi
发明人： Toru Seita , Takao Satoh , Mitsuo Kikuchi
CPC分类号： C08J5/2281 , C08J2327/18
摘要： A cation exchange membrane manufacturing method in which a film of a blend which consists of a perfluoro carbon polymer having a group transformable into a sulfonic acid group and a perfluoro carbon polymer having a group transformable into a carboxylic acid group or a film of a copolymer which consists of a perfluoro carbon monomer having a group transformable into a sulfonic acid group and a perfluoro carbon monomer having a group transformable into a carboxylic acid group and another film of a perfluoro carbon polymer having a group transformable into a carboxylic acid group are joined together. Following that, the group transformable into a carboxylic acid group and the group transformable into a sulfonic acid group are transformed respectively into the carboxylic acid group and the sulfonic acid group.
摘要翻译： 一种阳离子交换膜的制造方法，其中由具有可转化成磺酸基团的全氟碳聚合物和具有可转化成羧酸基团的全氟碳聚合物组成的共混物膜或共聚物膜 由具有可转化成磺酸基团的全氟碳单体和具有可转化成羧酸基的基团的全氟碳单体和具有可转化成羧酸基团的全氟碳聚合物的另一膜组合在一起。 之后，可转化成羧酸基团和可转化成磺酸基团的基团分别转化成羧酸基团和磺酸基团。
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公开(公告)号：US4316781A
公开(公告)日：1982-02-23
申请号：US192543
申请日：1980-09-30
申请人： Toru Seita , Takao Satoh , Mitsuo Kikuchi
发明人： Toru Seita , Takao Satoh , Mitsuo Kikuchi
CPC分类号： C25B1/46
摘要： An improved method for electrolyzing alkali metal halide. Electrolysis is carried out by supplying an aqueous solution of a halide of alkali metal into an anode chamber partitioned by a cation-exchange membrane and water into a cathode chamber to obtain halogen from the anode chamber and hydrogen and alkali hydroxide from the cathode chamber. The cation-exchange membrane is a fluorocarbon polymer membrane which is prepared by arranging one side thereof to have a cation exchange group concentration lower by 10 to 30% within a depth range of 1 to 100.mu. than that of the other side. The anode chamber is prepared with this side of the membrane which has the lower cation exchange group concentration arranged to face the anode chamber. By this arrangement, a high purity alkali hydroxide can be manufactured at a high rate of decomposition of halide of alkali metal and at a high current efficiency.
摘要翻译： 一种电解碱金属卤化物的改进方法。 通过将由阳离子交换膜和水分隔的阳极室供给碱金属卤化物的水溶液进入阴极室，从阳极室获得卤素，从阴极室供给氢和碱金属氢氧化物，进行电解。 阳离子交换膜是氟碳聚合物膜，其通过将其一侧的阳极交换基团浓度设定为比另一侧的1〜100μm的深度范围低10〜30％来制备。 阳极室由阳离子交换剂浓度较低的膜的这一侧制成，以面对阳极室。 通过这种布置，可以以高碱性金属的卤化物的高分解率和高电流效率制造高纯碱性氢氧化物。
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公开(公告)号：US4295944A
公开(公告)日：1981-10-20
申请号：US166787
申请日：1980-07-08
申请人： Takao Satoh , Toru Seita
发明人： Takao Satoh , Toru Seita
CPC分类号： C25B1/46
摘要： An alkali metal hydroxide and hydrogen in a cathode compartment and chlorine in an anode compartment by feeding an aqueous solution of an alkali metal chloride in said anode compartment which is partitioned from said cathode compartment with a cation exchange membrane made of a fluorinated polymer is produced under a condition that a temperature of said anode compartment is kept at lower than a temperature of said cathode compartment in said electrolysis.
摘要翻译： 在阴极室中的碱金属氢氧化物和氢气和阳极室中的氯通过在由所述阴极室分隔的所述阳极室中的碱金属氯化物水溶液与由氟化聚合物制成的阳离子交换膜进行制备 所述阳极室的温度保持低于所述电解中所述阴极室的温度的条件。
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公开(公告)号：US4205134A
公开(公告)日：1980-05-27
申请号：US920988
申请日：1978-06-30
申请人： Toru Seita , Akihiko Shimizu , Yoshio Kato , Tsutomu Hashimoto
发明人： Toru Seita , Akihiko Shimizu , Yoshio Kato , Tsutomu Hashimoto
CPC分类号： G01N30/482 , C08F8/30 , G01N30/34 , B01J2220/54
摘要： A carrier for liquid chromatography having main units ##STR1## wherein n=0 or an integer of 1 to 3; m=0 or 1; q=an integer of 1 to 3; p=0 or 1; w=90 to 16; x=57 to 2; y=0 to 30; z=5 to 30; B represents adenine, guanine, thymine, uracil or cytosine; X' represents OH Cl, Br or I; and CM represents styrene, a substituted styrene, acrylonitrile, a substituted acrylonitril, acrylic acid or a substituted acrylic acid and CCM represents crosslinking agent having two or more unsaturated group such as ethylene glycol diacrylate, divinylbenzene etc.
摘要翻译： 具有主要单元（I）的液相色谱载体，其中n = 0或1至3的整数; m = 0或1; q = 1〜3的整数; p = 0或1; w = 90〜16; x = 57〜2; y = 0〜30; z = 5〜30; B代表腺嘌呤，鸟嘌呤，胸腺嘧啶，尿嘧啶或胞嘧啶; X'表示OH Cl，Br或I; CM代表苯乙烯，取代苯乙烯，丙烯腈，取代丙烯腈，丙烯酸或取代的丙烯酸，CCM代表具有两个或多个不饱和基团的交联剂，如乙二醇二丙烯酸酯，二乙烯基苯等。
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公开(公告)号：US4200538A
公开(公告)日：1980-04-29
申请号：US807638
申请日：1977-06-17
申请人： Toru Seita , Kenji Takahashi , Shunichi Asami , Akihiko Shimizu
发明人： Toru Seita , Kenji Takahashi , Shunichi Asami , Akihiko Shimizu
IPC分类号： C25B13/08 , B01J47/12 , C08J5/22 , C08J7/16 , C08F259/08 , C08F265/02
CPC分类号： C08J5/2293 , C08J2327/18
摘要： A cation-exchange membrane is prepared by swelling a fluorinated polymer membrane having cation-exchangeable groups with an organic solvent and then removing the solvent from the swollen membrane and immersing a monomer with or without a crosslinking agent and a polymerization initiator into it and polymerizing the monomer. The membrane is preferably swollen with a water miscible organic solvent and then, the solvent is removed from the membrane.
摘要翻译： 通过使具有阳离子交换性基团的氟化聚合物膜与有机溶剂溶胀，然后从溶胀膜中除去溶剂并将具有或不具有交联剂和聚合引发剂的单体浸入其中并使其聚合，从而制备阳离子交换膜 单体。 膜优选用水混溶性有机溶剂溶胀，然后从膜上除去溶剂。
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10.发明授权Process for producing cation exchange membrane by treatment of fluorinated polymer containing sulfonyl halide groups with amine and vinyl monomer 失效通过处理含有磺酰卤基团的含氟聚合物与胺和乙烯基单体来生产阳离子交换膜的方法
公开(公告)号：US4154909A
公开(公告)日：1979-05-15
申请号：US929499
申请日：1978-07-31
申请人： Toru Seita , Kenji Takahashi , Shunichi Asami , Akihiko Shimizu
发明人： Toru Seita , Kenji Takahashi , Shunichi Asami , Akihiko Shimizu
CPC分类号： C08J5/2237 , C25B1/46 , C08J2327/18
摘要： A cation exchange membrane is produced by treating a membrane of a fluorinated polymer having sulfonyl halide group on side chains with a mixture of 1 a reaction product of an amine with a halogenated monomer and 2 a vinyl monomer and/or diene monomer each of which has carboxylic acid group, phenolic hydroxyl group, sulfonic acid group and/or a functional group being convertible into carboxylic acid group, phenolic hydroxyl group or sulfonic acid group.
摘要翻译： 阳离子交换膜是通过用胺与卤化单体的反应产物1和乙烯基单体和/或二烯单体的混合物处理侧链上具有磺酰卤基团的氟化聚合物的膜来制备的， 羧酸基，酚羟基，磺酸基和/或可转化为羧酸基的官能团，酚羟基或磺酸基。
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