Heat-expandable microspheres and a process for producing the same
    6.
    发明授权
    Heat-expandable microspheres and a process for producing the same 有权
    热膨胀性微球及其制造方法

    公开(公告)号:US08329298B2

    公开(公告)日:2012-12-11

    申请号:US12067771

    申请日:2006-10-04

    IPC分类号: C08J9/16 B32B15/02

    摘要: A method that heat-expandable microspheres includes the use of a shell of thermoplastic resin and a non-fluorine blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin. The method includes, a step of dispersing an oily mixture containing a polymerizable component, the blowing agent, and a polymerization initiator containing a peroxydicarbonate in an aqueous dispersing medium to polymerize the polymerizable component contained in the oily mixture. The resultant heat-expandable microsphres have a shell which is less apt to become thinner than its theoretical value, contain minimum amount of resin particle inside their shell, and have excellent heat-expanding performance.

    摘要翻译: 热膨胀性微球的方法包括使用热塑性树脂的壳和封入其中的沸点不高于热塑性树脂的软化点的非氟发泡剂。 该方法包括:将含有可聚合组分的油性混合物,发泡剂和含有过氧化二碳酸酯的聚合引发剂在含水分散介质中分散以使包含在油性混合物中的可聚合组分聚合的步骤。 所得到的热膨胀微孔具有较不易于其理论值变薄的外壳,其外壳中含有最少量的树脂颗粒,并且具有优异的热膨胀性能。

    HEAT-EXPANDABLE MICROSPHERES AND A PROCESS FOR PRODUCING THE SAME
    7.
    发明申请
    HEAT-EXPANDABLE MICROSPHERES AND A PROCESS FOR PRODUCING THE SAME 有权
    可热膨胀的微球及其制造方法

    公开(公告)号:US20090176098A1

    公开(公告)日:2009-07-09

    申请号:US12067771

    申请日:2006-10-04

    IPC分类号: C08J9/16 B32B1/00

    摘要: A method that heat-expandable microspheres includes the use of a shell of thermoplastic resin and a non-fluorine blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin. The method includes a step of dispersing an oily mixture containing a polymerizable component, the blowing agent, and a polymerization initiator containing a peroxydicarbonate in an aqueous dispersing medium to polymerize the polymerizable component contained in the oily mixture. The resultant heat-expandable microspheres have a shell which is less apt to become thinner than its theoretical value, contain minimum amount of resin particle inside their shell, and have excellent heat-expanding performance.

    摘要翻译: 热膨胀性微球的方法包括使用热塑性树脂的壳和封入其中的沸点不高于热塑性树脂的软化点的非氟发泡剂。 该方法包括将含有可聚合组分的油性混合物,发泡剂和含有过氧化二碳酸酯的聚合引发剂分散在水性分散介质中以使包含在油性混合物中的可聚合组分聚合的步骤。 所得到的热膨胀性微球体的外壳不易于其理论值变薄,在其壳内含有最少量的树脂颗粒,并且具有优异的热膨胀性能。

    Thermo-expansive microspheres, their production process and their application
    9.
    发明申请
    Thermo-expansive microspheres, their production process and their application 有权
    热膨胀微球,其生产工艺及其应用

    公开(公告)号:US20080293838A1

    公开(公告)日:2008-11-27

    申请号:US12068430

    申请日:2008-02-06

    IPC分类号: C08J9/224 C08J9/20

    摘要: The present invention provides a process for producing thermo-expansive microspheres comprising a thermoplastic resinous shell and a blowing agent being encapsulated in the shell, the blowing agent which is a fluorine-containing C2-10 compound having ether linkage, being free of chlorine and bromine atoms and gasifying at a temperature not higher than the softening point of the thermoplastic resin. The thermo-expansive microspheres have preferably an average particle size ranging from 1 to 100 μm and a CV, or coefficient of variation, of particle size distribution being 30% or less, and a retaining ratio of blowing agent encapsulated being 90% or more.

    摘要翻译: 本发明提供一种包含热塑性树脂壳和包封在壳中的发泡剂的热膨胀性微球的方法,发泡剂是具有醚键的含氟C2-10化合物,不含氯和溴 原子并在不高于热塑性树脂的软化点的温度下气化。 热膨胀性微球体的平均粒径优选为1〜100μm,粒径分布的CV或变异系数为30%以下,发泡剂的保持率为90%以上。

    Thermo-expansive microcapsules and their application
    10.
    发明申请
    Thermo-expansive microcapsules and their application 有权
    热膨胀微胶囊及其应用

    公开(公告)号:US20050026067A1

    公开(公告)日:2005-02-03

    申请号:US10923811

    申请日:2004-08-24

    IPC分类号: B01J13/14 G03C1/72

    CPC分类号: B01J13/14 Y10T428/2987

    摘要: Thermo-expansive microcapsules comprising a shell of a polymer produced by polymerizing a mixture of monomers, which comprises (I) a nitrile monomer, (II) a monomer having an unsaturated double bond and carboxyl groups in a molecule, (III) a monomer having two or more of polymerizable double bonds in a molecule, and optionally, (IV) a monomer different from and copolymerizable with the monomers (I), (II) and (III) and a blowing agent encapsulated in the shell. The volume retention of the expanded microcapsules of the thermo-expansive microcapsules is 50% or more after loaded with 15 MPa.

    摘要翻译: 包含通过聚合单体混合物制备的聚合物的壳的热膨胀微胶囊,其包含(I)腈单体,(II)分子中具有不饱和双键的单体和羧基,(III)具有 分子中的两个或更多个可聚合双键,和任选地(Ⅳ)与单体(I),(II)和(III)不同且可共聚的单体和包封在壳中的发泡剂。 热膨胀微胶囊的膨胀微胶囊的体积保留率在加载15MPa后为50%以上。