摘要:
A lithium secondary battery comprising a nonaqueous electrolyte obtained by dissolving an electrolytic salt in a solvent, a negative electrode comprising a negative electrode material and a positive electrode comprising a positive electrode active material, the electrolytic salt comprising: at least one electrolytic salt A selected from the group consisting of LiPF.sub.6, LiAsF.sub.6, LiSbF.sub.6, LiBF.sub.4, LiBiF.sub.4, LiAlF.sub.4, LiGaF.sub.4, LiInF.sub.4 and LiClO.sub.4, and at least one electrolytic salt B selected from the group consisting of LiN(C.sub.n F.sub.2n+1 SO.sub.2).sub.2 wherein n is an integer of 1, 2, 3 or 4 and LiC(C.sub.m F.sub.2m+1 SO.sub.2).sub.3 wherein m is an integer of 1, 2, 3 or 4. The battery is superior in the aspects of storage characteristic in a charged condition.
摘要:
A non-aqueous electrolyte battery according to the invention includes a positive electrode using a lithium-metal compound oxide as a positive electrode material, a negative electrode and a non-aqueous electrolyte solution, the battery employing a positive electrode material composed of the lithium-metal compound oxide which contains at least Ni, Co and Mn, and has a peak with a full width at half maximum of not greater than 0.22.degree. in a range of 2.theta.=18.71.+-.0.25.degree. as measured by the powder X-ray diffraction analysis using a Cu-K.alpha. X-ray source or employing a positive electrode material composed of a lithium-metal compound oxide which contains at least Ni, Co and Mn, and a non-aqueous electrolyte solution which includes a solvent containing ethylene carbonate and a solute containing at least one type of fluorine-containing compound.
摘要:
The opening to be sealed in a battery is sealed with an electrical insulating sealant S by placing an electrical insulating sealing material C, including a first sealing material A that is soften by heat applied for sealing and a second sealing material B that is more difficult to soften by the heat applied for sealing than the first sealing material A, and by heating and successively cooling the electrical insulating sealing material C. The second sealing material B is in the form of a mesh. Thus, a sealed battery with few defectives such as a sealing failure and a short-circuit can be manufactured in a high yield rate.
摘要:
In a polymer electrolyte battery provided with a positive electrode, a negative electrode, and a polymer electrolyte containing a non-aqueous electrolyte solution, a solvent in said non-aqueous electrolyte solution contains vinylene carbonate in a concentration of 0.1 to 90 vol % so that the non-aqueous electrolyte solution contained in the polymer electrolyte is restrained from reacting with the positive electrode and negative electrode.
摘要:
The opening to be sealed in a battery is sealed with an electrical insulating sealant S by placing an electrical insulating sealing material C, including a first sealing material A that is soften by heat applied for sealing and a second sealing material B that is more difficult to soften by the heat applied for sealing than the first sealing material A, and by heating and successively cooling the electrical insulating sealing material C. Thus, a sealed battery with few defectives such as a sealing failure and a short-circuit can be manufactured in a high yield rate.
摘要:
A lithium secondary battery of this invention includes a positive electrode using, as an active material, a lithium-containing manganese composite oxide with a spinel structure having a composition, during charge and discharge, represented by a formula, LixMn2-y-zNiyMzO4, in which M is at least one element selected from the group consisting of Fe, Co, Ti, V, Mg, Zn, Ga, Nb, Mo and Cu; 0.02≦×≦1.10, whereas x changes in accordance with occlusion and discharge of lithium ions during charge and discharge; 0.25≦y≦0.60; and 0
摘要翻译:本发明的锂二次电池包括使用具有由式LixMn2-y-zNiyMzO4表示的充电和放电组成的尖晶石结构的含锂锰复合氧化物作为活性材料的正极, 其中M为选自Fe,Co,Ti,V,Mg,Zn,Ga,Nb,Mo和Cu中的至少一种元素; 0.02 <= x <= 1.10,而x在充放电期间根据锂离子的闭塞和放电而改变; 0.25 <= y <= 0.60; 0
摘要:
In a non-aqueous electrolyte secondary battery provided with a positive electrode 1, a negative electrode 2, and a non-aqueous electrolyte solution, a lithium-containing composite nickel oxide is used as a chief component of the positive electrode material for the positive electrode, a lithium-containing titanium oxide is used as a chief component of the negative electrode material for the negative electrode, and the solvent of the non-aqueous electrolyte solution contains a cyclic carbonic ester and a chain carbonic ester in such a manner that the cyclic carbonic ester and chain carbonic ester are contained in amounts of not less than 10% by volume of the whole solvent, respectively, and the total content of the cyclic carbonic ester and the chain carbonic ester is not less than 60% by volume of the whole solvent.
摘要:
The battery of this invention includes a positive electrode including a gelled polymeric electrolyte (A) and using spinel type lithium manganese oxide as an active material; a negative electrode; a gelled polymeric electrolyte (B) in the shape of a film or sheet also serving as a separator, and both the gelled polymeric electrolyte (A) and the gelled polymeric electrolyte (B) are made from a polymer of poly(alkylene oxide) series impregnated with a liquid electrolyte. Since the battery includes the positive electrode using the specific gelled polymeric electrolyte (A), a contact area between the positive electrode active material and the gelled polymeric electrolyte is large, so as to attain large initial discharge capacity (at high rate discharge in particular). Also, since the battery includes the specific gelled polymeric electrolyte (B) as the electrolyte, manganese included in the spinel type lithium manganese oxide is minimally eluted, and hence, the discharge capacity is minimally degraded during charge-discharge cycles due to elution of manganese, resulting in attaining good charge-discharge cycle performance.
摘要:
In an inventive polymer electrolyte battery including a positive electrode, a negative electrode and a polymer electrolyte, at least one of the positive electrode and the negative electrode is formed with an inorganic amorphous solid electrolyte film at its interface with the polymer electrolyte.
摘要:
In a non-aqueous electrolyte battery using titanium oxide or lithium titanate as a negative electrode material for negative electrode, polymeric electrolyte is interposed between the negative electrode and a positive electrode. If titanium oxide or lithium titanate is used as the negative electrode material for negative electrode and the polymeric electrolyte is interposed between the negative electrode and the positive electrode, the polymeric electrolyte is less liable to be decomposed by catalytic reduction induced by titanium oxide or lithium titanate. This prevents decline in the charge/discharge efficiency which occurs when a non-aqueous electrolyte solution is used. Thus, the non-aqueous electrolyte battery excellent in charge/discharge efficiency is provided.