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    Method for partial nuclear hydrogenation of aromatic hydrocarbon compounds and a hydrogenation catalyst therefor
    3.
    发明授权
    Method for partial nuclear hydrogenation of aromatic hydrocarbon compounds and a hydrogenation catalyst therefor 失效
    芳烃化合物的部分核氢化方法及其加氢催化剂。

    公开(公告)号：US4495373A

    公开(公告)日：1985-01-22

    申请号：US582565

    申请日：1984-02-22

    申请人： Shuichi Niwa ,  Juichi Imamura ,  Fujio Mizukami ,  Kazuo Shimizu ,  Yoshio Orito

    发明人： Shuichi Niwa ,  Juichi Imamura ,  Fujio Mizukami ,  Kazuo Shimizu ,  Yoshio Orito

    IPC分类号： B01J23/00 ,  B01J23/46 ,  C07B61/00 ,  C07C1/00 ,  C07C5/11 ,  C07C13/20 ,  C07C67/00 ,  C07C5/02

    CPC分类号： B01J23/462 ,  C07C5/11 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2523/46 ,  C07C2523/72

    摘要： The invention provides an improvement in the partial nuclear hydrogenation of an aromatic hydrocarbon compound in the liquid phase with admixture of water catalyzed by a ruthenium-containing solid catalyst. The scope of the invention is in the use of a novel ruthenium-containing catalyst supported on a silica gel and the like carrier and the catalyst is prepared by the hydrolysis and gelation of an alkoxide of silicon or aluminum in a solution containing a ruthenium compound, e.g. ruthenium alkoxide, followed by drying of the gelled material so that the resultant catalyst is very uniformly impregnated with the ruthenium ingredient to be imparted with greatly improved catalytis activity and selectivity for the intended reaction over conventional ruthenium-containing catalysts prepared by post-impregnation of a preformed silica gel carrier.

    摘要翻译： 本发明提供了通过含钌固体催化剂催化的水的混合在液相中芳族烃化合物的部分核氢化的改进。 本发明的范围是使用负载在硅胶等载体上的新型含钌催化剂，并且通过在含有钌化合物的溶液中水解和凝胶化硅或铝的醇盐来制备催化剂， 例如 钌醇盐，然后干燥凝胶材料，使得所得到的催化剂非常均匀地浸渍钌成分，与所用的含钌催化剂相比，通过后浸渍法制备的催化剂活性和选择性大大提高。 预制的硅胶载体。