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    Ethylene random copolymers
    1.
    发明授权
    Ethylene random copolymers 失效
    乙烯无规共聚物

    公开(公告)号：US5218071A

    公开(公告)日：1993-06-08

    申请号：US900784

    申请日：1992-06-22

    申请人： Toshiyuki Tsutsui ,  Ken Yoshitsugu ,  Akinori Toyota

    发明人： Toshiyuki Tsutsui ,  Ken Yoshitsugu ,  Akinori Toyota

    IPC分类号： C08F4/659 ,  C08F4/6592 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F210/08 ,  C08F210/16

    CPC分类号： C08F10/06 ,  C08F210/08 ,  C08F210/16 ,  C08F110/06 ,  C08F210/06 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  Y10S526/943

    摘要： In accordance with the present invention, there are provided ethylene copolymers composed of structural units (a) derived from ethylene and structural units (b) derived from .alpha.-olefin of 3.about.20 carbon atoms, said ethylene copolymers having[A] a density of 0.85.about.0.92 g/cm.sup.3,[B] an intrinsic viscosity [.eta.] as measured in decalin at 135.degree. C. of 0.1.about.10 dl/g,[C] a ratio (Mw/Mn) of a weight average molecular weight (Mw) to a number average molecular weight (Mn) as measured by GPC of 1.2.about.4, and[D] a ratio (MFR.sub.10 /MFR.sub.2) of MFR.sub.10 under a load of 10 kg to MFR.sub.2 under a load of 2.16 kg at 190.degree. C. of 8.about.50, and being narrow in molecular weight distribution and excellent in flowability.

    摘要翻译： 根据本发明，提供由乙烯衍生的结构单元（a）和衍生自碳原子数3〜20的α-烯烃的结构单元（b）组成的乙烯共聚物，所述乙烯共聚物的[A]密度为 0.85差异0.92g / cm 3，[B]在135℃的十氢化萘中测得的特性粘度η为0.1Dd / g，[C]重均分子的比率（＆lt;上升＆Mw /＆lt;上升＆ 重量（＆Upbar＆Mw）与通过1.2差聚差4的GPC测定的数均分子量（＆amp; upbar＆Mn）和[D]在负载为10kg时MFR10的MFR 10与MFR 2的比（MFR 10 / MFR 2）在2.16 kg，在190℃为8分钟，分子量分布窄，流动性好。

    Ethylene random copolymers
    2.
    发明授权
    Ethylene random copolymers 失效
    乙烯无规共聚物

    公开(公告)号：US5639842A

    公开(公告)日：1997-06-17

    申请号：US650425

    申请日：1996-05-20

    申请人： Toshiyuki Tsutsui ,  Ken Yoshitsugu ,  Akinori Toyota

    发明人： Toshiyuki Tsutsui ,  Ken Yoshitsugu ,  Akinori Toyota

    IPC分类号： C08F4/64 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F210/08 ,  C08F210/16 ,  C08F210/02

    CPC分类号： C08F10/00 ,  C08F10/06 ,  C08F210/08 ,  C08F210/16 ,  C08F110/06 ,  C08F210/06 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927

    摘要： In accordance with the present invention, there are provided ethylene copolymers composed of structural units (a) derived from ethylene and structural units (b) derived from .alpha.-olefin of 3.about.20 carbon atoms, said ethylene copolymers having[A] a density of 0.85.about.0.92 g/cm.sup.3,[B] an intrinsic viscosity [.eta.] as measured in decalin at 135.degree. C. of 0.1-10 dl/g,[C] a ratio (Mw/Mn) of a weight average molecular weight (Mw) to a number average molecular weight (Mn) as measured by GPC of 1.2.about.4, and[D] a ratio (MFR.sub.10 /MFR.sub.2) of MFR.sub.10 under a load of 10 kg to MFR.sub.2 under a load of 2.16 kg at 190.degree. C. of 8.about.50, and being narrow in molecular weight distribution and excellent in flowability.

    摘要翻译： 根据本发明，提供由乙烯衍生的结构单元（a）和衍生自碳原子数3〜20的α-烯烃的结构单元（b）组成的乙烯共聚物，所述乙烯共聚物的[A]密度为 0.85差异0.92g / cm 3，[B]在135℃萘烷中测定的特性粘度η为0.1-10dl / g，[C]比率（+ E，ovs M + EE w / + E ，ovs M + EE n）的重均分子量（+ E，ovs M + EE w）至数均分子量（+ E，ovs M + EE n） D]在10℃的负荷下MFR10的MFR10与MFR2的摩尔比（MFR 10 / MFR 2）在190℃时的摩尔比为2.16kg，分子量分布窄，流动性优异。

    Ethylene random copolymers
    4.
    发明授权
    Ethylene random copolymers 失效
    乙烯无规共聚物

    公开(公告)号：US5916988A

    公开(公告)日：1999-06-29

    申请号：US831953

    申请日：1997-04-02

    申请人： Toshiyuki Tsutsui ,  Ken Yoshitsugu ,  Akinori Toyota

    发明人： Toshiyuki Tsutsui ,  Ken Yoshitsugu ,  Akinori Toyota

    IPC分类号： C08F4/64 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F210/08 ,  C08F210/16

    CPC分类号： C08F210/16 ,  C08F10/00 ,  C08F10/06 ,  C08F210/08 ,  C08F110/06 ,  C08F210/06 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  Y10S526/916 ,  Y10S526/943

    摘要： In accordance with the present invention, there are provided ethylene copolymers composed of structural units (a) derived from ethylene and structural units (b) derived from .alpha.-olefin of 3-20 carbon atoms, said ethylene copolymers having�A! a density of 0.85-0.92 g/cm.sup.3,�B! an intrinsic viscosity �.eta.! as measured in decalin at 135.degree. C. of 0.1-10 dl/g,�C! a ratio (Mw/Mn) of a weight average molecular weight (Mw) to a number average molecular weight (Mn) as measured by GPC of 1.2-4, and�D! a ratio (MFR.sub.10 /MFR.sub.2) of MFR.sub.10 under a load of 10 kg to MFR.sub.2 under a load of 2.16 kg at 190.degree. C. of 8-50, and being narrow in molecular weight distribution and excellent in flowability.

    摘要翻译： 根据本发明，提供了由衍生自乙烯的结构单元（a）和由3-20个碳原子的α-烯烃衍生的结构单元（b）组成的乙烯共聚物，所述乙烯共聚物具有[A] 0.85〜0.92g / cm 3，[135]萘烷中在135℃下测定的特性粘度η为0.1-10dl / g，[C]比率（+ E，ovs M + EE w / + E ，ovs M + EE n）的重均分子量（+ E，ovs M + EE w）与通过GPC测定的数均分子量（+ E，ovs M + EE n） D]在10℃负荷下MFR10的MFR10与MFR2在190℃时的负载为2.16kg的比率（MFR10 / MFR2）为8〜50，分子量分布窄，流动性优异。

    Olefin polymerization catalyst
    5.
    发明授权
    Olefin polymerization catalyst 失效
    烯烃聚合催化剂

    公开(公告)号：US5714426A

    公开(公告)日：1998-02-03

    申请号：US459795

    申请日：1995-06-02

    申请人： Toshiyuki Tsutsui ,  Ken Yoshitsugu ,  Akinori Toyota

    发明人： Toshiyuki Tsutsui ,  Ken Yoshitsugu ,  Akinori Toyota

    IPC分类号： C08F4/64 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F210/08 ,  C08F210/16

    CPC分类号： C08F210/16 ,  C08F10/00 ,  C08F10/06 ,  C08F210/08 ,  C08F110/06 ,  C08F210/06 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  Y10S526/916 ,  Y10S526/943

    摘要： In accordance with the present invention, there are provided ethylene copolymers composed of structural units (a) derived from ethylene and structural units (b) derived from .alpha.-olefin of 3.about.20 carbon atoms, said ethylene copolymers having �A! a density of 0.85.about.0.92 g/cm.sup.3, �B! an intrinsic viscosity �.eta.! as measured in decalin at 135.degree. C. of 0.1.about.10 dl/g, �C! a ratio (Mw/Mn) of a weight average molecular weight (Mw) to a number average molecular weight (Mn) as measured by GPC of 1.2.about.4, and �D! a ratio (MFR.sub.10 /MFR.sub.2) of MFR.sub.10 under a load of 10 kg to MFR.sub.2 under a load of 2.16 kg at 190.degree. C. of 8.about.50, and being narrow in molecular weight distribution and excellent in flowability.

    摘要翻译： 根据本发明，提供由乙烯衍生的结构单元（a）和衍生自碳原子数3〜20的α-烯烃的结构单元（b）组成的乙烯共聚物，所述乙烯共聚物的[A]密度为 0.85差异0.92g / cm 3，[B]在135℃萘烷中测得的特性粘度η为0.1Dd / g，[C]比率（+ E，ovs M + EE w / + E ，ovs M + EE n）的重均分子量（+ E，ovs M + EE w）至数均分子量（+ E，ovs M + EE n） D]在10℃的负荷下MFR10的MFR10与MFR2的摩尔比（MFR 10 / MFR 2）在190℃时的摩尔比为2.16kg，分子量分布窄，流动性优异。

    Process for preparing ethylene copolymers
    6.
    发明授权
    Process for preparing ethylene copolymers 失效
    制备乙烯共聚物的方法

    公开(公告)号：US5525689A

    公开(公告)日：1996-06-11

    申请号：US458696

    申请日：1995-06-02

    申请人： Toshiyuki Tsutsui ,  Ken Yoshitsugu ,  Akinori Toyota

    发明人： Toshiyuki Tsutsui ,  Ken Yoshitsugu ,  Akinori Toyota

    IPC分类号： C08F4/64 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F210/08 ,  C08F210/16 ,  C08F4/643 ,  C08F210/14

    CPC分类号： C08F210/16 ,  C08F10/00 ,  C08F10/06 ,  C08F210/08 ,  C08F110/06 ,  C08F210/06 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  Y10S526/916 ,  Y10S526/943

    摘要： In accordance with the present invention, there are provided ethylene copolymers composed of structural units (a) derived from ethylene and structural units (b) derived from .alpha.-olefin of 3.about.20 carbon atoms, said ethylene copolymers having[A] density of 0.85.about.0.92 g/cm.sup.3,[B] an intrinsic viscosity [.eta.] as measured in decalin at 135.degree. C. of 0.1.about.10 dl/g,[C] a ratio (Mw/Mn) of a weight average molecular weight (Mw) to a number average molecular weight (Mn) as measured by GPC of 1.2.about.4, and[D] a ratio (MFR.sub.10 /MFR.sub.2) of MFR.sub.10 under a load of 10 kg to MFR.sub.2 under a load of 2.16 kg at 190.degree. C. of 8.about.50, and being narrow in molecular weight distribution and excellent in flowability.

    摘要翻译： 根据本发明，提供由乙烯衍生的结构单元（a）和衍生自碳原子数3〜20的α-烯烃的结构单元（b）组成的乙烯共聚物，所述乙烯共聚物的[A]密度为0.85 差异0.92g / cm 3，[B]在135℃的十氢化萘中测得的特性粘度η为0.1Dd / g，[C]重均分子量的比率（＆lt;上升＆Mw /＆lt;上升＆ （＆Upbar＆Mw）与通过1.2DIFFERENCE 4的GPC测定的数均分子量（＆Upbar＆Mn）和[D]在10kg负荷下MFR10的MFR10与MFR2在2.16kg负荷下的比（MFR 10 / MFR 2） 在190℃，差异为50，分子量分布窄，流动性好。

    Process for olefin polymerization
    7.
    发明授权
    Process for olefin polymerization 失效
    烯烃聚合方法

    公开(公告)号：US6043325A

    公开(公告)日：2000-03-28

    申请号：US978602

    申请日：1997-11-26

    申请人： Toshiyuki Tsutsui ,  Ken Yoshitsugu ,  Masaaki Ohgizawa ,  Tetsuhiro Matsumoto ,  Junichi Imuta

    发明人： Toshiyuki Tsutsui ,  Ken Yoshitsugu ,  Masaaki Ohgizawa ,  Tetsuhiro Matsumoto ,  Junichi Imuta

    IPC分类号： C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  C08F4/64

    CPC分类号： C08F10/00 ,  C08F210/16 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  Y10S526/904 ,  Y10S526/943

    摘要： A process for olefin polymerization, including polymerizing or copolymerizing an olefin in the presence of an olefin polymerization catalyst composed of: a fine particle carrier; (A) a transition metal compound of a Group IVB metal of the periodic table, containing a ligand having a cyclopentadienyl skeleton; (B) an aluminoxane compound; and optionally (C) an organoaluminum compound, wherein said aluminoxane compound has an alkyl groups to aluminum ratio of 1.3 to 2.1; said transition metal compound (A) and said organoaluminum oxy-compound (B) and said organoaluminum compound being supported on the fine particle carrier; and said solid catalyst having a bulk density of 0.3 g/cm.sup.3 to 0.5 g/cm.sup.3 and a fluidity index of 45 to 70 and an olefin polymerization process using the olefin polymerization catalyst; and an olefin prepolymerized catalyst obtained by prepolymerizing the catalyst, and an olefin polymerization process using the olefin prepolymerized catalyst. The olefin polymerization process produces a polymer showing excellent particle properties and an olefin polymer which does not stick to the wall of the polymerization reactor.

    摘要翻译： 一种烯烃聚合方法，包括在烯烃聚合催化剂存在下聚合或共聚烯烃，所述烯烃聚合催化剂由微粒载体构成; （A）周期表第ⅣB族金属的过渡金属化合物，其含有具有环戊二烯基骨架的配位体; （B）铝氧烷化合物; 和任选地（C）有机铝化合物，其中所述铝氧烷化合物具有1.3至2.1的烷基与铝的比率; 所述过渡金属化合物（A）和所述有机铝氧化合物（B）和所述有机铝化合物负载在所述微粒载体上; 所述固体催化剂的体积密度为0.3g / cm 3〜0.5g / cm 3，流动性指数为45〜70，使用该烯烃聚合催化剂的烯烃聚合方法; 和通过使催化剂预聚合获得的烯烃预聚合催化剂和使用烯烃预聚合催化剂的烯烃聚合方法。 烯烃聚合方法产生显示出优异的颗粒性能的聚合物和不粘在聚合反应器壁上的烯烃聚合物。

    Olefin polymerization catalyst and process for olefin polymerization
    8.
    发明授权
    Olefin polymerization catalyst and process for olefin polymerization 失效
    烯烃聚合催化剂和烯烃聚合方法

    公开(公告)号：US5795838A

    公开(公告)日：1998-08-18

    申请号：US513088

    申请日：1995-08-09

    申请人： Toshiyuki Tsutsui ,  Ken Yoshitsugu ,  Masaaki Ohgizawa ,  Tetsuhiro Matsumoto ,  Junichi Imuta

    发明人： Toshiyuki Tsutsui ,  Ken Yoshitsugu ,  Masaaki Ohgizawa ,  Tetsuhiro Matsumoto ,  Junichi Imuta

    IPC分类号： C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  B01J31/00 ,  B01J37/00 ,  C08F4/02 ,  C08F4/60

    CPC分类号： C08F10/00 ,  C08F210/16 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  Y10S526/904 ,  Y10S526/943

    摘要： A solid olefin polymerization catalyst comprising: a fine particle carrier; (A) a transition metal compound of a Group IVB metal of the periodic table, containing a ligand having a cyclopentadienyl skeleton; (B) an organoaluminum oxy-compound; and optionally (C) an organoaluminum compound, wherein said organoaluminum oxy-compound has an alkyl to aluminum ratio of 1.3 to 2.1; said transition metal compound (A) and said organoaluminum oxy-compound (B) and said organoaluminum compound being supported on the fine particle carrier; and said solid catalyst having a bulk density of 0.3 g/cm.sup.3 to 0.5 g/cm.sup.3 and a fluidity index of 45 to 70 and an olefin polymerization process using the olefin polymerization catalyst; and an olefin prepolymerized catalyst obtained by prepolymerizing the catalyst, and an olefin polymerization process using the olefin prepolymerized catalyst. The olefin polymerization catalyst and the olefin prepolymerization catalyst when used to carry out the polymerization of olefins hardly produces a fine-powdery polymer and a polymer showing excellent particle properties can be obtained. Moreover, the resulting olefin polymer does not stick to the wall of the polymerization reactor.

    摘要翻译： 一种固体烯烃聚合催化剂，包括：细颗粒载体; （A）周期表第ⅣB族金属的过渡金属化合物，其含有具有环戊二烯基骨架的配位体; （B）有机铝氧化合物; 和任选的（C）有机铝化合物，其中所述有机铝氧化合物的烷基铝比例为1.3-2.1; 所述过渡金属化合物（A）和所述有机铝氧化合物（B）和所述有机铝化合物负载在所述微粒载体上; 所述固体催化剂的体积密度为0.3g / cm 3〜0.5g / cm 3，流动性指数为45〜70，使用该烯烃聚合催化剂的烯烃聚合方法; 和通过使催化剂预聚合获得的烯烃预聚合催化剂和使用烯烃预聚合催化剂的烯烃聚合方法。 当用于进行烯烃聚合的烯烃聚合催化剂和烯烃预聚合催化剂几乎不产生细粉状聚合物，并且可以获得显示出优异的颗粒性能的聚合物。 此外，所得烯烃聚合物不粘附到聚合反应器的壁。