公开(公告)号：US6057480A

公开(公告)日：2000-05-02

申请号：US930708

申请日：1997-10-16

申请人： Tsunemasa Ueno ,  Ikuyo Katsumi ,  Naoko Yamamoto ,  Hitoshi Mitsui

发明人： Tsunemasa Ueno ,  Ikuyo Katsumi ,  Naoko Yamamoto ,  Hitoshi Mitsui

IPC分类号： C07F3/02 ,  C07F5/02

CPC分类号： C07F3/02 ,  C07F5/027

摘要： A fluoroaryl magnesium derivative is produced by reacting aryl fluoride, hydrocarbon halide, and magnesium with one another in an ether solvent or a mixed solvent of the ether solvent and a hydrocarbon solvent. Also, a (fluoroaryl)borane compound is produced by mixing both a solution prepared by dissolving the fluoroaryl magnesium derivative into the ether solvent and another solvent prepared by dissolving the boron halide in the ether solvent with a hydrocarbon solvent having a higher boiling point than the ether solvent, so that the fluoroaryl magnesium derivative and boron halide react with each other while the ether solvent is being distilled out.

摘要翻译： PCT No.PCT / JP97 / 00391 Sec。 371日期：1997年10月16日 102（e）日期1997年10月16日PCT 1997年2月12日提交PCT公布。 公开号WO97 / 31924 PCT 日期1997年9月4日氟芳基镁衍生物通过芳基氟化物，烃卤化物和镁在醚溶剂或醚溶剂和烃溶剂的混合溶剂中彼此反应来制备。 此外，（氟化芳基）硼烷化合物是通过将通过将氟化芳基镁衍生物溶解在醚溶剂中制备的溶液和通过将卤化硼溶解在醚溶剂中制备的另一种溶剂与沸点高于 醚溶剂，使得氟化芳基镁衍生物和卤化硼在蒸出醚溶剂的同时彼此反应。

公开(公告)号：US06683218B1

公开(公告)日：2004-01-27

申请号：US08955854

申请日：1997-10-21

申请人： Hitoshi Mitsui ,  Ikuyo Katsumi ,  Naoko Yamamoto

发明人： Hitoshi Mitsui ,  Ikuyo Katsumi ,  Naoko Yamamoto

IPC分类号： C07F502

CPC分类号： C07F5/02

摘要： A fluoroaryl magnesium derivative expressed by General Formula (1): where each of R1-R5 represents a hydrogen atom, a fluorine atom, a hydrocarbon group, or an alkoxy group while at least one of R1-R5 representing a fluorine atom, and Xa represents a chlorine atom, a bromine atom, or an iodine atom; and boron halide expressed by General Formula (2): BXb3  (2)  where Xb represents a fluorine atom, a chlorine atom, a bromine atom, or an iodine atom, are reacted with each other in a solvent (a) containing diethyl ether and/or tetrahydrofuran, after which the resulting reaction solution is added to a solvent (b) having a higher boiling point than diethyl ether and/or tetrahydrofuran while diethyl ether and/or tetrahydrofuran are distilled out. Consequently, it has become possible to obtain a (fluoroaryl)borane compound expressed by General Formula (3):  where each of R1-R5, and Xb, represents the same as above, and n represents 2 or 3, from which magnesium halide produced as a by-product is separated and removed, selectively in a simple manner at a low cost.

摘要翻译： 由通式（1）表示的氟化芳基镁衍生物：其中R1-R5各自表示氢原子，氟原子，烃基或烷氧基，而R1-R5中至少一个表示氟原子，Xa 表示氯原子，溴原子或碘原子; 由通式（2）表示的卤代硼：其中Xb表示氟原子，氯原子，溴原子或碘原子，在含有二乙醚和/或四氢呋喃的溶剂（a）中彼此反应，之后 将所得反应溶液加入到沸点比二乙醚和/或四氢呋喃高的溶剂（b）中，同时蒸馏出乙醚和/或四氢呋喃。 因此，可以获得由通式（3）表示的（氟化芳基）硼烷化合物：其中R1-R5和Xb各自表示与上述相同的含义，n表示2或3，由此产生卤化镁 作为副产物以低成本以简单的方式选择性地分离和除去。

公开(公告)号：US06291452B1

公开(公告)日：2001-09-18

申请号：US09269752

申请日：1999-04-30

申请人： Yoshinari Sato ,  Seiichiro Tabuchi ,  Hitoshi Mitsui ,  Ikuyo Katsumi ,  Naoko Yamamoto

发明人： Yoshinari Sato ,  Seiichiro Tabuchi ,  Hitoshi Mitsui ,  Ikuyo Katsumi ,  Naoko Yamamoto

IPC分类号： A61K315513

CPC分类号： C07K5/0821 ,  A61K38/00 ,  C07D243/14 ,  C07D243/18 ,  C07K5/0205 ,  C07K5/06139

摘要： Benzodiazepine derivatives of the formula: wherein R2 is alkyl or cycloalkyl-alkyl when R4 is hydrogen, or R2 is a variety of specified groups when R4 is alkyl, halogen or dialkylamino, are useful as cholecystokinin antagonists.

摘要翻译： 下式的苯并二氮杂衍生物：当R 4为氢时，R 2为烷基或环烷基 - 烷基，或者当R 4为烷基，卤素或二烷基氨基时，R 2为多种规定基团，可用作缩胆囊素拮抗剂。

公开(公告)号：US06624329B2

公开(公告)日：2003-09-23

申请号：US10024306

申请日：2001-12-21

申请人： Hitoshi Mitsui ,  Tsunemasa Ueno ,  Ikuyo Ikeno ,  Naoko Yamamoto

发明人： Hitoshi Mitsui ,  Tsunemasa Ueno ,  Ikuyo Ikeno ,  Naoko Yamamoto

IPC分类号： C07F502

CPC分类号： C07F5/027

摘要： Tetrakis(fluoroaryl)borate•magnesium halide (Ar4BMgX) expressed by General Formula (1): where each of R1-R10 represents a hydrogen atom, a fluorine atom, a hydrocarbon group, or an alkoxy group, provided that at least one of R1-R5 represents a fluorine atom and at least one of R6-R10 represents a fluorine atom, X represents a chlorine atom, a bromine atom, or an iodide atom, and n represents 2 or 3, is treated with alkali metal salts of carboxylic acid and/or alkali earth metal salts of carboxylic acid. Then, a tetrakis(fluoroaryl)borate derivative (Ar4BZ) is produced by reacting treated Ar4BMgX with a compound generating monovalent cation seeds (for example, N,N-dimethylaniline•hydrochloride). Consequently, it has become possible to provide a purifying process of separating/removing impurities from Ar4BMgX readily and efficiently, and a process of producing inexpensive Ar4BX efficiently.

摘要翻译： 由通式（1）表示的四（氟化芳基）硼酸镁卤化物（Ar4BMgX）：其中R1-R10各自表示氢原子，氟原子，烃基或烷氧基，条件是R 1 -R5表示氟原子，R6-R10中的至少一个表示氟原子，X表示氯原子，溴原子或碘原子，n表示2或3，用羧酸的碱金属盐处理 和/或羧酸的碱土金属盐。 然后，通过使处理的Ar4BMgX与产生一价阳离子种子（例如N，N-二甲基苯胺盐酸盐）的化合物反应来制备四（氟化芳基）硼酸盐衍生物（Ar4BZ）。 因此，可以容易且高效地提供从Ar4BMgX中分离除去杂质的净化方法，以及有效地制造廉价的Ar4BX的工序。

公开(公告)号：US06215025B1

公开(公告)日：2001-04-10

申请号：US09171832

申请日：1998-10-26

申请人： Hitoshi Mitsui ,  Tsunemasa Ueno ,  Ikuyo Ikeno ,  Naoko Yamamoto

发明人： Hitoshi Mitsui ,  Tsunemasa Ueno ,  Ikuyo Ikeno ,  Naoko Yamamoto

IPC分类号： C07F502

CPC分类号： C07F5/027

摘要： Tetrakis(fluoroaryl)borate.magnesium halide (Ar4BMgX) expressed by General Formula (1): where each of R1-R10 represents a hydrogen atom, a fluorine atom, a hydrocarbon group, or an alkoxy group, provided that at least one of R1-R5 represents a fluorine atom and at least one of R6-R10 represents a fluorine atom, X represents a chlorine atom, a bromine atom, or an iodide atom, and n represents 2 or 3, is treated with alkali metal salts of carboxylic acid and/or alkali earth metal salts of carboxylic acid. Then, a tetrakis(fluoroaryl)borate derivative (Ar4BZ) is produced by reacting treated Ar4BMgX with a compound generating monovalent cation seeds (for example, N,N-dimethylaniline.hydrochloride). Consequently, it has become possible to provide a purifying process of separating/removing impurities from Ar4BMgX readily and efficiently, and a process of producing inexpensive Ar4BX efficiently.

摘要翻译： 由通式（1）表示的四（氟化芳基）硼酸镁卤化物（Ar4BMgX）：其中R1-R10各自表示氢原子，氟原子，烃基或烷氧基，条件是R1 -R5表示氟原子，R6-R10中的至少一个表示氟原子，X表示氯原子，溴原子或碘原子，n表示2或3，用羧酸的碱金属盐处理 和/或羧酸的碱土金属盐。 然后，通过使处理的Ar4BMgX与产生一价阳离子种子（例如N，N-二甲基苯胺盐酸盐）的化合物反应来制备四（氟化芳基）硼酸盐衍生物（Ar4BZ）。 因此，可以容易且高效地提供从Ar4BMgX中分离除去杂质的净化方法，以及有效地制造廉价的Ar4BX的工序。

公开(公告)号：US6118026A

公开(公告)日：2000-09-12

申请号：US104042

申请日：1998-06-25

申请人： Hitoshi Mitsui ,  Tsunemasa Ueno ,  Ikuyo Ikeno ,  Naoko Yamamoto

发明人： Hitoshi Mitsui ,  Tsunemasa Ueno ,  Ikuyo Ikeno ,  Naoko Yamamoto

IPC分类号： C07F5/02 ,  C07C5/02

CPC分类号： C07F5/027

摘要： A (fluoroaryl)borane compound expressed by General Formula (1): ##STR1## where each of R.sub.1 -R.sub.5 represents a hydrogen atom, a fluorine atom, a hydrocarbon group, or an alkoxy group, provided that at least one of R.sub.1 -R.sub.5 represents a fluorine atom, X represents a fluorine atom, a chlorine atom, a bromine atom, or an iodine atom, and n represents 2 or 3, is stabilized by letting inorganic metal salts having a fluorine atom coexist with the (fluoroaryl)borane compound in a hydrocarbon solution. After the hydrocarbon solution is concentrated in the presence of the inorganic metal salts, the inorganic metal salts are removed and the fluoroaryl)borane compound is crystallized. Consequently, it has become possible to provide a method of stabilizing a (fluoroaryl)borane compound by suppressing the decomposition reaction while the solution is heated and concentrated, stored (preserved), or transported/transferred, and a crystallizing method of isolating highly-pure crystals (powders) of the (fluoroaryl)borane compound efficiently.

摘要翻译： 由通式（1）表示的（氟化芳基）硼烷化合物：其中R 1 -R 5各自表示氢原子，氟原子，烃基或烷氧基，条件是R 1 -R 5中的至少一个表示氟 原子，X表示氟原子，氯原子，溴原子或碘原子，n表示2或3，通过使具有氟原子的无机金属盐与（氟化​​芳基）硼烷化合物在烃中共存而稳定化 解。 在无机金属盐存在下将烃溶液浓缩后，除去无机金属盐，并使氟代芳基）硼烷化合物结晶。 因此，可以提供一种通过在将溶液加热浓缩，储存（保存）或输送/转移的同时抑制分解反应来稳定（氟化芳基）硼烷化合物的方法，以及分离高纯度 （氟化芳基）硼烷化合物的结晶（粉末）有效。

公开(公告)号：US06380435B2

公开(公告)日：2002-04-30

申请号：US09779673

申请日：2001-02-09

申请人： Hitoshi Mitsui ,  Tsunemasa Ueno ,  Ikuyo Ikeno ,  Naoko Yamamoto

发明人： Hitoshi Mitsui ,  Tsunemasa Ueno ,  Ikuyo Ikeno ,  Naoko Yamamoto

IPC分类号： C07F502

CPC分类号： C07F5/027

摘要： Tetrakis (fluoroaryl)borate.magnesium halide (Ar4BMgX) expressed by General Formula (1): where each of R1-R10 represents a hydrogen atom, a fluorine atom, a hydrocarbon group, or an alkoxy group, provided that at least one of R1-R5 represents a fluorine atom and at least one of R6-R10 represents a fluorine atom, X represents a chlorine atom, a bromine atom, or an iodide atom, and n represents 2 or 3, is treated with alkali metal salts of carboxylic acid and/or alkali earth metal salts of carboxylic acid. Then, a tetrakis(fluoroaryl)borate derivative (Ar4BZ) is produced by reacting treated Ar4BMgX with a compound generating monovalent cation seeds (for example, N,N-dimethylaniline.hydrochloride). Consequently, it has become possible to provide a purifying process of separating/removing impurities from Ar4BMgX readily and efficiently, and a process of producing inexpensive Ar4BX efficiently.

摘要翻译： 由通式（1）表示的四（氟化芳基）硼酸镁卤化物（Ar4BMgX）：其中R1-R10各自表示氢原子，氟原子，烃基或烷氧基，条件是R1 -R5表示氟原子，R6-R10中的至少一个表示氟原子，X表示氯原子，溴原子或碘原子，n表示2或3，用羧酸的碱金属盐处理 和/或羧酸的碱土金属盐。 然后，通过使处理的Ar4BMgX与产生一价阳离子种子（例如N，N-二甲基苯胺盐酸盐）的化合物反应来制备四（氟化芳基）硼酸盐衍生物（Ar4BZ）。 因此，可以容易且高效地提供从Ar4BMgX中分离除去杂质的净化方法，以及有效地制造廉价的Ar4BX的工序。

公开(公告)号：US08135742B2

公开(公告)日：2012-03-13

申请号：US11696932

申请日：2007-04-05

申请人： Naoko Yamamoto ,  Masaji Munekuni ,  Shigeki Mori

发明人： Naoko Yamamoto ,  Masaji Munekuni ,  Shigeki Mori

IPC分类号： G06F7/00 ,  G06F17/30

CPC分类号： H04L67/16 ,  H04L12/66

摘要： A proxy service providing apparatus includes a service search unit adapted to, upon receiving, from a connection device connectable to a network, a request of a service provided by each device connected to the network, search for a providable service to the connection device in accordance with a relationship with the connection device, and a providing unit adapted to replicate and provide the providable service to the connection device based on a search result of said service search unit.

摘要翻译： 代理服务提供装置包括：服务搜索单元，适于在从可连接到网络的连接装置接收到由连接到网络的每个设备提供的服务的请求时，根据所述连接设备搜索可提供的服务 与连接装置的关系，以及提供单元，其适于基于所述服务搜索单元的搜索结果来复制并提供可提供的服务到连接装置。

公开(公告)号：US07478609B2

公开(公告)日：2009-01-20

申请号：US10494562

申请日：2002-10-11

申请人： Naoko Yamamoto ,  I'atsushi Yamamoto ,  Masaki Hirayama ,  I'adahiro Ohmi

发明人： Naoko Yamamoto ,  I'atsushi Yamamoto ,  Masaki Hirayama ,  I'adahiro Ohmi

IPC分类号： C23C16/00 ,  C23F1/00 ,  H01L21/306

CPC分类号： H01J37/32238 ,  H01J37/32192

摘要： A plasma processing apparatus and a processing apparatus having a widened process condition range allowing plasma generation are obtained by increasing microwave propagation efficiency. The plasma processing apparatus includes a processing chamber where plasma processing is performed, and microwave introducer for introducing microwaves into the processing chamber. The microwave introducer includes a dielectric member transmitting the microwaves. The dielectric member has a shape in cross section in a direction approximately perpendicular to a transmitting direction of the microwaves through the dielectric member that allows transmission of the microwaves of substantially a single mode. The dielectric member has a thickness T in the transmitting direction that satisfies a condition of (λ×(2m+0.7)/4)≦T≦(λ×(2m+1.3)/4), where λ is a wavelength of the microwaves of the single mode transmitted through the dielectric member and m is an arbitrary integer.

摘要翻译： 通过提高微波传播效率，可以获得等离子体处理装置和具有允许等离子体产生的加宽处理条件范围的处理装置。 等离子体处理装置包括进行等离子体处理的处理室和用于将微波引入处理室的微波导引器。 微波导引器包括传输微波的电介质构件。 电介质构件的形状在大致垂直于通过电介质构件的微波的传输方向的方向上的横截面，其允许基本上单模的微波的传输。 电介质构件具有满足条件（lambdax（2m + 0.7）/ 4）<= T <=（lambdax（2m + 1.3）/ 4）的传输方向的厚度T，其中λ是微波的波长 通过介电构件传输的单一模式，m是任意整数。

公开(公告)号：US08694498B2

公开(公告)日：2014-04-08

申请号：US12327359

申请日：2008-12-03

申请人： Naoko Yamamoto

发明人： Naoko Yamamoto

IPC分类号： G06F17/30

CPC分类号： G06F17/30997 ,  G06F17/30265 ,  G06F17/3028

摘要： In a data management apparatus that performs data management by assigning metadata to a plurality of data, the plurality of data are displayed according to a display mode chosen from a plurality of display modes for displaying the plurality of data as a set of attribute information of the data, and a candidate for metadata to be assigned to the displayed data is determined based on the display mode.

摘要翻译： 在通过将元数据分配给多个数据来执行数据管理的数据管理装置中，根据从多个显示模式中选择的显示模式显示多个数据，用于显示多个数据作为一组属性信息 基于显示模式来确定要分配给所显示的数据的元数据和候选数据。