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    Cross-linked pullulan
    2.
    发明授权
    Cross-linked pullulan 失效
    交联支链淀粉

    公开(公告)号：US4152170A

    公开(公告)日：1979-05-01

    申请号：US695762

    申请日：1976-06-14

    申请人： Tsuneyuki Nagase ,  Kozo Tsuji ,  Masanori Fujimoto ,  Fujio Masuko

    发明人： Tsuneyuki Nagase ,  Kozo Tsuji ,  Masanori Fujimoto ,  Fujio Masuko

    IPC分类号： C08B37/00 ,  C08L5/00

    CPC分类号： C08B37/0018

    摘要： Cross-linked pullulans are obtained by the reaction of pullulan with a cross-linking agent selected from the group consisting of polycarboxylic acids, halogenated dicarboxylic acids, polycarboxylic anhydrides, aldehyde compounds, N-methylol compounds, isocyanate compounds, metaphosphoric acid salts, divinyl compounds, bis-aziridine and bifunctional compounds of the formula,X--R--Zwherein X and Z are each a halogen atom or an epoxy group and R is an aliphatic residue having 1 to 30 carbon atoms, in a solvent, and are useful as gels or beds for chromatography or in various fields requiring high degrees of water absorbency and retention.

    摘要翻译： 通过支链淀粉与选自多元羧酸，卤代二羧酸，多羧酸酐，醛化合物，N-羟甲基化合物，异氰酸酯化合物，偏磷酸盐，二乙烯基化合物的交联剂的反应获得交联的起始链优化 ，双氮丙啶和下式的双官能化合物XRZ，其中X和Z各自为卤素原子或环氧基，R为具有1至30个碳原子的脂族残基，并且可用作凝胶或床 色谱法或需要高吸水度和保留度的各种领域。

    Enzyme immobilization with pullulan gel
    7.
    发明授权
    Enzyme immobilization with pullulan gel 失效
    酶固定与支链淀粉凝胶

    公开(公告)号：US4247642A

    公开(公告)日：1981-01-27

    申请号：US878572

    申请日：1978-02-16

    申请人： Hideo Hirohara ,  Shigeyasu Nabeshima ,  Masanori Fujimoto ,  Tsuneyuki Nagase

    发明人： Hideo Hirohara ,  Shigeyasu Nabeshima ,  Masanori Fujimoto ,  Tsuneyuki Nagase

    IPC分类号： C08B37/00 ,  C12N11/10

    CPC分类号： C08B37/0018 ,  C12N11/10

    摘要： Enzymes are immobilized by a process wherein the carrier used for immobilizing is a hydrophilic pullulan gel having a three-dimensionally reticulated structure obtained by the reaction between pullulan and a bifunctional compound capable of forming an ether linkage with the hydroxyl group contained in the glucose unit of pullulan, or an ionic pullulan gel obtained by the reaction between said hydrophilic pullulan gel and a compound having at one end an ionizable group and at the other end a functional group capable of forming an ether linkage with the hydroxyl group in the pullulan gel in the presence of an alkaline coumpound. Immobilized enzymes prepared according to this process have a high activity and good retention of the activity.

    摘要翻译： 通过一种方法将酶固定化，其中用于固定的载体是具有三维网状结构的亲水支链淀粉凝胶，其通过支链淀粉与能够与葡萄糖单元中所含的羟基形成醚键的双官能化合物反应而获得 支链淀粉或通过所述亲水支链淀粉凝胶和一端具有可离子化基团的反应获得的离子支链淀粉凝胶，另一端是能够与支链淀粉凝胶中的羟基形成醚键的官能团 碱性化合物的存在。 根据该方法制备的固定化酶具有高活性和良好的活性保留性。

    Preparing a hydrophilic gel by hydrolyzing a vinyl ester-acrylic or methacrylic ester copolymer
    8.
    发明授权
    Preparing a hydrophilic gel by hydrolyzing a vinyl ester-acrylic or methacrylic ester copolymer 失效
    通过水解乙烯基酯 - 丙烯酸或甲基丙烯酸酯共聚物制备亲水凝胶

    公开(公告)号：US4155893A

    公开(公告)日：1979-05-22

    申请号：US841910

    申请日：1977-10-13

    申请人： Masanori Fujimoto ,  Toshifumi Tamura ,  Tsuneyuki Nagase

    发明人： Masanori Fujimoto ,  Toshifumi Tamura ,  Tsuneyuki Nagase

    IPC分类号： C08F8/12 ,  C08F8/42 ,  C08L29/02

    CPC分类号： C08F8/42 ,  C08F2800/10

    摘要： A method for the preparation of water-insoluble gels containing at least a hydroxyl group and a carboxylate group in molecules thereof which comprises saponifying copolymers comprising a vinyl ester component and an acrylic or methacrylic acid ester component or terpolymers comprising said two components and an ethylene component in the presence of an alkali catalyst and a solvent under conditions in which said copolymers or terpolymers are not dissolved.

    摘要翻译： 一种在分子中制备至少含有羟基和羧酸酯基团的水不溶性凝胶的方法，其包括包含乙烯基酯组分和丙烯酸或甲基丙烯酸酯组分的皂化共聚物或包含所述两种组分的三元共聚物和乙烯组分 在碱性催化剂和溶剂的存在下，在所述共聚物或三元共聚物不溶解的条件下进行。

    Covered electrode for arc welding
    9.
    发明授权
    Covered electrode for arc welding 失效
    电弧焊用电极

    公开(公告)号：US4205218A

    公开(公告)日：1980-05-27

    申请号：US890506

    申请日：1978-03-27

    申请人： Kousuke Fukami ,  Masanori Fujimoto ,  Fumio Fujita ,  Tsuneyuki Nagase

    发明人： Kousuke Fukami ,  Masanori Fujimoto ,  Fumio Fujita ,  Tsuneyuki Nagase

    IPC分类号： B23K35/365 ,  B23K35/40

    CPC分类号： B23K35/404 ,  B23K35/365

    摘要： A covered electrode for arc welding is disclosed which exhibits tight adhesion between the cover material and the core wire and provides good arc stability. This covered electrode comprises a core wire coated with a coating composition comprising (a) a powdered mixture of an inorganic oxide, carbonate and fluoride, (b) an alkali silicate and (c) 0.001 to 5.0% by weight of pullulan based on the alkali silicate.

    摘要翻译： 公开了一种用于电弧焊的覆盖电极，其在覆盖材料和芯线之间表现出紧密的粘合性并提供良好的电弧稳定性。 该覆盖电极包括涂覆有涂料组合物的芯线，其包含（a）无机氧化物，碳酸盐和氟化物的粉末混合物，（b）碱金属硅酸盐和（c）基于碱的0.001至5.0重量％的支链淀粉 硅酸盐。

    Ionic pullulan gels and production thereof
    10.
    发明授权
    Ionic pullulan gels and production thereof 失效
    离子支链淀粉凝胶及其生产

    公开(公告)号：US4174440A

    公开(公告)日：1979-11-13

    申请号：US890505

    申请日：1978-03-27

    申请人： Fumio Fujita ,  Kousuke Fukami ,  Masanori Fujimoto ,  Tsuneyuki Nagase

    发明人： Fumio Fujita ,  Kousuke Fukami ,  Masanori Fujimoto ,  Tsuneyuki Nagase

    IPC分类号： B01J39/22 ,  C08B37/00 ,  C07H15/04

    CPC分类号： C08B37/0018 ,  B01J39/22

    摘要： A process for producing ionic pullulan gels which comprises gelation of pullulan by crosslinking and introduction of ionic groups into the resulting pullulan gel, the former comprising reacting pullulan with a bi-functional compound in a solvent in the presence of an alkaline substance, and the latter comprising reacting the resulting pullulan gel with a compound having a carboxyl, sulfonic, phosphoric or amino group in a solvent in the presence of an alkaline substance.

    摘要翻译： 一种生产离子支链淀粉凝胶的方法，其包括通过将离子基团交联并引入所得支链淀粉凝胶中而使支链淀粉凝胶化，前者包括在碱性物质存在下在溶剂中将支链淀粉与双官能化合物反应，后者 包括使所得支链淀粉凝胶与在溶剂中在碱性物质存在下具有羧基，磺酸基，磷酸基或氨基的化合物反应。