摘要:
A visible light curable resin composition containing a photocurable resin, a photoreaction initiator and a photosensitizer having the formula (1). The composition has a very high sensitivity to a general-purpose visible light laser, so that a high-speed scanning exposure is possible by the laser, and an extremely fine high resolution can be obtained. In addition, the composition can be used for coating or printing under safelight irradiating conditions and under bright circumstantial conditions without any thickening of the composition, and hence the composition can exert excellent noticeable effects in points of safe operativity, operational efficiency and the stability of products. Formula (1) is as follows: ##STR1## wherein rings X.sub.1 and X.sub.2 are each an optionally substituted pyrrole ring; Y is H, CN, optionally substituted alkyl, aralkyl, aryl, heteroaryl or alkenyl group; and Z.sub.1 and Z.sub.2 are halogen, optionally substituted alkyl, alkoxy, alkylthio, aralkyl, aralkyloxy, aryl, aryloxy, arylthio, heteroaryl, heteroaryloxy or heteroarylthio group, provided that at least one of substituents on the pyrrole rings X.sub.1 and X.sub.2, groups Z.sub.1 and Z.sub.2 is the alkoxy, aralkyloxy or aryloxy group.
摘要:
An optical recording medium having at least a recording layer and a reflective layer on a substrates, the said recording layer contains a dipyrromethene metal chelate compound obtained from a dipyrromethene compound represented by the general formula (1) and a metal ion: ##STR1## wherein R.sup.1 to R.sup.7 are defined in the specification.
摘要:
An optical recording medium having at least a recording layer and a reflective layer on a substrate. The recording layer contains a dipyrromethene metal chelate compound obtained from a dipyrromethene compound represented by the general formula (1) and a metal ion: ##STR1## wherein R.sup.1 to R.sup.7 are defined in the specification.
摘要:
A near infrared light-absorbing dye comprising phthalocyanine compounds represented by the following formula (2): ##STR1## wherein in formula (2), M is two hydrogen atoms, a divalent metallic atom, a trivalent monosubstituted metallic atom, a tetravalent disubstituted metallic atom or an oxymetal atom, and L.sup.1, L.sup.2, L.sup.3 and L.sup.4 are each independently formula (a) or (b), ##STR2## in the formula (a) or (b), R.sup.1 and R.sup.3 are each a substituted or unsubstituted alkyl group, and R.sup.2 is a straight chain or branched halogenated alkyl or alkenyl group having 3 to 10 carbon atoms, X is a chlorine, bromine or iodine atom, and m is an integer of 1 to 12, provided that formula (2) represents a mixture of L.sup.1 =L.sup.2 =L.sup.3 =L.sup.4 =formula (a), L.sup.1 =L.sup.2 =L.sup.4 =formula (a) and L.sup.3 =formula (b), L.sup.1 =L.sup.4 =formula (a) and L.sup.2 =L.sup.3 =formula (b), L.sup.1 =L.sup.3 =formula (a) and L.sup.2 =L.sup.4 =formula (b), L.sup.1 =formula (a) and L.sup.2 =L.sup.3 =L.sup.4 =formula (b), and L.sup.1 =L.sup.2 =L.sup.3 =L.sup.4 =formula (b), and an optical recording medium comprising the phthalocyanine mixture.
摘要:
The present invention relates to an optical recording medium having a recording layer, a reflective layer and a protective layer on a substrate, wherein a quinophthalone compound represented by the following formula (1) is contained in the above recording layer. The use of the quinophthalone compound or a mixture of the quinophthalone compound and a photoabsorbing compound having an absorption maximum in a wavelength falling in a range of 550 to 900 nm in the recording layer makes it possible to provide an interchangeable optical recording medium not only capable of recording and reproducing with a laser having a wavelength falling in a range of 480 to 600 nm, but is also capable of recording and reproducing with red lasers having wavelengths of 630 nm and 680 nm and a near infrared laser having a wavelength of 780 nm. ##STR1##
摘要:
A novel optical recording medium having at least a recording layer and a reflective layer on a substrate is herein disclosed, wherein at least one dipyrromethene metal chelate compound represented by formula (1) is contained in the recording layer: wherein R1 and R9 are each independently an alkenyl group, an aryl group or a heteroaryl group; R2 to R8 are each independently a hydrogen atom, a halogen atom, or a substituted or unsubstituted alkyl, alkoxy, alkenyl, acyl, alkoxycarbonyl, aralkyl, aryl or heteroaryl group having 20 or less carbon atoms; and M is a transition metal.
摘要翻译:本文公开了一种在基片上至少具有记录层和反射层的新型光学记录介质,其中至少一种由式(1)表示的二吡咯亚甲基金属螯合物包含在记录层中:其中R1和R9各自独立地 烯基,芳基或杂芳基; R 2至R 8各自独立地为具有20个或更少碳原子的氢原子,卤素原子或取代或未取代的烷基,烷氧基,烯基,酰基,烷氧基羰基,芳烷基,芳基或杂芳基; M是过渡金属。
摘要:
A novel optical recording medium having at least a recording layer and a reflective layer on a substrate is herein disclosed, wherein at least one dipyrromethene metal chelate compound represented by formula (1) is contained in the recording layer: ##STR1## wherein R.sub.1 and R.sub.9 are each independently an alkenyl group, an aryl group or a heteroaryl group; R.sub.2 to R.sub.8 are each independently a hydrogen atom, a halogen atom, or a substituted or unsubstituted alkyl, alkoxy, alkenyl, acyl, alkoxycarbonyl, aralkyl, aryl or heteroaryl group having 20 or less carbon atoms; and M is a transition metal.
摘要翻译:本文公开了一种在基片上至少具有记录层和反射层的新型光学记录介质,其中至少一种由式(1)表示的二吡咯亚甲基金属螯合物包含在记录层中:其中R1和R9各自独立地 烯基,芳基或杂芳基; R 2至R 8各自独立地为具有20个或更少碳原子的氢原子,卤素原子或取代或未取代的烷基,烷氧基,烯基,酰基,烷氧基羰基,芳烷基,芳基或杂芳基; M是过渡金属。
摘要:
An optical recording medium comprising a recording layer, a light interference layer, a reflective layer and a protective layer that are laminated on a substrate, characterized in that said recording layer and said light interference layer comprise at least one organic dye, and that a light absorbent and/or a thermal decomposition promoter are/is added to said light interference layer, wherein the optical recording medium has compatibility that allows good recording and/or reproduction by using lasers of different two wavelength ranges and has good recording properties.
摘要:
This invention provides sulfur-containing (meth)acrylic ester compounds each of which is represented by the following formula (1); wherein R1 and R2 each independently represent a hydrogen atom or an alkyl group or may be fused together to form a ring, R3 represents a hydrogen atom or a methyl group, X1 represents an oxygen atom or a sulfur atom, m stands for an integer of from 0 to 3, and n stands for an integer of from 1 to 4, polymerizable compositions comprising the sulfur-containing (meth)acrylic acids, and cured products and optical parts obtained by polymerizing the polymerizable compositions. The sulfur-containing (meth)acrylic ester compounds according to the present invention are very useful, as monomers for photocurable, polymerizable compositions, in applications such as optical materials and dental materials. The optical parts obtained by curing the polymerizable compositions are excellent in optical properties, thermal properties and mechanical properties and are also good in productivity.
摘要:
A sulfur-containing (thio)ether (co)polymer comprising repetitive structural units represented by general formulas 1 and 2, and an optical element using the (co)polymer: where A and B are bivalent organic group; R1 and R2 are hydrogen or alkyl; X1 to X4 are oxygen or sulfur; Y1 and Y2 are halogen, hydroxy, —OR3 or —SR4, in which R3 is sulfur-containing alkyl, aryl, heterocycle or acyl optionally having a substituent other than SH; and R4 is alkyl, aryl, heterocycle or acyl; provided that —OR3 and/or —SR4 constitute 10 to 100% of the total of Y1+Y2. The (co)polymer exhibits good optical, mechanical and thermal properties and a higher refractive index, and may be prepared in a good productivity. The sulfur-containing (thio)ether (co)polymer is useful for manufacturing a variety of optical elements.