Photosensitizer, visible light curable resin composition using the same,
and use of the composition
    1.
    发明授权
    Photosensitizer, visible light curable resin composition using the same, and use of the composition 失效
    光敏剂,使用其的可见光固化树脂组合物,以及组合物的用途

    公开(公告)号:US06106999A

    公开(公告)日:2000-08-22

    申请号:US131418

    申请日:1998-08-10

    IPC分类号: C08F2/00 G03F7/029 G03C1/105

    摘要: A visible light curable resin composition containing a photocurable resin, a photoreaction initiator and a photosensitizer having the formula (1). The composition has a very high sensitivity to a general-purpose visible light laser, so that a high-speed scanning exposure is possible by the laser, and an extremely fine high resolution can be obtained. In addition, the composition can be used for coating or printing under safelight irradiating conditions and under bright circumstantial conditions without any thickening of the composition, and hence the composition can exert excellent noticeable effects in points of safe operativity, operational efficiency and the stability of products. Formula (1) is as follows: ##STR1## wherein rings X.sub.1 and X.sub.2 are each an optionally substituted pyrrole ring; Y is H, CN, optionally substituted alkyl, aralkyl, aryl, heteroaryl or alkenyl group; and Z.sub.1 and Z.sub.2 are halogen, optionally substituted alkyl, alkoxy, alkylthio, aralkyl, aralkyloxy, aryl, aryloxy, arylthio, heteroaryl, heteroaryloxy or heteroarylthio group, provided that at least one of substituents on the pyrrole rings X.sub.1 and X.sub.2, groups Z.sub.1 and Z.sub.2 is the alkoxy, aralkyloxy or aryloxy group.

    摘要翻译: 一种含有光固化树脂,光反应引发剂和具有式(1)的光敏剂的可见光固化树脂组合物。 该组合物对通用可见光激光器具有非常高的灵敏度,使得可以通过激光进行高速扫描曝光,并且可以获得非常好的高分辨率。 此外,该组合物可以在安全照射条件下和明亮的环境条件下用于涂布或印刷,而不会使组合物变厚,因此组合物可以在安全操作性,操作效率和产品稳定性方面发挥出色的显着效果 。 式(1)如下:其中环X1和X2各自为任选取代的吡咯环; Y是H,CN,任选取代的烷基,芳烷基,芳基,杂芳基或烯基; 并且Z 1和Z 2是卤素,任选取代的烷基,烷氧基,烷硫基,芳烷基,芳烷氧基,芳基,芳氧基,芳硫基,杂芳基,杂芳氧基或杂芳硫基,条件是吡咯环X1和X2上的至少一个取代基, Z2是烷氧基,芳烷氧基或芳氧基。

    Phthalocyanine compounds and optical recording media comprising them
    4.
    发明授权
    Phthalocyanine compounds and optical recording media comprising them 失效
    酞菁化合物和包含它们的光学记录介质

    公开(公告)号:US5693396A

    公开(公告)日:1997-12-02

    申请号:US753173

    申请日:1996-11-20

    摘要: A near infrared light-absorbing dye comprising phthalocyanine compounds represented by the following formula (2): ##STR1## wherein in formula (2), M is two hydrogen atoms, a divalent metallic atom, a trivalent monosubstituted metallic atom, a tetravalent disubstituted metallic atom or an oxymetal atom, and L.sup.1, L.sup.2, L.sup.3 and L.sup.4 are each independently formula (a) or (b), ##STR2## in the formula (a) or (b), R.sup.1 and R.sup.3 are each a substituted or unsubstituted alkyl group, and R.sup.2 is a straight chain or branched halogenated alkyl or alkenyl group having 3 to 10 carbon atoms, X is a chlorine, bromine or iodine atom, and m is an integer of 1 to 12, provided that formula (2) represents a mixture of L.sup.1 =L.sup.2 =L.sup.3 =L.sup.4 =formula (a), L.sup.1 =L.sup.2 =L.sup.4 =formula (a) and L.sup.3 =formula (b), L.sup.1 =L.sup.4 =formula (a) and L.sup.2 =L.sup.3 =formula (b), L.sup.1 =L.sup.3 =formula (a) and L.sup.2 =L.sup.4 =formula (b), L.sup.1 =formula (a) and L.sup.2 =L.sup.3 =L.sup.4 =formula (b), and L.sup.1 =L.sup.2 =L.sup.3 =L.sup.4 =formula (b), and an optical recording medium comprising the phthalocyanine mixture.

    摘要翻译: (2)表示的酞菁化合物的近红外光吸收性染料:其中,在式(2)中,M为2个氢原子,2价金属原子,3价单取代金属原子, 四价二取代金属原子或氧金属原子,L1,L2,L3和L4各自独立地为式(a)或(b),(a)或(b)中的 ),R 1和R 3各自为取代或未取代的烷基,R 2为碳原子数3〜10的直链或支链卤代烷基或烯基,X为氯,溴或碘原子,m为 (2)表示L1 = L2 = L3 = L4 =式(a)的混合,L1 = L2 = L4 =式(a)和L3 =式(b),L1 = L4 =式 (a)和L2 = L3 =公式(b),L1 = L3 =公式(a)和L2 = L4 =公式(b),L1 =公式(a)和L2 = L3 = L4 =公式(b) L1 = L2 = L3 = L4 =式(b),以及包含酞菁混合物的光记录介质。

    Optical recording medium
    5.
    发明授权
    Optical recording medium 失效
    光记录介质

    公开(公告)号:US5672462A

    公开(公告)日:1997-09-30

    申请号:US661071

    申请日:1996-06-10

    摘要: The present invention relates to an optical recording medium having a recording layer, a reflective layer and a protective layer on a substrate, wherein a quinophthalone compound represented by the following formula (1) is contained in the above recording layer. The use of the quinophthalone compound or a mixture of the quinophthalone compound and a photoabsorbing compound having an absorption maximum in a wavelength falling in a range of 550 to 900 nm in the recording layer makes it possible to provide an interchangeable optical recording medium not only capable of recording and reproducing with a laser having a wavelength falling in a range of 480 to 600 nm, but is also capable of recording and reproducing with red lasers having wavelengths of 630 nm and 680 nm and a near infrared laser having a wavelength of 780 nm. ##STR1##

    摘要翻译: 本发明涉及在基板上具有记录层,反射层和保护层的光记录介质,其中在上述记录层中包含由下式(1)表示的喹酞酮化合物。 在记录层中使用喹酞酮化合物或者喹酞酮化合物和吸收光吸收化合物的混合物在波长在550nm至900nm范围内的吸收最大值使得可以提供可互换的光学记录介质,不仅能够 使用波长为480〜600nm的波长的激光进行记录再现,但也能够使用波长为630nm,680nm的红色激光和780nm的近红外激光进行记录再现 。 (1)

    Sulfur compound and use thereof
    9.
    发明授权
    Sulfur compound and use thereof 有权
    硫化合物及其用途

    公开(公告)号:US06570025B1

    公开(公告)日:2003-05-27

    申请号:US10048002

    申请日:2002-01-25

    IPC分类号: C07D33906

    摘要: This invention provides sulfur-containing (meth)acrylic ester compounds each of which is represented by the following formula (1); wherein R1 and R2 each independently represent a hydrogen atom or an alkyl group or may be fused together to form a ring, R3 represents a hydrogen atom or a methyl group, X1 represents an oxygen atom or a sulfur atom, m stands for an integer of from 0 to 3, and n stands for an integer of from 1 to 4, polymerizable compositions comprising the sulfur-containing (meth)acrylic acids, and cured products and optical parts obtained by polymerizing the polymerizable compositions. The sulfur-containing (meth)acrylic ester compounds according to the present invention are very useful, as monomers for photocurable, polymerizable compositions, in applications such as optical materials and dental materials. The optical parts obtained by curing the polymerizable compositions are excellent in optical properties, thermal properties and mechanical properties and are also good in productivity.

    摘要翻译: 本发明提供了各自由下式(1)表示的含硫(甲基)丙烯酸酯化合物,其中R 1和R 2各自独立地表示氢原子或烷基,或者可以一起稠合形成环,R 3 表示氢原子或甲基,X1表示氧原子或硫原子,m表示0〜3的整数,n表示1〜4的整数,包含含硫( 甲基)丙烯酸,以及通过聚合可聚合组合物获得的固化产物和光学部件。 作为本发明的含硫(甲基)丙烯酸酯化合物,作为光固化性聚合性组合物的单体,在光学材料和牙科用材料等应用中是非常有用的。 通过固化可聚合组合物获得的光学部件的光学性能,热性能和机械性能优异,并且生产率也良好。

    Sulfur-containing (thio)ether (co)polymer and a use thereof
    10.
    发明授权
    Sulfur-containing (thio)ether (co)polymer and a use thereof 有权
    含硫(硫)醚(共)聚合物及其用途

    公开(公告)号:US06320020B1

    公开(公告)日:2001-11-20

    申请号:US09389317

    申请日:1999-09-03

    IPC分类号: C08G7560

    摘要: A sulfur-containing (thio)ether (co)polymer comprising repetitive structural units represented by general formulas 1 and 2, and an optical element using the (co)polymer: where A and B are bivalent organic group; R1 and R2 are hydrogen or alkyl; X1 to X4 are oxygen or sulfur; Y1 and Y2 are halogen, hydroxy, —OR3 or —SR4, in which R3 is sulfur-containing alkyl, aryl, heterocycle or acyl optionally having a substituent other than SH; and R4 is alkyl, aryl, heterocycle or acyl; provided that —OR3 and/or —SR4 constitute 10 to 100% of the total of Y1+Y2. The (co)polymer exhibits good optical, mechanical and thermal properties and a higher refractive index, and may be prepared in a good productivity. The sulfur-containing (thio)ether (co)polymer is useful for manufacturing a variety of optical elements.

    摘要翻译: 包含由通式1和2表示的重复结构单元的含硫(硫)醚(共)聚合物和使用(共)聚合物的光学元件:其中A和B是二价有机基团; R1和R2是氢或烷基; X1至X4为氧或硫; Y1和Y2是卤素,羟基,-OR3或-SR4,其中R3是任选具有除SH以外的取代基的含硫烷基,芳基,杂环或酰基; 和R4是烷基,芳基,杂环或酰基; 条件是-OR3和/或-SR4构成Y1 + Y2总数的10〜100%。 (共)聚合物显示出良好的光学,机械和热性能以及更高的折射率,并且可以以良好的生产率制备。 含硫(硫)醚(共)聚合物可用于制造各种光学元件。