摘要:
An electrode binder resin composition containing a polyamic acid, a water-soluble polymer other than the polyamic acid, and a solvent. The use of the electrode binder resin composition improves cyclic characteristics.
摘要:
A method for producing a polyimide film includes: (i) applying a polyamic acid solution composition, which includes at least one of the following solvents: N-methylformamide, N,N-dimethylpropionamide, N,N-dimethylisobutylamide and tetramethylurea, and a polyamic acid, to a substrate; and then (ii) imidizing the polyamic acid by subjecting the composition to heat treatment, to obtain the polyimide film.
摘要:
A polyimide-based binder for power storage device having a repeated breaking energy retention ratio of 70% or more. The use of the binder enables improvement of a power storage device having a high capacity.
摘要:
An electrode for an all-solid secondary battery, including an electrode active material layer comprising an electrode active material and a binder resin on a current collector, the binder resin including a polyimide resin, and the electrode active material layer does not contain an electrolyte; and an all-solid secondary battery, including the electrode as a positive electrode or a negative electrode.
摘要:
Disclosed is a method for producing a polyimide laminate, the method including the steps of applying a polyimide precursor solution onto a substrate and heating the polyimide precursor solution, to thereby form a polyimide film layer on the substrate. The substrate is any plate selected from a glass plate, a metal plate, and a ceramic plate. The heating step includes irradiation with far infrared rays using an infrared heater that generates a maximum radiant energy at an infrared wavelength of 3.5 to 6 μm. The highest heating temperature is preferably 350 to 550° C. The time required to increase the temperature from 180 to 280° C. during a temperature-increasing process is preferably 2 minutes or longer.
摘要:
An electrode is produced by forming an electrode layer on a surface of a current collector using an electrode composition containing a binder including a polyamide acid that is obtained from a specific aromatic tetracarboxylic acid compound and a diamine component containing a diamine having a carboxyl group, and subsequently performing heat treatment to remove a solvent and perform an imidization reaction of the polyamide acid. It is preferable that the electrode composition further contains a crosslinking agent having an epoxy group or an oxazoline group. It is also preferable that the electrode composition further contains a pyridine
摘要:
A power storage device including a negative electrode active material layer which contains carbon particles, silicon-based particles and a polyimide-based binder, in which the negative electrode active material layer has a porosity of more than 40%. The power storage device has a high charge/discharge capacity and excellent cycle characteristics.
摘要:
A method for producing an aqueous polyimide precursor solution composition includes forming a polyamic acid by the reaction of a tetracarboxylic acid component and a diamine component in an aqueous solvent together with an imidazole in an amount of 1.6 mole or more per mole of the tetracarboxylic acid component of the polyamic acid.
摘要:
A binder resin for electrodes consisting of a polyimide-based resin having a melting point of 300° C. or lower, an electrode mixture paste including the binder resin for electrodes, an electrode active material, and a solvent; and an electrode including an electrode mixture layer including the binder resin for electrodes and an electrode active material; and a method for producing the electrode.
摘要:
Provided are a polyimide binder for energy storage device capable of improving properties of an energy storage device in a broad temperature range, and an electrode sheet and an energy storage device using the same. The polyimide binder for energy storage device, which is a polyimide obtained by subjecting an aqueous solution of a polyamic acid composed of a repeating unit represented by the following general formula (I) to an imidization reaction, the polyimide having a tensile elastic modulus of 1.5 GPa or more and 2.7 GPa or less. In the formula, A is a tetravalent group resulting from eliminating a carboxyl group from a specified tetracarboxylic acid, and B is a divalent group resulting from eliminating an amino group from a specified diamine, provided that 55 mol % or more of B in a total amount of the repeating unit is the divalent group resulting from eliminating an amino group from an aliphatic diamine having a molecular weight of 500 or less.