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公开(公告)号：US08704026B1
公开(公告)日：2014-04-22
申请号：US14077331
申请日：2013-11-12
Applicant: UOP LLC
Inventor： Christopher P. Nicholas , Edwin P. Boldingh , Marc R. Schreier
IPC: C07C6/12
Abstract: A new family of aluminosilicate zeolites designated UZM-44 has been synthesized. These zeolites are represented by the empirical formula. NanMmk+TtAl1-xExSiyOz where M represents a metal or metals from zine, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, “m” is the mole ratio of M to (Al+E), T is the organic structure directing agent or agents, and E is a framework element such as gallium. UZM-44 may be used to catalyze a process for the transalkylation of a feedstream comprising one or more of C7, C9, C10 and C11+ aromatics to obtain a transalkylation product stream having an increased concentration of C8 aromatics relative to that of the feedstream.
Abstract translation: 已经合成了一系列名为UZM-44的硅铝酸盐沸石。 这些沸石由经验公式表示。 NanMmk + TtAl1-xExSiyOz其中M表示金属或来自ine族，第1族，第2族，第3族和/或元素周期表的镧系元素的金属，“m”是M与（Al + E）的摩尔比，T 是有机结构导向剂或试剂，E是诸如镓的骨架元素。 UZM-44可用于催化包含C 7，C 9，C 10和C 11+芳族化合物中的一种或多种的进料流的烷基转移的方法，以获得相对于进料流的C 8芳族化合物浓度增加的烷基转移产物流。
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Patent Agency Ranking
公开(公告)号：US20140163286A1
公开(公告)日：2014-06-12
申请号：US14077352
申请日：2013-11-12
Applicant: UOP LLC
Inventor： Christopher P. Nicholas , Edwin P. Boldingh , Marc R. Schreier
IPC: C07C6/06
CPC classification number: C07C6/06 , B01J29/70 , B01J29/78 , B01J29/80 , B01J2229/20 , B01J2229/42 , C01B39/46 , C01B39/48 , C07C6/126 , C07C2529/70 , Y02P20/52 , C07C15/08
Abstract: A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and shown to be effective catalysts for aromatic transalkylation reactions. These zeolites are represented by the empirical formula. NanMmk+TtAl1-xExSiyOz where M represents a metal or metals from zinc or Group 1 (IUPAC 1), Group 2 (IUPAC 2), Group 3 (IUPAC 3) or the lanthanide series of the periodic table, T is the organic directing agent derived from reactants R and Q where R is an A,Ω-dihalosubstituted alkane such as 1,4-dibromobutane and Q is at least one neutral amine having 6 or fewer carbon atoms such as 1-methylpyrrolidine. E is a framework element such as gallium. The process involves transalkylation of a feedstream comprising one or more of C7, C9, C10 and C11+ aromatics to obtain a transalkylation product stream having an increased concentration of C8 aromatics relative to that of the feedstream.
Abstract translation: 已经合成了一系列TUN和IMF染色体类型的相干生长复合材料，并被证明是芳族烷基转移反应的有效催化剂。 这些沸石由经验公式表示。 NanMmk + TtAl1-xExSiyOz其中M表示来自锌或组1（IUPAC 1），组2（IUPAC 2），组3（IUPAC 3）或周期表的镧系元素的金属或金属，T是有机导向剂 衍生自反应物R和Q，其中R是A，OHG-二卤代烷烃如1,4-二溴丁烷和Q是至少一种具有6个或更少碳原子的中性胺如1-甲基吡咯烷。 E是诸如镓的骨架元素。 该方法涉及包含C 7，C 9，C 10和C 11+芳族化合物中的一种或多种的进料流的烷基转移，以获得相对于进料流的C 8芳族化合物浓度增加的烷基转移产物流。
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公开(公告)号：US08841502B2
公开(公告)日：2014-09-23
申请号：US14077352
申请日：2013-11-12
Applicant: Uop LLC
Inventor： Christopher P. Nicholas , Edwin P. Boldingh , Marc R. Schreier
CPC classification number: C07C6/06 , B01J29/70 , B01J29/78 , B01J29/80 , B01J2229/20 , B01J2229/42 , C01B39/46 , C01B39/48 , C07C6/126 , C07C2529/70 , Y02P20/52 , C07C15/08
Abstract: A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and shown to be effective catalysts for aromatic transalkylation reactions. These zeolites are represented by the empirical formula. NanMmk+TtAl1-xExSiyOz where M represents a metal or metals from zinc or Group 1 (IUPAC 1), Group 2 (IUPAC 2), Group 3 (IUPAC 3) or the lanthanide series of the periodic table, T is the organic directing agent derived from reactants R and Q where R is an A,Ω-dihalosubstituted alkane such as 1,4-dibromobutane and Q is at least one neutral amine having 6 or fewer carbon atoms such as 1-methylpyrrolidine. E is a framework element such as gallium. The process involves transalkylation of a feedstream comprising one or more of C7, C9, C10 and C11+ aromatics to obtain a transalkylation product stream having an increased concentration of C8 aromatics relative to that of the feedstream.
Abstract translation: 已经合成了一系列TUN和IMF染色体类型的相干生长复合材料，并被证明是芳族烷基转移反应的有效催化剂。 这些沸石由经验公式表示。 NanMmk + TtAl1-xExSiyOz其中M表示来自锌或组1（IUPAC 1），组2（IUPAC 2），组3（IUPAC 3）或周期表的镧系元素的金属或金属，T是有机导向剂 衍生自反应物R和Q，其中R是A，OHG-二卤代烷烃如1,4-二溴丁烷和Q是至少一种具有6个或更少碳原子的中性胺如1-甲基吡咯烷。 E是诸如镓的骨架元素。 该方法涉及包含C 7，C 9，C 10和C 11+芳族化合物中的一种或多种的进料流的烷基转移，以获得相对于进料流的C 8芳族化合物浓度增加的烷基转移产物流。
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公开(公告)号：US20140100403A1
公开(公告)日：2014-04-10
申请号：US13645998
申请日：2012-10-05
Applicant: UOP LLC
Inventor： Naiyl A. Rashid , Edwin P. Boldingh , Raymond Shih , Marc R. Schreier , David S. Lafyatis
CPC classification number: C07C6/126 , B01J29/185 , B01J29/20 , B01J29/26 , B01J29/40 , B01J29/7049 , B01J29/72 , B01J29/80 , B01J37/20 , B01J37/28 , B01J2229/42 , C07C2529/18 , C07C2529/70 , Y02P20/52 , C07C15/08
Abstract: A process for transalkylation is described. The process operates at a lower pressure than a typical transalkylation processes, and provides higher benzene purity with comparable or lower ring loss compared to the typical transalkylation process. The xylene selectivity is comparable to or higher than the standard process, and the ethyl benzene selectivity is comparable to or lower than the standard process.
Abstract translation: 描述了烷基转移的方法。 该方法在比典型的烷基转移方法更低的压力下操作，并且与典型的烷基转移方法相比，提供较高的苯纯度，具有相当或更低的环损失。 二甲苯选择性与标准方法相当或更高，乙苯选择性与标准方法相当或低于标准方法。
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公开(公告)号：US08618343B1
公开(公告)日：2013-12-31
申请号：US13792610
申请日：2013-03-11
Applicant: UOP LLC
Inventor： Christopher P. Nicholas , Edwin P. Boldingh , Marc R. Schreier
IPC: C07C6/12
CPC classification number: C07C6/06 , B01J29/70 , B01J29/78 , B01J29/80 , B01J2229/20 , B01J2229/42 , C01B39/46 , C01B39/48 , C07C6/126 , C07C2529/70 , Y02P20/52 , C07C15/08
Abstract: A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and shown to be effective catalysts for aromatic transalkylation reactions. These zeolites are represented by the empirical formula. NanMmk+TtAl1-xExSiyOz where M represents a metal or metals from zinc or Group 1 (IUPAC 1), Group 2 (IUPAC 2), Group 3 (IUPAC 3) or the lanthanide series of the periodic table, T is the organic directing agent derived from reactants R and Q where R is an A,Ω-dihalosubstituted alkane such as 1,4-dibromobutane and Q is at least one neutral amine having 6 or fewer carbon atoms such as 1-methylpyrrolidine. E is a framework element such as gallium. The process involves transalkylation of a feedstream comprising one or more of C7, C9, C10 and C11+ aromatics to obtain a transalkylation product stream having an increased concentration of C8 aromatics relative to that of the feedstream.
Abstract translation: 已经合成了一系列TUN和IMF染色体类型的相干生长复合材料，并被证明是芳族烷基转移反应的有效催化剂。 这些沸石由经验公式表示。 NanMmk + TtAl1-xExSiyOz其中M表示来自锌或组1（IUPAC 1），组2（IUPAC 2），组3（IUPAC 3）或周期表的镧系元素的金属或金属，T是有机导向剂 衍生自反应物R和Q，其中R是A，ω-二卤代烷烃如1,4-二溴丁烷和Q是至少一种具有6个或更少碳原子的中性胺如1-甲基吡咯烷。 E是诸如镓的骨架元素。 该方法涉及包含C 7，C 9，C 10和C 11+芳族化合物中的一种或多种的进料流的烷基转移，以获得相对于进料流的C 8芳族化合物浓度增加的烷基转移产物流。
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公开(公告)号：US08609921B1
公开(公告)日：2013-12-17
申请号：US13792667
申请日：2013-03-11
Applicant: UOP LLC
Inventor： Christopher P. Nicholas , Edwin P. Boldingh , Marc R. Schreier
IPC: C07C6/12
Abstract: A new family of aluminosilicate zeolites designated UZM-44 has been synthesized. These zeolites are represented by the empirical formula. NanMmk+TtAl1-xExSiyOz where M represents a metal or metals from zine, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, “m” is the mole ratio of M to (Al+E), T is the organic structure directing agent or agents, and E is a framework element such as gallium. UZM-44 may be used to catalyze a process for the transalkylation of a feedstream comprising one or more of C7, C9, C10 and C11+ aromatics to obtain a transalkylation product stream having an increased concentration of C8 aromatics relative to that of the feedstream.
Abstract translation: 已经合成了一系列名为UZM-44的硅铝酸盐沸石。 这些沸石由经验公式表示。 NanMmk + TtAl1-xExSiyOz其中M表示金属或来自ine族，第1族，第2族，第3族和/或元素周期表的镧系元素的金属，“m”是M与（Al + E）的摩尔比，T 是有机结构导向剂或试剂，E是诸如镓的骨架元素。 UZM-44可用于催化包含C 7，C 9，C 10和C 11+芳族化合物中的一种或多种的进料流的烷基转移的方法，以获得相对于进料流的C 8芳族化合物浓度增加的烷基转移产物流。
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