公开(公告)号：US3702232A

公开(公告)日：1972-11-07

申请号：US3702232D

申请日：1971-11-19

申请人： US AGRICULTURE

发明人： ROBERTS EARL J ,  BRANNAN MARY ANN F ,  ROWLAND STANLEY P

IPC分类号： C07F9/22 ,  D06M13/292 ,  D06M13/26 ,  D06M13/40 ,  D06M13/44

CPC分类号： C07F9/224 ,  D06M13/292

摘要： TRIS(2-CHLOROETHYL)PHOSPHORAMIDE WAS PREPARED FROM ETHYLENEIMINE AND PHOSPHORUS OXYCHLORIDE AND REACTED WITH COTTON CELLULOSE IN THE FORM OF FABRIC BY A PAD-DRYCURE PROCESS IN THE PRESENCE OF A BASIC SALT, SUCH AS SODIUM CARBONATE. REAGENT INCORPORATION LEVELS UP TO 6% BY WEIGHT WERE ACHIEVED. COTTON FABRICS MODIFIED WITH TRIS(2-CHLOROETHYL)PHOSPHORAMIDE WERE FOUND TO HAVE ENHANCED WRINKLE RECOVERY PROPERTIES.

摘要翻译： 由乙烯亚胺和三氯氧磷制备三（2-氯乙基）磷酰胺，并在碱性盐如碳酸钠存在下通过垫干固化法与织物形式的棉纤维素反应。 试剂合并达到了6％（重量）。 发现用三（2-氯乙基）磷酰胺改性的棉织物具有增强的皱纹恢复性能。

公开(公告)号：US3647352A

公开(公告)日：1972-03-07

申请号：US3647352D

申请日：1971-02-17

申请人： US AGRICULTURE

发明人： ROBERTS EARL J ,  ROWLAND STANLEY P ,  BRANNAN MARY ANN F

IPC分类号： D06M13/256 ,  D06M13/368 ,  D06M13/36 ,  D06M13/38

CPC分类号： D06M13/368 ,  D06M13/256

摘要： N-methylbis(2-sulfatoethyl)amine and the monosodium salt of this new compound have been prepared and applied to cotton to impart crease-resistant characteristics to the fabrics. N-methylbis(2chloroethyl)amine, a related known compound, was also reacted with the fibrous cellulose. Respectively, a pad-cure process was employed on the one and a pad wet-cure process was employed on the other to produce cross-linked cellulosic derivatives.

摘要翻译： 已经制备了N-甲基双（2-硫酸基乙基）胺和这种新化合物的单钠盐并将其应用于棉织物以赋予织物抗皱特性。 相关已知化合物的N-甲基双（2-氯乙基）胺也与纤维状纤维素反应。 分别使用垫固化方法，另一方面采用垫湿固化方法来生产交联的纤维素衍生物。

公开(公告)号：US3885069A

公开(公告)日：1975-05-20

申请号：US27991972

申请日：1972-08-11

申请人： US AGRICULTURE

发明人： ROBERTS EARL J ,  ROWLAND STANLEY P

IPC分类号： B01J20/22 ,  B01J39/22 ,  C02F1/28 ,  D06M13/487 ,  D06M15/61 ,  C02B1/46 ,  D06M13/48 ,  D06M15/12

CPC分类号： D06M13/487 ,  B01J20/22 ,  B01J39/22 ,  C02F1/288 ,  D06M15/61

摘要： Cotton and other fibrous material is impregnated with ethylenimine prepolymer prepared by reacting ethylenimine and certain di- and polyfunctional alkyl or aryl halide to produce an insoluble in situ formed network polymer which is physically bound in the structure of the substrate used. This new material is an excellent scavenger of heavy metals in water. This material can be prepared to be simultaneously low in ion-exchange capacity while being high in capacity for complexing with heavy metals.

摘要翻译： 用乙烯亚胺和某些二官能和多官能烷基或芳基卤反应制备的乙烯亚胺预聚物浸渍棉和其它纤维材料，以产生物理结合在所用基材结构中的不溶性原位形成的网状聚合物。 这种新材料是水中重金属的优良清除剂。 该材料可以制备成同时具有低离子交换能力，同时与重金属络合的能力高。

公开(公告)号：US3884972A

公开(公告)日：1975-05-20

申请号：US4955170

申请日：1970-06-24

申请人： US AGRICULTURE

发明人： ROBERTS EARL J ,  BRANNAN MARY ANN F ,  ROWLAND STANLEY P

IPC分类号： C07F9/22 ,  D06M13/292

CPC分类号： C07F9/224 ,  D06M13/292

摘要： Tris(2-chloroethyl)phosphoramide was prepared from ethylenimine and phosphorus oxychloride and reacted with cotton cellulose in the form of fabric by a pad-dry-cure process in the presence of a basic salt, such as sodium carbonate. Reagent incorporation levels up to 6 percent by weight were achieved. Cotton fabrics modified with tris(2-chloroethyl)phosphoramide were found to have enhanced wrinkle recovery properties.

公开(公告)号：US2481557A

公开(公告)日：1949-09-13

申请号：US72644847

申请日：1947-02-04

申请人： US AGRICULTURE

发明人： AMBLER JOSEPH A ,  ROBERTS EARL J

IPC分类号： C07C51/487

CPC分类号： C07C51/487 ,  C07C57/02

公开(公告)号：US2448831A

公开(公告)日：1948-09-07

申请号：US69602246

申请日：1946-09-10

申请人： US AGRICULTURE

发明人： ROBERTS EARL J ,  AMBLER JOSEPH A ,  LAURENCE CURI ALFRED

IPC分类号： C07C51/38

CPC分类号： C07C51/38 ,  C07C57/13