公开(公告)号：US20060247377A1

公开(公告)日：2006-11-02

申请号：US10558996

申请日：2004-06-04

申请人： Ulrich Riegel ,  Thomas Daniel ,  Matthias Weismantel ,  Mark Elliott ,  Rudiger Funk ,  Reinhold Schwalm

发明人： Ulrich Riegel ,  Thomas Daniel ,  Matthias Weismantel ,  Mark Elliott ,  Rudiger Funk ,  Reinhold Schwalm

IPC分类号： C08L67/02 ,  C07C67/26

CPC分类号： C07C69/54 ,  C07C67/08

摘要： The present invention relates to novel (meth)acrylic esters of polyalkoxylated glycols of the formula where AO is independently at each instance is —O—CHR3-CHR4- or —CHR3-CHR4-O— where R3 and R4 are independently H, linear or branched C1-C8-alkyl, p1 is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, or 35, p2 is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, or 35, n is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 447, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 86, 87, 88, 89, 90, 91, 92, 93, 94, 95, 96, 97, 98, 99, 100, R1 and R2 are independently H or CH3, wherein there is at least one AO in (AO)p1 and also at least one AO in (AO)p2 where R3 and R4 are not both H at one and the same time, a simplified process for preparing these esters and use of reaction mixtures thus obtainable.

摘要翻译： 本发明涉及下式的聚烷氧基化二醇的（甲基）丙烯酸酯：其中AO各自独立地为-O-CHR 3 -CHR 4 - 或-CHR 3 -CHR 4 -O-，其中R 3和R 4独立地为H，直链或 支链C 1 -C 8 - 烷基，p 1为1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21 ，22,23,24,25,26,27,28,29,30,31,32,33,34或35中，p2分别为1,2,3,4,5,6,7,8,9,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34或35， 10，11，12，13，14，15，16，17，18，19，20，21，22，23，24，25，26，27，28，29，30，31，32，33，34， 或35，n为1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23 ，24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,447,48 ，49，50，51，52，53，54，55，56，57，58，59，60，61，62，63，64，65，66，67，68，69，70，，71，72，73 ，74，75，76，77，78，79，80，81，82，83，84，85，86，87，88，89，90，91，92，93，94，95，96，97，98 ，99,100，R 1和R 2独立地为H或CH 3，其中存在至少一个AO （AO）p 1和（AO）p2中的至少一个AO，其中R3和R4不同时为一个，制备这些酯的简化方法和使用由此获得的反应混合物。

公开(公告)号：US07405321B2

公开(公告)日：2008-07-29

申请号：US10558996

申请日：2004-06-04

申请人： Ulrich Riegel ,  Thomas Daniel ,  Matthias Weismantel ,  Mark Elliott ,  Rudiger Funk ,  Reinhold Schwalm

发明人： Ulrich Riegel ,  Thomas Daniel ,  Matthias Weismantel ,  Mark Elliott ,  Rudiger Funk ,  Reinhold Schwalm

IPC分类号： C07C69/52 ,  C08F20/10 ,  C08F220/12

CPC分类号： C07C69/54 ,  C07C67/08

摘要： The present invention relates to novel (meth)acrylic esters of polyalkoxylated glycols of the formula where AO is independently at each instance is —O—CHR3-CHR4- or —CHR3-CHR4-O— where R3 and R4 are independently H, linear or branched C1-C8-alkyl, p1 is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, or 35, p2 is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, or 35, n is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 447, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 86, 87, 88, 89, 90, 91, 92, 93, 94, 95, 96, 97, 98, 99, 100, R1 and R2 are independently H or CH3, wherein there is at least one AO in (AO)p1 and also at least one AO in (AO)p2 where R3 and R4 are not both H at one and the same time, a simplified process for preparing these esters and use of reaction mixtures thus obtainable.

摘要翻译： 本发明涉及下式的聚烷氧基化二醇的（甲基）丙烯酸酯：其中AO各自独立地为-O-CHR 3 -CHR 4 - 或-CHR 3 -CHR 4 -O-，其中R 3和R 4独立地为H，直链或 支链C 1 -C 8 - 烷基，p 1为1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21 ，22,23,24,25,26,27,28,29,30,31,32,33,34或35中，p2分别为1,2,3,4,5,6,7,8,9,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34或35， 10，11，12，13，14，15，16，17，18，19，20，21，22，23，24，25，26，27，28，29，30，31，32，33，34， 或35，n为1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23 ，24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,447,48 ，49，50，51，52，53，54，55，56，57，58，59，60，61，62，63，64，65，66，67，68，69，70，，71，72，73 ，74，75，76，77，78，79，80，81，82，83，84，85，86，87，88，89，90，91，92，93，94，95，96，97，98 ，99,100，R 1和R 2独立地为H或CH 3，其中存在至少一个AO （AO）p1和（AO）p2中的至少一个AO，其中R3和R4不同时为一个，一个简单的制备这些酯的方法和使用如此获得的反应混合物。

公开(公告)号：US20050215752A1

公开(公告)日：2005-09-29

申请号：US10517042

申请日：2003-06-06

申请人： Andreas Popp ,  Thomas Daniel ,  Jurgen Schroder ,  Thomas Jaworek ,  Rudiger Funk ,  Reinhold Schwalm ,  Matthias Weismantel ,  Ulrich Riegel

发明人： Andreas Popp ,  Thomas Daniel ,  Jurgen Schroder ,  Thomas Jaworek ,  Rudiger Funk ,  Reinhold Schwalm ,  Matthias Weismantel ,  Ulrich Riegel

IPC分类号： C08G65/332 ,  A61L15/60 ,  C07B61/00 ,  C07C67/08 ,  C07C69/54 ,  C08F290/06 ,  C08G65/26 ,  C08G65/28 ,  C08G63/02

CPC分类号： C08G65/3322 ,  A61L15/60 ,  C07C67/08 ,  C08G65/2609 ,  Y10T428/249921 ,  C07C69/54

摘要： The present invention relates to novel (meth)acrylic esters of polyalkoxylated trimethylolpropane of the formula where AO is for each AO independently at each instance EO, PO or BO where EO is O—CH2-CH2- PO is independently at each instance O—CH2-CH(CH3)- or O—CH(CH3)-CH2- BO is independently at each instance O—CH2-CH(CH2-CH3)- or O—CH(CH2-CH3)-CH2- p1+p2+p3 is 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74 or 75, R1, R2 and R3 are independently H or CH3, a simplified process for preparing these esters and the use of reaction mixtures thus obtainable.

摘要翻译： 本发明涉及下式的聚烷氧基化三羟甲基丙烷的新的（甲基）丙烯酸酯：其中AO各自独立地为每个AO，PO或BO，其中EO为O-CH 2 -CH 2 - ，PO各自独立地为O-CH 2 -CH（CH 3） - 或O-CH（CH 3）-CH 2 - BO在每种情况下独立地为O-CH 2 -CH（CH 2 -CH 3） - 或O-CH（CH 2 -CH 3）-CH 2 - ，p 1 + p 2 + p 3 是28，29，30，31，32，33，34，35，36，37，38，39，40，41，42，43，44，45，46，47，48，49，50，51，52 ，53,54,55,66,57,58,59,60,61,62,63,64,65,66,67,68,69,70,71,72,73,74或75，R1，R2 和R3独立地为H或CH3，制备这些酯的简化方法以及由此得到的反应混合物的使用。

公开(公告)号：US20050165208A1

公开(公告)日：2005-07-28

申请号：US10516702

申请日：2003-06-10

申请人： Andreas Popp ,  Thomas Daniel ,  Jurgen Schroder ,  Thomas Kaworek ,  Rudiger Funk ,  Reinhold Schwalm ,  Matthias Weismantel ,  Ulrich Riegel

发明人： Andreas Popp ,  Thomas Daniel ,  Jurgen Schroder ,  Thomas Kaworek ,  Rudiger Funk ,  Reinhold Schwalm ,  Matthias Weismantel ,  Ulrich Riegel

IPC分类号： A61L15/60 ,  C07B61/00 ,  C07C67/08 ,  C07C67/62 ,  C07C69/54 ,  C08F20/20 ,  C08G65/26 ,  C08G65/332 ,  C08G63/66

CPC分类号： C08G65/3322 ,  A61L15/60 ,  C07C67/08 ,  C08G65/2609 ,  C08G2650/58 ,  C07C69/54

摘要： The present invention relates to novel (meth)acrylic esters of polyalkoxylated glycerol, a simplified process for preparing these esters and the use of reaction mixtures thus obtainable.

摘要翻译： 本发明涉及聚烷氧基化甘油的新型（甲基）丙烯酸酯，制备这些酯的简化方法以及由此得到的反应混合物的用途。

公开(公告)号：US07259212B2

公开(公告)日：2007-08-21

申请号：US10516698

申请日：2003-06-10

申请人： Andreas Popp ,  Thomas Daniel ,  Jürgen Schröder ,  Thomas Jaworek ,  Rüdiger Funk ,  Reinhold Schwalm ,  Matthias Weismantel ,  Ulrich Riegel

发明人： Andreas Popp ,  Thomas Daniel ,  Jürgen Schröder ,  Thomas Jaworek ,  Rüdiger Funk ,  Reinhold Schwalm ,  Matthias Weismantel ,  Ulrich Riegel

IPC分类号： C08F2/02 ,  C08F2/62 ,  C08F1/02 ,  C08F1/62

CPC分类号： C08G65/3322 ,  A61L15/60 ,  C07C67/08 ,  C08G65/2609 ,  C07C69/54

摘要： The present invention relates to novel (meth)acrylic esters of polyalkoxylated trimethylolpropane of the formula where EO is O—CH2-CH2- PO is independently at each instance O—CH2-CH(CH3)- or O—CH(CH3)-CH2- n1, n2 and n3 are independently 4, 5 or 6, n1+n2+n3 is 14, 15 or 16, m1, m2 and m3 are independently 1, 2 or 3, m1+m2+m3 is 4, 5 or 6, R1, R2 and R3 are independently H or CH3, a simplified process for preparing these esters and the use of reaction mixtures thus obtainable.

摘要翻译： 本发明涉及下式的聚烷氧基化三羟甲基丙烷的新型（甲基）丙烯酸酯：其中EO为O-CH 2 -CH 2 - ，PO各自独立地为O-CH 2 -CH（CH 3） - 或O-CH（CH 3）-CH 2 - n1，n2和n3分别为4,5或6，n1 + n2 + n3为14,15或16，m1，m2和m3分别为1,2或3，m1 + m2 + m3为4,5或6 ，R 1，R 2和R 3独立地为H或CH 3，制备这些酯的简化方法以及由此得到的反应混合物的用途。

公开(公告)号：US20060020078A1

公开(公告)日：2006-01-26

申请号：US10516698

申请日：2003-06-10

申请人： Andreas Popp ,  Thomas Daniel ,  Jurgen Schroder ,  Thomas Jaworek ,  Rudiger Funk ,  Reinhold Schwalm ,  Matthias Wesimantel ,  Ulrich Riegel

发明人： Andreas Popp ,  Thomas Daniel ,  Jurgen Schroder ,  Thomas Jaworek ,  Rudiger Funk ,  Reinhold Schwalm ,  Matthias Wesimantel ,  Ulrich Riegel

IPC分类号： C08L33/00 ,  C07C69/52

CPC分类号： C08G65/3322 ,  A61L15/60 ,  C07C67/08 ,  C08G65/2609 ,  C07C69/54

摘要： The present invention relates to novel (meth)acrylic esters of polyalkoxylated trimethylolpropane of the formula where EO is O—CH2-CH2- PO is independently at each instance O—CH2-CH(CH3)- or O—CH(CH3)-CH2- n1, n2 and n3 are independently 4, 5 or 6, n1+n2+n3 is 14, 15 or 16, m1, m2 and m3 are independently 1, 2 or 3, m1+m2+m3 is 4, 5 or 6, R1, R2 and R3 are independently H or CH3, a simplified process for preparing these esters and the use of reaction mixtures thus obtainable.

摘要翻译： 本发明涉及下式的聚烷氧基化三羟甲基丙烷的新型（甲基）丙烯酸酯：其中EO为O-CH 2 -CH 2 - ，PO各自独立地为O-CH 2 -CH（CH 3） - 或O-CH（CH 3）-CH 2 - n1，n2和n3分别为4,5或6，n1 + n2 + n3为14,15或16，m1，m2和m3分别为1,2或3，m1 + m2 + m3为4,5或6 ，R 1，R 2和R 3独立地为H或CH 3，制备这些酯的简化方法以及由此得到的反应混合物的用途。

公开(公告)号：US07199211B2

公开(公告)日：2007-04-03

申请号：US10517042

申请日：2003-06-06

申请人： Andreas Popp ,  Thomas Daniel ,  Jürgen Schröder ,  Thomas Jaworek ,  Rüdiger Funk ,  Reinhold Schwalm ,  Matthias Weismantel ,  Ulrich Riegel

发明人： Andreas Popp ,  Thomas Daniel ,  Jürgen Schröder ,  Thomas Jaworek ,  Rüdiger Funk ,  Reinhold Schwalm ,  Matthias Weismantel ,  Ulrich Riegel

IPC分类号： C08G63/78 ,  C08G63/82

CPC分类号： C08G65/3322 ,  A61L15/60 ,  C07C67/08 ,  C08G65/2609 ,  Y10T428/249921 ,  C07C69/54

摘要： The present invention relates to novel (meth)acrylic esters of polyalkoxylated trimethylolpropane of the formula where AO is for each AO independently at each instance EO, PO or BO where EO is O—CH2-CH2- PO is independently at each instance O—CH2-CH(CH3)- or O—CH(CH3)-CH2- BO is independently at each instance O—CH2-CH(CH2-CH3)- or O—CH(CH2-CH3)-CH2- p1+p2+p3 is 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74 or 75, R1, R2 and R3 are independently H or CH3, a simplified process for preparing these esters and the use of reaction mixtures thus obtainable.

摘要翻译： 本发明涉及下式的聚烷氧基化三羟甲基丙烷的新型（甲基）丙烯酸酯

公开(公告)号：US20060235141A1

公开(公告)日：2006-10-19

申请号：US10551605

申请日：2004-03-30

申请人： Ulrich Riegel ,  Thomas Daniel ,  Dieter Hermeling ,  Mark Elliott ,  Reinhold Schwalm

发明人： Ulrich Riegel ,  Thomas Daniel ,  Dieter Hermeling ,  Mark Elliott ,  Reinhold Schwalm

IPC分类号： C09D5/02

CPC分类号： C09D5/02 ,  C08G65/2609 ,  C08G65/3322

摘要： A mixture of at least two compounds each having at least two double bonds, said mixture having a WFR from 200 to 600 g/mol of double bond and at least two of said compounds each comprising at least two (meth)acrylic esters as double bond component, WFR being given by: ∑ i = 1 n ⁢ α i ⨯ MW i / Z i = WFR ⁢   ⁢ where ∑ i = 1 n ⁢ α i = 1 αi is equal to the molar fraction of compound (i) in said mixture, n is equal to the number of compounds in said mixture and n is ≧2, Zi is equal to the number of double bonds in said compound (i), MWi is equal to the molecular weight of said compound (i).

公开(公告)号：US07772420B2

公开(公告)日：2010-08-10

申请号：US10562239

申请日：2004-06-30

申请人： Dieter Hermeling ,  Thomas Daniel ,  Mark Elliott ,  Ulrich Riegel ,  Frank Dietsche ,  Reinhold Schwalm

发明人： Dieter Hermeling ,  Thomas Daniel ,  Mark Elliott ,  Ulrich Riegel ,  Frank Dietsche ,  Reinhold Schwalm

IPC分类号： C07C69/33 ,  C07C69/54 ,  C08G63/52 ,  C08G63/02 ,  C08G18/62

CPC分类号： C08G65/332 ,  A61L15/60 ,  C08G65/2606 ,  C08G65/3322 ,  Y10S524/916

摘要： Disclosed are novel (meth)acrylic esters of monoalkoxylated polyols, a process for their preparation and their use for preparing crosslinked swellable hydrogel-forming polymers and crosslinked swellable hydrogel-forming polymers.

摘要翻译： 公开了单烷氧基化多元醇的新型（甲基）丙烯酸酯，其制备方法及其用于制备交联的可溶胀水凝胶形成聚合物和交联的可膨胀的水凝胶形成聚合物。

公开(公告)号：US07652111B2

公开(公告)日：2010-01-26

申请号：US10576892

申请日：2004-11-18

申请人： Dieter Hermeling ,  Thomas Daniel ,  Mark Elliott ,  Ulrich Riegel ,  Frank Dietsche ,  Reinhold Schwalm

发明人： Dieter Hermeling ,  Thomas Daniel ,  Mark Elliott ,  Ulrich Riegel ,  Frank Dietsche ,  Reinhold Schwalm

IPC分类号： C08F118/02 ,  C07C229/02

CPC分类号： C08F220/14 ,  C07C219/08 ,  C08F20/40 ,  C08F226/02 ,  C08F226/04

摘要： Disclosed are novel (meth)acrylic esters of unsaturated amino alcohols, a process for their preparation and their use for preparing crosslinked swellable hydrogel-forming polymers and crosslinked swellable hydrogel-forming polymers.

摘要翻译： 公开了不饱和氨基醇的新型（甲基）丙烯酸酯，其制备方法及其用于制备交联的可溶胀水凝胶形成聚合物和交联的可膨胀的水凝胶形成聚合物。