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1.发明申请Novel Anionic Polyalkoxy Group Comprising Surfactants on Basis of Guerbet-Alcohols, Method of Manufacture and Use in Enhanced Oil Recovery (EOR) Applications 有权新型阴离子聚烷氧基，其基于乙烯醇的表面活性剂，在增强采油（EOR）应用中的制造和使用方法公开(公告)号：US20110281779A1
公开(公告)日：2011-11-17
申请号：US13085248
申请日：2011-04-12
申请人： Upali P. Weerasooriya , Gary A. Pope , Christian Bittner , Gunter Oetter , Jack F. Tinsley , Christian Spindler , Gabriela Alvarez Jurgenson , Sophie Maitro-Vogel
发明人： Upali P. Weerasooriya , Gary A. Pope , Christian Bittner , Gunter Oetter , Jack F. Tinsley , Christian Spindler , Gabriela Alvarez Jurgenson , Sophie Maitro-Vogel
IPC分类号： C09K8/584 , C07C303/04 , C07C309/10
CPC分类号： C09K8/584 , C07C305/10 , C07C309/10 , C08G65/2609 , C08G65/3344 , E21B43/16
摘要： Compositions and methods of synthesis of anionic surfactants by alkoxylation of a Guerbet alcohol (GA) having 12 to 36 carbon atoms using butylene oxide, and optionally propylene oxide and/or ethylene oxide followed by the incorporation of a terminal anionic group are described herein. The GA of the present invention is made by a facile and inexpensive method that involves high temperature base catalyzed dimerization of alcohols with 6 to 18 carbon atoms. The large hydrophobe ether surfactants of the present invention find uses in enhanced oil recovery (EOR) applications where it is used for solubilization and mobilization of oil and for environmental cleanup. Further, the hydrophobe alkoxylated GA without anionic terminal group can be used as an ultra-high molecular weight non-ionic surfactant.
摘要翻译： 本文描述了通过使用环氧丁烷和任选的环氧丙烷和/或环氧乙烷烷氧基化具有12至36个碳原子的格伯特醇（GA），然后引入末端阴离子基团来合成阴离子表面活性剂的组合物和方法。 本发明的GA通过易于且廉价的方法制备，其涉及具有6至18个碳原子的醇的高温碱催化二聚。 本发明的大型疏水醚表面活性剂用于增强采油（EOR）应用中，其用于溶解和动员油并用于环境清洁。 此外，不含阴离子末端基团的疏水基烷氧基化GA可用作超高分子量非离子表面活性剂。
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2.发明授权Anionic polyalkoxy group comprising surfactants on basis of guerbet-alcohols, method of manufacture and use in enhanced oil recovery (EOR) applications 有权基于优尔特 - 醇的基于表面活性剂的阴离子聚烷氧基，制备方法和用于增强采油（EOR）应用中公开(公告)号：US08841241B2
公开(公告)日：2014-09-23
申请号：US13085248
申请日：2011-04-12
申请人： Upali P. Weerasooriya , Gary A. Pope , Christian Bittner , Guenter Oetter , Jack F. Tinsley , Christian Spindler , Gabriela Alvarez-Jurgenson , Sophie Maitro-Vogel
发明人： Upali P. Weerasooriya , Gary A. Pope , Christian Bittner , Guenter Oetter , Jack F. Tinsley , Christian Spindler , Gabriela Alvarez-Jurgenson , Sophie Maitro-Vogel
CPC分类号： C09K8/584 , C07C305/10 , C07C309/10 , C08G65/2609 , C08G65/3344 , E21B43/16
摘要： Compositions and methods of synthesis of anionic surfactants by alkoxylation of a Guerbet alcohol (GA) having 12 to 36 carbon atoms using butylene oxide, and optionally propylene oxide and/or ethylene oxide followed by the incorporation of a terminal anionic group are described herein. The GA of the present invention is made by a facile and inexpensive method that involves high temperature base catalyzed dimerization of alcohols with 6 to 18 carbon atoms. The large hydrophobe ether surfactants of the present invention find uses in enhanced oil recovery (EOR) applications where it is used for solubilization and mobilization of oil and for environmental cleanup. Further, the hydrophobe alkoxylated GA without anionic terminal group can be used as an ultra-high molecular weight non-ionic surfactant.
摘要翻译： 本文描述了通过使用环氧丁烷和任选的环氧丙烷和/或环氧乙烷烷氧基化具有12至36个碳原子的格伯特醇（GA），然后引入末端阴离子基团来合成阴离子表面活性剂的组合物和方法。 本发明的GA通过易于且廉价的方法制备，其涉及具有6至18个碳原子的醇的高温碱催化二聚。 本发明的大型疏水醚表面活性剂用于增强采油（EOR）应用中，其用于溶解和动员油并用于环境清洁。 此外，不含阴离子末端基团的疏水基烷氧基化GA可用作超高分子量非离子表面活性剂。
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公开(公告)号：US10155900B2
公开(公告)日：2018-12-18
申请号：US15263710
申请日：2016-09-13
申请人： Christian Bittner , Günter Oetter , Jack Tinsley , Christian Spindler , Gabriela Alvarez-Juergenson , Sophie Maitro-Vogel
发明人： Christian Bittner , Günter Oetter , Jack Tinsley , Christian Spindler , Gabriela Alvarez-Juergenson , Sophie Maitro-Vogel
摘要： The present invention relates to a surfactant mixture comprising at least three ionic surfactants which differ in terms of the hydrocarbyl moiety (R1)(R2)—CH—CH2— and are of the general formula (I) where R1, R2, A0, k, X, o, Y, a, b, M are each as defined in the description and the claims. The invention further relates to the use and preparation thereof, and to aqueous surfactant formulations comprising the mixtures, and to processes for producing mineral oil by means of Winsor type III microemulsion flooding, in which the aqueous surfactant formulation is injected into a mineral oil deposit through injection wells and crude oil is withdrawn from the deposit through production wells.
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4.发明申请PROCESS FOR MINERAL OIL PRODUCTION USING SURFACTANTS FROM THE CLASS OF THE ALKYL POLYGLUCOSIDES 审中-公开使用烷基聚糖的类别中的表面活性剂生产矿物油的方法公开(公告)号：US20120241151A1
公开(公告)日：2012-09-27
申请号：US13426305
申请日：2012-03-21
申请人： Christian Bittner , Günter Oetter , Jack Tinsley , Christian Spindler , Gabriela Alvarez Jürgenson , Sophie Maitro-Vogel , Monika Santa , Jianhua Mao
发明人： Christian Bittner , Günter Oetter , Jack Tinsley , Christian Spindler , Gabriela Alvarez Jürgenson , Sophie Maitro-Vogel , Monika Santa , Jianhua Mao
IPC分类号： E21B43/22
CPC分类号： C09K8/584
摘要： A process for mineral oil production, in which an aqueous surfactant formulation comprising at least one alkyl polyglucoside is injected into a mineral oil deposit through at least one injection borehole and crude oil is withdrawn from the deposit through at least one production borehole, wherein the formulation does not comprise any alcohols as cosolvents.
摘要翻译： 一种矿物油生产方法，其中包含至少一种烷基聚葡萄糖苷的含水表面活性剂制剂通过至少一个注射钻孔注入矿物油沉积物中，并且原油通过至少一个生产钻孔从沉积物中排出，其中制剂 不包含任何醇作为助溶剂。
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5.发明申请Process for Producing Mineral Oil Using Surfactants Based on C16C18-Containing Alkyl Propoxy Surfactants 有权基于含C16C18烷基丙氧基表面活性剂的表面活性剂生产矿物油的工艺公开(公告)号：US20140163255A1
公开(公告)日：2014-06-12
申请号：US14069785
申请日：2013-11-01
申请人： Christian Bittner , Günter Oetter , Jack Tinsley , Christian Spindler , Gabriela Alvarez-Juergenson , Sophie Maitro-Vogel , Veronika Wloka , Marcus Guzmann
发明人： Christian Bittner , Günter Oetter , Jack Tinsley , Christian Spindler , Gabriela Alvarez-Juergenson , Sophie Maitro-Vogel , Veronika Wloka , Marcus Guzmann
IPC分类号： C09K8/60
CPC分类号： C09K8/602 , B01F17/0057 , B01F17/0064 , C07C305/06 , C09K8/584
摘要： The invention relates to a process for mineral oil production by means of Winsor Type III microemulsion flooding, in which an aqueous surfactant formulation comprising at least one ionic surfactant of the general formula R1—O—(CH2C(CH3)HO)m(CH2CH2O)n—XY−M+ is injected through injection boreholes into a mineral oil deposit, and crude oil is withdrawn from the deposit through production boreholes. The invention further relates to ionic surfactants of the general formula.
摘要翻译： 本发明涉及一种通过Winsor III型微乳液驱油的矿物油生产方法，其中含有至少一种通式为R 1 -O-（CH 2 C（CH 3）HO）m（CH 2 CH 2 O） n-XY-M +通过注射钻孔注入矿物油沉积物中，原油通过生产钻孔从沉积物中排出。 本发明还涉及通式的离子表面活性剂。
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6.发明授权Process for producing mineral oil using surfactants based on C16C18-containing alkyl propoxy surfactants 有权基于含C16C18烷基丙氧基表面活性剂的表面活性剂生产矿物油的方法公开(公告)号：US09505973B2
公开(公告)日：2016-11-29
申请号：US14069785
申请日：2013-11-01
申请人： Christian Bittner , Günter Oetter , Jack Tinsley , Christian Spindler , Gabriela Alvarez-Juergenson , Sophie Maitro-Vogel , Veronika Wloka , Marcus Guzmann
发明人： Christian Bittner , Günter Oetter , Jack Tinsley , Christian Spindler , Gabriela Alvarez-Juergenson , Sophie Maitro-Vogel , Veronika Wloka , Marcus Guzmann
IPC分类号： C09K8/60 , B01F17/00 , C07C305/06 , C09K8/584
CPC分类号： C09K8/602 , B01F17/0057 , B01F17/0064 , C07C305/06 , C09K8/584
摘要： The invention relates to a process for mineral oil production by means of Winsor Type III microemulsion flooding, in which an aqueous surfactant formulation comprising at least one ionic surfactant of the general formula R1—O—(CH2C(CH3)HO)m(CH2CH2O)n—XY−M+ is injected through injection boreholes into a mineral oil deposit, and crude oil is withdrawn from the deposit through production boreholes. The invention further relates to ionic surfactants of the general formula.
摘要翻译： 本发明涉及一种通过Winsor III型微乳液驱油的矿物油生产方法，其中含有至少一种通式为R 1 -O-（CH 2 C（CH 3）HO）m（CH 2 CH 2 O） n-XY-M +通过注射钻孔注入矿物油沉积物中，原油通过生产钻孔从沉积物中排出。 本发明还涉及通式的离子表面活性剂。
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7.发明授权Process for extracting mineral oil using surfactants based on butylene oxide-containing alkyl alkoxylates 有权使用基于含环氧丁烷烷基烷氧基化物的表面活性剂提取矿物油的方法公开(公告)号：US08607865B2
公开(公告)日：2013-12-17
申请号：US13044345
申请日：2011-03-09
申请人： Christian Bittner , Günter Oetter , Jack Tinsley , Christian Spindler , Gabriela Alvarez-Jüergenson , Sophie Vogel
发明人： Christian Bittner , Günter Oetter , Jack Tinsley , Christian Spindler , Gabriela Alvarez-Jüergenson , Sophie Vogel
IPC分类号： E21B43/22
CPC分类号： C07F9/46 , B01F17/0021 , C07C305/06 , C09K8/584
摘要： The invention relates to a process for mineral oil extraction by means of Winsor Type III microemulsion flooding, in which an aqueous surfactant formulation comprising at least one ionic surfactant of the general formula R1—O-(D)n-(B)m-(A)l-XY−M+ is injected through injection boreholes into a mineral oil deposit, and crude oil is withdrawn from the deposit through production boreholes. The invention further relates to ionic surfactants of the general formula.
摘要翻译： 本发明涉及一种通过Winsor III型微乳液淹水进行矿物油提取的方法，其中含有至少一种通式R 1 -O-（D）n-（B）m - （D）的离子表面活性剂 A）l-XY-M +通过注射钻孔注入矿物油沉积物，原油通过生产钻孔从沉积物中排出。 本发明还涉及通式的离子表面活性剂。
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8.发明申请PROCESS FOR PRODUCING MINERAL OIL USING SURFACTANTS BASED ON A MIXTURE OF C32 GUERBET-, C34 GUERBET-, C36 GUERBET-CONTAINING ALKYL ALKOXYLATES 有权使用C32GERBET-，C34 GUERBET-，C36含有烷基烷氧基化物的混合物，使用表面活性剂生产矿物油的方法公开(公告)号：US20110263467A1
公开(公告)日：2011-10-27
申请号：US13091677
申请日：2011-04-21
申请人： CHRISTIAN BITTNER , Günter Oetter , Jack Tinsley , Christian Spindler , Gabriela Alvarez Jürgenson , Sophie Vogel , Petra Neumann , Veronika Wloka , Martin Bock
发明人： CHRISTIAN BITTNER , Günter Oetter , Jack Tinsley , Christian Spindler , Gabriela Alvarez Jürgenson , Sophie Vogel , Petra Neumann , Veronika Wloka , Martin Bock
IPC分类号： C09K8/584
摘要： The present invention relates to a process for mineral oil extraction by means of Winsor type III microemulsion flooding, in which an aqueous surfactant formulation comprising at least three ionic surfactants which are different with regard to the alkyl moiety (R1)(R2)—CH—CH2— and are of the general formula (R1)(R2)—CH—CH2—O—(D)n—(B)m—(A)l—XYa− a/b Mb+ is injected through injection boreholes into a mineral oil deposit, and crude oil is withdrawn from the deposit through production boreholes. The invention further relates to surfactant formulations of ionic surfactants of the general formula.
摘要翻译： 本发明涉及一种通过Winsor III型微乳液淹水进行矿物油提取的方法，其中包含至少三种离子表面活性剂的水性表面活性剂制剂，其对于烷基部分（R 1）（R 2）-CH- CH 2 - 并且具有通式（R1）（R2）-CH-CH2-O-（D）n-（B）m-（A）1-XYa- a / b Mb +通过注射孔注入矿物 石油储藏和原油通过生产井眼从沉积物中取出。 本发明还涉及通式为离子表面活性剂的表面活性剂制剂。
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公开(公告)号：US08584751B2
公开(公告)日：2013-11-19
申请号：US12903762
申请日：2010-10-13
申请人： Christian Bittner , Günter Oetter , Jack Tinsley , Christian Spindler , Gabriela Alvarez Jürgenson , Sophie Vogel
发明人： Christian Bittner , Günter Oetter , Jack Tinsley , Christian Spindler , Gabriela Alvarez Jürgenson , Sophie Vogel
摘要： A process for mineral oil production especially Winsor type III microemulsion flooding, in which an aqueous surfactant formulation which comprises at least one nonionic surfactant having 11 to 40 ethoxy units and a hydrophobic radical having 8 to 32 carbon atoms and at least one further surfactant differing therefrom is forced through injection wells into a mineral oil deposit and crude oil is removed from the deposit through production wells.
摘要翻译： 一种用于矿物油生产的方法，特别是Winsor III型微乳液驱油，其中包含至少一种具有11至40个乙氧基单元的非离子表面活性剂和具有8至32个碳原子的疏水基团和至少一种不同于此的其它表面活性剂的表面活性剂配方 被迫通过注入井进入矿物油沉积物，原油通过生产井从沉积物中移出。
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10.发明授权公开(公告)号：US08584750B2
公开(公告)日：2013-11-19
申请号：US12903441
申请日：2010-10-13
申请人： Christian Bittner , Oetter Günter , Jack Tinsley , Christian Spindler , Gabriela Alvarez Jürgenson , Sophie Vogel
发明人： Christian Bittner , Oetter Günter , Jack Tinsley , Christian Spindler , Gabriela Alvarez Jürgenson , Sophie Vogel
CPC分类号： C09K8/584
摘要： A process for mineral oil production, especially Winsor type III microemulsion flooding, in which an aqueous surfactant formulation which comprises at least one nonionic surfactant having 8 to 30 ethoxy units, which has a polydispersity of from 1.01 to 1.12, and at least one further surfactant is forced through injection wells into a mineral oil deposit and crude oil is removed from the deposit through production wells.
摘要翻译： 一种用于矿物油生产的方法，特别是Winsor III型微乳液淹水，其中含有至少一种具有8〜30个乙氧基单元的非离子表面活性剂，其分散性为1.01〜1.12，以及至少一种其它表面活性剂 被迫通过注入井进入矿物油沉积物，原油通过生产井从沉积物中移出。
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