N-alkyl ammonium acetonitrile salts, methods therefor and compositions therewith
    2.
    发明授权
    N-alkyl ammonium acetonitrile salts, methods therefor and compositions therewith 失效
    N-烷基铵乙腈盐,其方法和组合物

    公开(公告)号:US06764613B2

    公开(公告)日:2004-07-20

    申请号:US09849388

    申请日:2001-05-03

    IPC分类号: C09K300

    摘要: Substantially solid compositions are provided having therein a compound with the structure of Formula I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) —CR2R3C≡N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is a value in the range of 0 to 10, and wherein Y is monovalent or multivalent and is sulfate, bisulfate, tosylate, or mixtures of sulfate and bisulfate as counterion. These compositions have reduced water uptake due to the Formula I compound.

    摘要翻译: 其中提供了具有式I结构的化合物的基本固体组合物,其中A是除了N1原子之外由多个原子形成的饱和环,饱和环原子包括至少一个碳原子和至少一个O, S和N原子,与式I结构的N1原子结合的取代基R1包括(a)C1-24烷基或烷氧基为烷氧基的烷基,C2烷基,(b)C4-24环烷基,( c)C7-24烷芳基,(d)重复或不重复的烷氧基或烷氧基化醇,其中烷氧基单元是C 2-4,或(e)-CR 2 R 3 C = N,其中R 2和R 3各自为H, ,环烷基或烷芳基,或重复或非重复烷氧基或烷氧基化醇,其中烷氧基单元为C 2-4,R 2和R 3取代基各为H,C 1-4烷基,环烷基或烷芳基,或重复或非重复烷氧基 或烷氧基化醇,其中烷氧基单元为C2-4,Z为0至10的范围内的值,并且其中Y为单价或mu 是硫酸盐,硫酸氢盐,甲苯磺酸盐,或硫酸盐和硫酸氢盐的混合物作为抗衡离子。 这些组合物由于式I化合物而降低了吸水率。