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公开(公告)号:US06183665B2
公开(公告)日:2001-02-06
申请号:US09280178
申请日:1999-03-29
申请人: Sarah P. Blondeau , Susan P. Huestis , Agnes Jaszenovics , Gregory M. Piche , David C. Sandoval , William P. Sibert
发明人: Sarah P. Blondeau , Susan P. Huestis , Agnes Jaszenovics , Gregory M. Piche , David C. Sandoval , William P. Sibert
IPC分类号: C09K300
CPC分类号: C11D3/38618 , C07D295/15 , C11D3/3925 , C11D3/3947 , C11D3/42 , C11D17/06 , D06L4/12 , D06L4/17
摘要: Granules are provided that are useful for oxidizing applications when the granules are dissolved in the presence of an active oxygen source. These granules include a salt having the structure of Formula I wherein A is a saturated ring formed by a plurality of atoms in addition to the N1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R1 bound to the N1 atom of the Formula I structure including either (a) a C1-24 alkyl or alkoxylated alkyl where the alkoxy is C2-4, (b) a C4-24 cycloalkyl, (c) a C7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C2-4, or (e) —CR2R3C≡N where R2 and R3 are each H, a C1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, the R2 and R3 substituents being each H, a C1-24 alky, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C2-4, Z is in the range of 0 to 10, and wherein Y is a counterion. An improved granule is produced when the salt is carried by, coated with, or admixed with a solid particulate such as silica gel, silicic acid, silicate, aluminum oxide, clay, or mixtures thereof.
摘要翻译: 当颗粒在活性氧源的存在下溶解时,提供可用于氧化应用的颗粒。 这些颗粒包括具有式I结构的盐,其中A是除了N1原子之外由多个原子形成的饱和环,饱和环原子包括至少一个碳原子和O,S和N中的至少一个 原子,与式I结构的N1原子结合的取代基R1包括(a)C1-24烷基或烷氧基为烷氧基的烷氧基为C2-4,(b)C4-24环烷基,(c)C7 -24烷芳基,(d)重复或非重复烷氧基或烷氧基化醇,其中烷氧基单元是C 2-4,或(e)-CR 2 R 3 C = N,其中R 2和R 3各自为H,C 1-24烷基,环烷基或 烷芳基或重复或非重复烷氧基或烷氧基化醇,其中烷氧基单元为C 2-4,R 2和R 3取代基各为H,C 1-4烷基,环烷基或烷芳基,或重复或非重复烷氧基或烷氧基化醇,其中 烷氧基单元为C2-4,Z为0〜10的范围,Y为抗衡离子。 当盐被固体颗粒如硅胶,硅酸,硅酸盐,氧化铝,粘土或它们的混合物携带,涂覆或混合时,产生改进的颗粒。
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公开(公告)号:US5730306A
公开(公告)日:1998-03-24
申请号:US292627
申请日:1994-03-31
CPC分类号: B65D53/04 , B65D51/1616 , B65D51/1622
摘要: A dual cap lining for bi-directional venting comprising a substantially round, disc-shaped, laminated, fluid-impermeable, gas-permeablematerial bottom layer, and having an extruded and cast polyethylene material top layer which is provided with apertures which communicate with the bottom layer and also communicate with channels provided on the upper surface of the top layer, and the material of construction of the laminated bottom layer is gas-permeable such that the dual lining allows bi-directional gas flow therethrough, for gases which have built-up in the interior of the connected container to safely escape by venting from the interior of the container to the external ambient atmosphere through openings existing between the spiral screw threads of the cap closure and threads of the container neck, and the reverse venting to equilibrate for relatively increased external pressure, without passage of solid or liquid material from the interior of the container through the lining to the closure and to the exterior of the container.
摘要翻译: 一种用于双向排气的双盖衬里,包括基本上圆形的盘形层压不透流体的气体可渗透材料底层,并且具有挤出和浇铸的聚乙烯材料顶层,该顶层设置有与底部连通的孔 并且还与顶层的上表面上设置的通道连通,并且层压底层的构造材料是透气的,使得双层衬里允许双向气体流过其中,用于已经积聚的气体 在连接的容器的内部,通过存在于盖子的螺旋螺纹和容器颈部的螺纹之间的开口,通过从容器的内部排放到外部环境大气以安全地逃逸,并且反向排气以相对于平衡 增加的外部压力,而不会使固体或液体材料从容器的内部通过衬里通过 封闭和容器的外部。
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公开(公告)号:US5252245A
公开(公告)日:1993-10-12
申请号:US832275
申请日:1992-02-07
IPC分类号: C11D1/14 , C11D1/58 , C11D1/72 , C11D1/75 , C11D1/825 , C11D1/94 , C11D3/02 , C11D3/30 , C11D3/32 , C11D3/33 , C11D3/43 , C11D1/50 , C11D3/26 , C11D9/00
CPC分类号: C11D3/044 , C11D1/825 , C11D1/94 , C11D3/30 , C11D3/32 , C11D3/323 , C11D3/33 , C11D3/43 , C11D1/146 , C11D1/58 , C11D1/72 , C11D1/75
摘要: The invention provides an aqueous, hard surface cleaner with significantly improved residue removed and substantially reduced filming/streaking, said cleaner comprising:(a) an effective amount of a solvent selected from C.sub.1-6 alkanol, C.sub.3-24 alkylene glycol ether, and mixtures thereof;(b) an effective amount of a surfactant selected from amphoteric, nonionic and anionic surfactants, and mixtures thereof;(c) an effective amount of a buffering system which comprises a nitrogenous buffer selected from the group consisting of:ammonium or alkaline earth carbamates, guanidine derivatives, alkoxylalkylamines and alkyleneamines; and(d) the remainder as substantially all water.
摘要翻译: 本发明提供了一种水性硬表面清洁剂,其具有显着改善的残留物去除并显着减少成膜/条纹,所述清洁剂包括:(a)有效量的选自C 1-6链烷醇,C 3-24亚烷基二醇醚和混合物 的; (b)有效量的选自两性,非离子和阴离子表面活性剂的表面活性剂及其混合物; (c)有效量的缓冲系统,其包含选自以下的含氮缓冲液:铵或碱土氨基甲酸酯,胍衍生物,烷氧基烷基胺和亚烷基胺; 和(d)其余部分基本上全部为水。
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公开(公告)号:US5523024A
公开(公告)日:1996-06-04
申请号:US518384
申请日:1995-08-23
IPC分类号: C11D1/14 , C11D1/58 , C11D1/72 , C11D1/75 , C11D1/825 , C11D1/94 , C11D3/02 , C11D3/10 , C11D3/20 , C11D3/30 , C11D3/32 , C11D3/33 , C11D3/43 , C11D1/66 , C11D3/26 , C11D3/28
CPC分类号: C11D3/046 , C11D1/75 , C11D1/825 , C11D1/94 , C11D3/044 , C11D3/10 , C11D3/201 , C11D3/2068 , C11D3/30 , C11D3/32 , C11D3/323 , C11D3/33 , C11D3/43 , C11D1/146 , C11D1/58 , C11D1/72
摘要: The invention provides an aqueous, hard surface cleaner with significantly improved residue removal and substantially reduced filming/streaking, said cleaner comprising:(a) an effective amount of at least one organic solvent with a vapor pressure of at least 0.001 mm Hg at 25.degree. C., and mixtures of such solvents;(b) an effective amount of at least one semi-polar nonionic surfactant, said surfactant having the structure: ##STR1## wherein R.sup.1 is C.sub.5-20 alkyl, R.sup.2 and R.sup.3 are both C.sub.1-4 alkyl, or --(CH.sub.2).sub.p --OH, although R.sup.2 and R.sup.3 do not have to be equal, and p is 1-6;(c) an effective amount of a buffering system which comprises a nitrogenous buffer which will result in a pH of greater than 6.5; and(d) the remainder as substantially all water.
摘要翻译: 本发明提供了一种水性硬表面清洁剂,其具有显着改善的残余物去除和基本上减少的成膜/条纹,所述清洁剂包括:(a)有效量的至少一种有机溶剂,其在25℃下的蒸气压至少为0.001mm Hg C.和这些溶剂的混合物; (b)有效量的至少一种半极性非离子表面活性剂,所述表面活性剂具有以下结构:其中R1为C5-20烷基,R2和R3均为C1-4烷基或 - (CH2)p- OH,尽管R2和R3不必相等,p为1-6; (c)有效量的缓冲系统,其包含将导致大于6.5的pH的含氮缓冲液; 和(d)其余部分基本上全部为水。
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公开(公告)号:US5468423A
公开(公告)日:1995-11-21
申请号:US134348
申请日:1993-10-08
申请人: Aram Garabedian, Jr. , Scott C. Mills , William P. Sibert , Clement K. Choy , Fernando J. Rebelo do Couto
发明人: Aram Garabedian, Jr. , Scott C. Mills , William P. Sibert , Clement K. Choy , Fernando J. Rebelo do Couto
IPC分类号: C11D1/14 , C11D1/58 , C11D1/72 , C11D1/75 , C11D1/825 , C11D1/94 , C11D3/02 , C11D3/30 , C11D3/32 , C11D3/33 , C11D3/43 , C11D1/66 , C11D3/26 , C11D3/28
CPC分类号: C11D3/044 , C11D1/825 , C11D1/94 , C11D3/30 , C11D3/32 , C11D3/323 , C11D3/33 , C11D3/43 , C11D1/146 , C11D1/58 , C11D1/72 , C11D1/75
摘要: The invention provides an aqueous, hard surface cleaner with significantly improved residue removal and substantially reduced filming/streaking, said cleaner comprising:(a) an effective amount of a solvent selected from C.sub.1-6 alkanol, C.sub.3-24 alkylene glycol ether, and mixtures thereof;(b) an effective amount of at least one nonionic surfactant;(c) an effective amount of a buffering system which comprises a nitrogenous buffer selected from the group consisting of:ammonium or alkaline earth carbamates, guanidine derivatives, alkoxylalkylamines and alkyleneamines; and(d) the remainder as substantially all water.
摘要翻译: 本发明提供一种水性硬表面清洁剂,其具有显着改善的残留物去除和显着减少的成膜/条纹,所述清洁剂包括:(a)有效量的选自C 1-6链烷醇,C 3-24亚烷基二醇醚和混合物 的; (b)有效量的至少一种非离子表面活性剂; (c)有效量的缓冲系统,其包含选自以下的含氮缓冲液:铵或碱土氨基甲酸酯,胍衍生物,烷氧基烷基胺和亚烷基胺; 和(d)其余部分基本上全部为水。
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公开(公告)号:US5888419A
公开(公告)日:1999-03-30
申请号:US758539
申请日:1996-11-29
申请人: Victor M. Casella , Ulrich Brockel , Clement K. Choy , James E. Deline , Lafayette D. Foland , Susan P. Huestis , Kevin A. Klotter , Sarah A. Perkins , David Peterson , Michael J. Petrin , Martin J. Phillippi , William P. Sibert , Michael Schonherr , Hans Peter Seelmann-Eggebert , William L. Smith , Alfred G. Zielske , Thomas W. Kaaret
发明人: Victor M. Casella , Ulrich Brockel , Clement K. Choy , James E. Deline , Lafayette D. Foland , Susan P. Huestis , Kevin A. Klotter , Sarah A. Perkins , David Peterson , Michael J. Petrin , Martin J. Phillippi , William P. Sibert , Michael Schonherr , Hans Peter Seelmann-Eggebert , William L. Smith , Alfred G. Zielske , Thomas W. Kaaret
IPC分类号: C07D295/14 , C07D295/15 , C11D3/12 , C11D3/28 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , C11D17/06 , D06L3/02 , H04B7/06 , C09K3/00 , B27N5/00 , C01B15/10
CPC分类号: C07D295/15 , C11D17/06 , C11D3/3925 , C11D3/3935 , D06L3/021 , D06L3/026
摘要: Granules are provided that are useful for oxidizing applications when the granules are dissolved in the presence of an active oxygen source. These granules include a salt having the structure of Formula I ##STR1## wherein A is a saturated ring formed by a plurality of atoms in addition to the N.sub.1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R.sub.1 bound to the N.sub.1 atom of the Formula I structure including either (a) a C.sub.1-24 alkyl or alkoxylated alkyl where the alkoxy is C.sub.2-4, (b) a C.sub.4-24 cycloalkyl, (c) a C.sub.7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C.sub.2-4, or (e) --CR.sub.2 R.sub.3 C.tbd.N where R.sub.2 and R.sub.3 are each H, a C.sub.1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C.sub.2-4, the R.sub.2 and R.sub.3 substituents being each H, a C.sub.1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C.sub.2-4, Z is in the range of 0 to 10, and wherein Y is a counterion. The salt is carried by, coated with, or admixed with a solid particulate such as silica gel, silicic acid, silicate, aluminum oxide, clay, aluminum silicate, or mixtures thereof.
摘要翻译: 当颗粒在活性氧源的存在下溶解时,提供可用于氧化应用的颗粒。 这些颗粒包括具有式I结构的盐,其中A是除N1原子之外由多个原子形成的饱和环,饱和环原子包括至少一个碳原子和至少一个碳原子 O,S和N原子,与式I结构的N1原子结合的取代基R1包括(a)C1-24烷基或烷氧基为烷氧基的烷基,其中烷氧基为C2-4,(b)C4-24环烷基 ,(c)C7-24烷芳基,(d)重复或非重复烷氧基或烷氧基化醇,其中烷氧基单元为C 2-4,或(e)-CR 2 R 3 C 3 N N其中R 2和R 3各自为H, 24烷基,环烷基或烷芳基,或重复或非重复烷氧基或烷氧基化醇,其中烷氧基单元为C 2-4,R 2和R 3取代基各为H,C 1-4烷基,环烷基或烷芳基,或重复或 非重复烷氧基或烷氧基化醇,其中烷氧基单元为C 2-4,Z在0至10的范围内,并且其中Y为抗衡离子。 盐与硅胶,硅酸,硅酸盐,氧化铝,粘土,硅酸铝或其混合物等固体颗粒携带,涂覆或混合。
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公开(公告)号:US5817615A
公开(公告)日:1998-10-06
申请号:US657075
申请日:1996-06-03
IPC分类号: C11D1/14 , C11D1/58 , C11D1/72 , C11D1/75 , C11D1/825 , C11D1/94 , C11D3/02 , C11D3/10 , C11D3/20 , C11D3/30 , C11D3/32 , C11D3/33 , C11D3/43 , C11D3/44 , C11D7/12
CPC分类号: C11D1/75 , C11D1/825 , C11D1/94 , C11D3/044 , C11D3/046 , C11D3/10 , C11D3/201 , C11D3/2068 , C11D3/30 , C11D3/32 , C11D3/323 , C11D3/33 , C11D3/43 , C11D1/146 , C11D1/58 , C11D1/72
摘要: The invention provides an aqueous, hard surface cleaner with significantly improved residue removal and substantially reduced filming/streaking, said cleaner comprising: (a) an effective amount of at least one organic solvent with a vapor pressure of at least 0.001 mm Hg at 25.degree. C., and mixtures of such solvents; (b) an effective amount of at least one semi-polar nonionic surfactant, said surfactant having the structure: ##STR1## wherein R.sup.1 is C.sub.5-20 alkyl, R.sup.2 and R.sup.3 are both C.sub.1-4 alkyl, or --(CH.sub.2).sub.p --OH, although R.sup.2 and R.sup.3 do not have to be equal, and p is 1-6; (c) an effective amount of a buffering system which comprises a nitrogenous buffer which will result in a pH of greater than 6.5; and (d) the remainder as substantially all water.
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公开(公告)号:US5579936A
公开(公告)日:1996-12-03
申请号:US332208
申请日:1994-10-31
CPC分类号: B65D51/1622
摘要: A dual cap lining for bi-directional venting comprising a substantially shaped, laminated or secured, fluid-impermeable, gas-permeable material bottom layer congruent with a container opening, and having an extruded and cast polyethylene material top layer which is provided with channels on the lower surface of the top layer, and the material of construction of the laminated bottom layer is gas-permeable such that the dual lining allows bi-directional gas flow therethrough, for gases which have built-up in the interior of the connected container to safely escape by venting from the interior of the container to the external ambient atmosphere through openings existing between the spiral screw threads of the cap closure and threads of the container neck, and the reverse venting to equilibrate for relatively increased external pressure, without passage of solid or liquid material from the interior of the container through the lining to the closure and to the exterior of the container.
摘要翻译: 一种用于双向排气的双盖衬里,包括与容器开口一致的基本上成形的,层压的或固定的不透流体的气体可渗透的材料底层,并且具有挤出和浇铸的聚乙烯材料顶层,其上设置有通道 顶层的下表面和层压底层的构造材料是透气的,使得双层衬里允许双向气体流过其中,用于在连接的容器的内部积聚的气体 通过存在于帽盖的螺旋螺纹和容器颈部的螺纹之间的开口,通过从容器内部排放到外部环境大气而安全地逃逸,并且反向排气以平衡相对增加的外部压力,而不通过固体 或液体材料从容器的内部通过衬里到封闭件和容器的外部。
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公开(公告)号:US5437807A
公开(公告)日:1995-08-01
申请号:US134349
申请日:1993-10-08
IPC分类号: C11D1/14 , C11D1/58 , C11D1/72 , C11D1/75 , C11D1/825 , C11D1/94 , C11D3/02 , C11D3/30 , C11D3/32 , C11D3/33 , C11D3/43 , C11D1/50 , C11D3/26
CPC分类号: C11D3/044 , C11D1/825 , C11D1/94 , C11D3/30 , C11D3/32 , C11D3/323 , C11D3/33 , C11D3/43 , C11D1/146 , C11D1/58 , C11D1/72 , C11D1/75
摘要: The invention provides an aqueous, hard surface cleaner with significantly improved residue removal and substantially reduced filming/streaking, said cleaner comprising:(a) an effective amount of a solvent selected from C.sub.1-6 alkanol, C.sub.3-24 alkylene glycol ether, and mixtures thereof;(b) an effective amount of a surfactant selected from amphoteric, nonionic and anionic surfactants, and mixtures thereof;(c) an effective amount of a buffering system which comprises a nitrogenous buffer selected from the group consisting of:ammonium or alkaline earth carbamates, guanidine derivatives, alkoxylalkylamines and alkyleneamines; and(d) the remainder as substantially all water.
摘要翻译: 本发明提供一种水性硬表面清洁剂,其具有显着改善的残留物去除和显着减少的成膜/条纹,所述清洁剂包括:(a)有效量的选自C 1-6链烷醇,C 3-24亚烷基二醇醚和混合物 的; (b)有效量的选自两性,非离子和阴离子表面活性剂的表面活性剂及其混合物; (c)有效量的缓冲系统,其包含选自以下的含氮缓冲液:铵或碱土氨基甲酸酯,胍衍生物,烷氧基烷基胺和亚烷基胺; 和(d)其余部分基本上全部为水。
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公开(公告)号:US6022843A
公开(公告)日:2000-02-08
申请号:US151188
申请日:1998-09-09
摘要: The invention is an improved, non-phosphate, non-bleach, agglomerated laundry booster which has a) a solids portion with i) at least 5% by weight of a first builder selected from the group consisting of alkali metal carbonate, alkali metal bicarbonate, alkali metal sesquicarbonate, and mixtures thereof; and ii) a second builder of at least 25% by weight alkali metal tetraborate pentahydrate; and b) i) a first liquid which comprises an anionic, acidic surfactant, in an amount no greater than about 10% by weight; and ii) a second liquid which comprises an agglomerating agent. The first liquid is neutralized by the first builder of a)i) to form a first set of particles, the second builder forms a second set of particles, and the second liquid co-agglomerates both the first and second sets of particles. The invention also provides a method for preparing this laundry booster.
摘要翻译: 本发明是一种改进的非磷酸盐,非漂白,附聚的洗衣增效剂,其具有a)固体部分,其中i)至少5重量%的第一助洗剂,其选自碱金属碳酸盐,碱金属碳酸氢盐 ,碱金属倍半碳酸盐,及其混合物; 和ii)至少25重量%碱金属四硼酸盐五水合物的第二助洗剂; 和b)i)第一液体,其包含不大于约10重量%的阴离子,酸性表面活性剂; 和ii)包含附聚剂的第二液体。 第一液体被a)i)的第一助洗剂中和以形成第一组颗粒,第二助洗剂形成第二组颗粒,第二液体共同聚集第一组和第二组颗粒。 本发明还提供了一种用于制备该衣物助剂的方法。
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